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Research Article | Open Access | Online First

Selective synergy of 1,3-diketone for different base oil to promote the realization of oil-based superlubricity

Shaonan Du1Yanan Meng1Chenhui Zhang1( )Zhi Luo2( )
State Key Laboratory of Tribology in Advanced Equipment, Tsinghua University, Beijing 100084, China
Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
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Abstract

The mixed lubricant prepared by mixing 1-(4-ethylphenyl)-nonane-1,3-dione (0206) and chelate (0206-Fe) in a ratio of 4:6 had better tribological properties than 0206. In this study, it was found that the mixed lubricant prepared by mixing alkane lubricants with 0206-Fe(60%) at a ratio of 2:8 can not only achieve superlubricity, but also reduce the wear scar diameter (WSD) of the friction pairs. The mixed solution prepared by the four polar solutions with 0206-Fe(60%) cannot achieve superlubricity. The results of surface analysis and molecular dynamics (MD) simulation showed that the four polar molecules were preferentially adsorbed on the metal surface, occupying the diketone adsorption sites, and the adsorption layer formed by them cannot produce synergistic lubrication with the chelates.

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Friction
Cite this article:
Du S, Meng Y, Zhang C, et al. Selective synergy of 1,3-diketone for different base oil to promote the realization of oil-based superlubricity. Friction, 2025, https://doi.org/10.26599/FRICT.2025.9440941

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Received: 23 December 2023
Revised: 22 March 2024
Accepted: 29 May 2024
Published: 23 January 2025
© The Author(s) 2025.

This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, http://creativecommons.org/licenses/by/4.0/).

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