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Publishing Language: Chinese | Open Access

Effect of Sintering Agent Li2CO3 on Thermal-Mechanical-Optical Properties of Yttrium Tantalate Transparent Ceramics

Jian-Yu LI1Jia-Qi LI1Meng MA1Chun-Yu GE1,2Zi-Fan ZHAO1( )Jing FENG1( )
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
Faculty of Material Science and Engineering, Jiamusi University, Jiamusi 154007, China
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Abstract

Tantalum pentoxide and yttrium oxide were used as base materials. By adding alkali metal sintering agent Li2CO3, the doped tantalate ceramic samples were prepared by high temperature solid-phase sintering. The effects of alkali metal sintering agent Li2CO3 on the physical and chemical properties of rare earth yttrium tantalate coating were studied by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), laser pulse method (LFA), thermal-mechanical analyzer (TMA) and UV-visive-near-infrared spectrophotometer. The results show that under the sintering system at 1530℃, the ceramic is compact, resulting in Li3TaO4 ceramic. With more Li2CO3 inclusion, the higher Li3TaO4 of the second phase is generated. With a stable thermal expansion coefficient, the range of 8.2-8.6×10-6K-1(900℃); The Young's modulus and hardness of the samples decreased with the increase of the added sintering aid dose. When 6% alkali metal sintering agent Li2O3 is mixed into the ceramic, the transmittance rate of YTaO4 ceramic can be stable at more than 80%, which shows that YTaO4 ceramic has superior potential of optical ceramics.

CLC number: O482 Document code: A Article ID: 1005-1198(2024)03-0268-11

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Advanced Ceramics
Pages 268-278
Cite this article:
LI J-Y, LI J-Q, MA M, et al. Effect of Sintering Agent Li2CO3 on Thermal-Mechanical-Optical Properties of Yttrium Tantalate Transparent Ceramics. Advanced Ceramics, 2024, 45(3): 268-278. https://doi.org/10.16253/j.cnki.37-1226/tq.2024.03.006

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Received: 15 December 2023
Revised: 25 February 2024
Published: 01 June 2024
© Advanced Ceramics.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/).

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