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Research Article | Open Access

Construction of metal–organic framework-derived Al-doped Na3V2(PO4)3 cathode materials for high-performance rechargeable Na-ion batteries

Yihan Zhao1,2, Xueqi Lai2, Pengfei Wang1,2, Zonglin Liu2, Tingfeng Yi1,2( )
School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, China
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Abstract

Na3V2(PO4)3 (NVP) has emerged as one of the most promising cathode materials for sodium-ion batteries (SIBs) owing to its high ionic conductivity and high theoretical energy density. However, the inherent inferior conductivity of NVP prevents its achievement of the theoretical energy density even at low rates, thereby limiting the practical application of NVP in massive energy storage. Here, Al3+-doped Na3V2−xAlx(PO4)3 (NVAP) materials derived from aluminum terephthalate (MIL-53(Al)) were synthesized for the first time, and the effects of Al3+ doping on the structural and electrochemical performances of NVP were investigated. The NVAP materials, particularly Na3V1.97Al0.03(PO4)3 (NVAP2), exhibited superior cycling performance and rate capabilities compared with the NVP material. NVAP2 exhibited a good rate capability, with high reversible discharge capacities of 111.6, 110.3, 108.9, 106.6, 103.4, 96.9, and 88.7 mAh g−1 at 0.1, 0.2, 0.5, 1, 2, 5, and 10C rates, respectively. Moreover, the NVAP2 material exhibited a prominent initial discharge capacity of 102.3 mAh g−1 and maintained an excellent capacity retention rate of 92.0% after 2000 cycles at 10C, indicating significant cycling stability. Overall, this work provides an efficient technique for enhancing the electrochemical properties of cathode materials with a sodium superionic conductor structure for SIBs.

Keywords

Na-ion batteryNa3V2(PO4)3dopingcycling stabilityrate capability

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Energy Materials and Devices
Volume 1 Issue 2,
December 2023
Article number: 9370021
DOI: 10.26599/EMD.2023.9370021
Cite this article:
Zhao Y, Lai X, Wang P, et al. Construction of metal–organic framework-derived Al-doped Na3V2(PO4)3 cathode materials for high-performance rechargeable Na-ion batteries. Energy Materials and Devices, 2023, 1(2): 9370021. https://doi.org/10.26599/EMD.2023.9370021

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Received: 03 January 2024
Revised: 16 January 2024
Accepted: 16 January 2024
Published: 26 January 2024
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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