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Publishing Language: Chinese

Preparation and Properties of Glass Composite Phosphor for Laser Lighting

Guilu WANG1,2Yuqiang KONG1,2Yonggang ZHU1,2( )Xigui ZHENG1,2Yanna LU1,2Yuelong MA3,4Xingyu QI3Yongxing HAO1,2
School of Mechanical Engineering, Zhengzhou University of Science and Technology, Zhengzhou 450064, Henan, China
Henan Province Engineering Research Center of Digital & Intelligent Equipment, Zhengzhou University of Science and Technology, Zhengzhou 450064, Henan, China
School of Mechanical and Electrical Engineering, Henan University of Technology, Zhengzhou 450001, Henan, China
Songshan Laboratory, Zhengzhou 450046, Henan, China
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Abstract

Laser lighting has shown enormous potential in various fields, such as automotive lighting, military reconnaissance and projection display, due to its advantages of high brightness, small size and long illumination distance. However, phosphor in glass (PIG) has the problem of balancing high color rendering index (CRI) and high luminous flux (LF). Therefore, a composite PIG containing yellow phosphor (YAG:Ce3+) and red phosphor (CASN:Eu2+) was prepared. The internal quantum efficiency (IQE) of the prepared YAG:Ce3+ PIG is as high as 90.50% (95.4% of the original phosphor) and the luminous intensity at 150 ℃ is 93.3% of that at room temperature. After encapsulating YAG: Ce3+ with a mass percentage of 10 wt.% PIG and LD, the maximum LF obtained is 3479.2 lm. The LF of 7 wt.% CaAlSiN red PIG under 7.8 W laser excitation is 413 lm. By optimizing the ratio in the composite PIG, the maximum CRI of the laser device is 82.2, the correlation color temperature (CCT) is 4281 K, the luminous efficiency (LE) is 171.2 lm·W−1 and the LF is 2036.6 lm with the combination of 10 wt.% YAG:Ce3+ and 7 wt.%CASN:Eu2+. Meanwhile, high CRI and high LF of PIG-based laser devices are realized. Therefore, PIG with homogenous structure combination is regarded as a potential phosphor conversion material.

CLC number: TQ174.75 Document code: A Article ID: 1000-2278(2024)05-0968-09

References

[1]

SCHUBERT E F, KIM J K. Solid-state light sources getting smart [J]. Science, 2005, 308(5726): 1274–1278.

[2]
WANG G L, ZHENG X G, CAO A G, et al. Journal of Ceramics, 2023, 44(1): 38–57.
[3]

KIM Y H, ARUNKUMAR P, KIM B Y, et al. A zerothermal-quenching phosphor [J]. Nature Materials, 2017, 16(5): 543–550.

[4]

CHO J, PARK J H, KIM J K, et al. White light-emitting diodes: history, progress, and future [J]. Laser & Photonics Reviews, 2017, 11(2): 1600147.

[5]
WANG M E, WU D, XU W P, et al. Laser & Infrared, 2022, 52(10): 1427–1435.
[6]

SAHRANESHIN A, TAKAMI S, MINAMI K, et al. Synthesis and morphology control of surface functionalized nanoscale yttrium aluminum garnet particles via supercritical hydrothermal method [J]. Progress in Crystal Growth and Characterization of Materials, 2012, 58(1): 43–50.

[7]
XIE F, YAN R, WANG R, et al. Electronic Components and Materials, 2020, 39(2): 39–44.
[8]
ZHANG Y, LIU S, XU H J, et al. Journal of Inorganic Materials, 2015, 30(6): 588–592.
[9]

ZHOU Y, YU C K, SONG E H, et al. Three birds with one stone: K2SiF6: Mn4+ single crystal phosphors for high-power and laser-driven lighting [J]. Advanced Optical Materials, 2020, 8(23): 2000976.

[10]

REJMAN M, BABIN V, KUCERKOVÁ R, et al. Temperature dependence of CIE-x, y color coordinates in YAG: Ce single crystal phosphor [J]. Journal of Luminescence, 2017, 187: 20–25.

[11]

MA Y L, WANG Z D, PANG T, et al. A cyan-green-emitting garnet-structured Lu3-xScxAl2-yScyAl3-zSczO12: Ce3+ phosphor ceramics towards high-color-quality laser-driven lighting [J]. Ceramics International, 2024, 50(12): 21074–21082.

[12]

MA Y L, LI X C, WU L, et al. Preparation of (Lu, Y)3(Al, Sc, Cr)2Al3O12 phosphor ceramic with high thermal stability for near-infrared LED/LD [J]. Journal of Advanced Ceramics, 2024, 13(3): 354–363.

[13]

XU F C, LIANG Y Y, ZHANG J D, et al. High efficiency green-emitting phosphor-in-glass films for high-power solid-state laser lighting [J]. Ceramics International, 2022, 48(14): 20817–20824.

[14]

ZENG Y, GUO F, RAO G H, et al. High CRI white lightemitting phosphor-in-glass film for laser lighting applications by adding cyan phosphor BaSi2O2N2: Eu2+ [J]. Ceramics International, 2023, 49(5): 7927–7934.

[15]

LIANG Y F, DING X R, YAN C M, et al. Phosphor-in-glass (PIG) converter sintered by a fast joule heating process for high-power laser-driven white lighting [J]. Optics Express, 2021, 29(10): 14218–14230.

[16]

WANG L H, ZHANG J D, XU L, et al. Ce: GdYAG phosphor-in-glass: an innovative yellow-emitting color converter for solid-state laser lighting [J]. Journal of Materials Science & Technology, 2023, 134: 42–49.

[17]

PENG Y, MOU Y, GUO X, et al. Flexible fabrication of a patterned red phosphor layer on a YAG: Ce3+ phosphor-in-glass for high-power WLEDs [J]. Optical Materials Express, 2018, 8(3): 605–614.

[18]

WU H J, HAO Z D, PAN G H, et al. Phosphor-SiO2 composite films suitable for white laser lighting with excellent color rendering [J]. Journal of the European Ceramic Society, 2020, 40(6): 2439–2444.

[19]

HUANG Q, SUI P, HUANG F, et al. Toward high-quality laser-driven lightings: Chromaticity-tunable phosphor-in-glass film with "phosphor pattern" design [J]. Laser & Photonics Reviews, 2022, 16(7): 2200040.

[20]
HOU H L, LIU C L, LIU F S, et al. Chinese Journal of Lasers, 2023, 50(10): 75–82.
[21]

BAO H R, LIN H, ZHANG D W, et al. Sr AlSiN3: Eu2+ containing phosphor-in-glass: A color converter for solid state laser lighting [J]. Optical Materials, 2022, 126: 112169.

Journal of Ceramics
Pages 968-976
Cite this article:
WANG G, KONG Y, ZHU Y, et al. Preparation and Properties of Glass Composite Phosphor for Laser Lighting. Journal of Ceramics, 2024, 45(5): 968-976. https://doi.org/10.13957/j.cnki.tcxb.2024.05.011

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Received: 09 September 2024
Revised: 12 June 2024
Published: 01 October 2024
© 2024 Journal of Ceramics
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