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Research Article | Open Access

Functional LiTaO3 filler with tandem conductivity and ferroelectricity for PVDF-based composite solid-state electrolyte

Yu Yuan1,2,†, Likun Chen1,2,†, Yuhang Li1,2, Xufei An1,2, Jianshuai Lv1,2, Shaoke Guo1,2, Xing Cheng1,2, Yang Zhao1,2, Ming Liu1( ), Yan-Bing He1( ), Feiyu Kang1,2
Shenzhen All-Solid-State Lithium Battery Electrolyte Engineering Research Center, Institute of Materials Research (IMR), Tsinghua Shenzhen International Graduate School, Shenzhen 518055, China
School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

† Yu Yuan and Likun Chen contributed equally to this work.

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Abstract

Composite solid-state electrolytes have received significant attention due to their combined advantages as inorganic and polymer electrolytes. However, conventional ceramic fillers offer limited ion conductivity enhancement for composite solid-state electrolytes due to the space-charge layer between the polymer matrix and ceramic phase. In this study, we develop a ferroelectric ceramic ion conductor (LiTaO3) as a functional filler to simultaneously alleviate the space-charge layer and provide an extra Li+ transport pathway. The obtained composite solid-state electrolyte comprising LiTaO3 filler and poly (vinylidene difluoride) matrix (P-LTO15) achieves an ionic conductivity of 4.90 × 10−4 S cm−1 and a Li+ transference number of 0.45. The polarized ferroelectric LiTaO3 creates a uniform electric field and promotes homogenous Li plating/stripping, providing the Li symmetrical batteries with an ultrastable cycle life for 4000 h at 0.1 mA cm−2 and a low polarization overpotential (~50 mV). Furthermore, the solid-state NCM811/P-LTO15/Li full batteries achieve an ultralong cycling performance (1400 cycles) at 1 C and a high discharge capacity of 102.1 mAh g−1 at 5 C. This work sheds light on the design of functional ceramic fillers for composite solid-state electrolytes to effectively enhance ion conductivity and battery performance.

Keywords

ferroelectric ion conductorcomposite solid-state electrolytesspace charge layerLi deposition

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Energy Materials and Devices
Volume 1 Issue 1,
September 2023
Article number: 9370004
DOI: 10.26599/EMD.2023.9370004
Cite this article:
Yuan Y, Chen L, Li Y, et al. Functional LiTaO3 filler with tandem conductivity and ferroelectricity for PVDF-based composite solid-state electrolyte. Energy Materials and Devices, 2023, 1(1): 9370004. https://doi.org/10.26599/EMD.2023.9370004

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Received: 04 August 2023
Revised: 26 August 2023
Accepted: 31 August 2023
Published: 21 September 2023
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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