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Research Article | Open Access

Determining the electrochemical activation mechanism of Prussian blue analog precatalysts for a high-efficiency oxygen evolution reaction

Wei Hua1, Huanhuan Sun1, Yueying Li2, Yu Zhang3( ), Jian-Gan Wang1,2( )
State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Lab of Graphene (NPU), Xi’an 710072, China
New Energy (Photovoltaic) Industry Research Center, Qinghai University, Xining 810016, China
School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237, China
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Abstract

Prussian blue analogs (PBAs) are effective precatalysts for the oxygen evolution reaction (OER); however, the underlying mechanism of their electrochemical activation is still not well elucidated. In this study, we designed and constructed PBA-based precatalysts to determine the electrochemical activation mechanism and achieve high-efficiency OER. The PBAs undergo in situ electrochemical transformation to form the corresponding metal (oxy)hydroxides (M(O)OH) as the true OER catalyst. More importantly, the hexacyanoferrate ligands undergo repetitive interfacial coordination/etching with/from M(O)OH during the activation process. The distinct mechanism could achieve in situ Fe doping and enable defect incorporation. The defect-enriched Fe-NiOOH derived from a well-designed NiHCF/Ni(OH)2 precatalyst requires a low overpotential of 227 mV to reach a current density of 10 mA cm−2 and works stably at 130 mA cm−2 over 100 h. This study provides fundamental insights into the electrochemical activation mechanism for developing advanced precatalysts for OER.

Keywords

electrochemical activationPrussian blue analogsoxygen evolution reactionwater splitting

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Energy Materials and Devices
Volume 1 Issue 2,
December 2023
Article number: 9370014
DOI: 10.26599/EMD.2023.9370014
Cite this article:
Hua W, Sun H, Li Y, et al. Determining the electrochemical activation mechanism of Prussian blue analog precatalysts for a high-efficiency oxygen evolution reaction. Energy Materials and Devices, 2023, 1(2): 9370014. https://doi.org/10.26599/EMD.2023.9370014

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Received: 04 December 2023
Revised: 15 January 2024
Accepted: 16 January 2024
Published: 24 January 2024
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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