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• We developed 2D-printed AgNPs/GF substrate for surface-enhanced Raman spectroscopy.
• The SERS substrate exhibits high SERS activity, good reproducibility and stability.
• The method detected melamine in milk with high sensitivity.
Melamine is one of the most frequently detected adulterants in dairy products. The current study proposes a surface-enhanced Raman spectroscopy (SERS)-based analytical tool for fast and reliable screening of melamine in bovine milk. A hand-held Raman spectrometer was used in conjunction with a substrate composed of silver nanoparticles (AgNPs) that was 2D printed onto glass fiber (GF) filter paper. Under optimized conditions, a sensitive and fingerprint-like signal at 674 cm−1 was obtained. The AgNPs/GF substrate exhibited high sensitivity to melamine in milk down to 1.9498×10−5 mg/mL, which is well below the USA and EU safety limits (2.5×10−3 mg/mL). Remarkably, the proposed technology was also highly reproducible, showing spot-to-spot and block-to-block variations below 3.3% and 4.9% at 674 cm−1 in Raman intensity, respectively. The characteristic peak intensity and concentration of melamine showed an acceptable linear relationship (R2=0.9909) within the range of 0.0001-1 mg/mL. Overall, the method established in this study can provide an efficient and effective method for the quantitative target screening and detection of melamine in dairy products.
C.L. Huang, S.P. Jiang, F.X. Kou, et al., Development of jellyfish-like ZnO@Ag substrate for sensitive SERS detection of melamine in milk, Appl. Surf. Sci. 600 (2022) 154153. https://doi.org/10.1016/j.apsusc.2022.154153.
K. Rovina, S. Siddiquee, A review of recent advances in melamine detection techniques, J. Food Compost. Anal. 43 (2015) 25-38. https://doi.org/10.1016/j.jfca.2015.04.008.
Z.G. Wang, R.P. Chen, Y. Hou, et al., DNA hydrogels combined with microfluidic chips for melamine detection, Anal. Chim. Acta 1228 (2022) 340312. https://doi.org/10.1016/j.aca.2022.340312.
B. Meier, D. Spriano, Modern HPTLC: a perfect tool for quality control of herbals and their preparations, J. AOAC Int. 93 (2010) 1399-409. https://doi.org/10.1093/jaoac/93.5.1399.
X.Y. Cao, F. Shen, M.W. Zhang, et al., Highly sensitive detection of melamine based on fluorescence resonance energy transfer between rhodamine B and gold nanoparticles, Dyes Pigments 111 (2014) 99-107. https://doi.org/10.1016/j.dyepig.2014.06.001.
M.L. Yin, L.F. Zhao, Q. Wei, et al., Rapid colorimetric detection of melamine by H2O2-Au nanoparticles, RSC Adv. 5 (2015) 32897-32901. https://doi.org/10.1039/C5RA02717A.
L.C. Mecker, K.M. Tyner, J.F. Kauffman, et al., Selective melamine detection in multiple sample matrices with a portable Raman instrument using surface enhanced Raman spectroscopy-active gold nanoparticles, Anal. Chim. Acta 733 (2012) 48-55. https://doi.org/10.1016/j.aca.2012.05.001.
M.W. Zhang, H. Ping, X.Y. Cao, et al., Rapid determination of melamine in milk using water-soluble CdTe quantum dots as fluorescence probes, Food Addit. Contam.-Chem. 29 (2012) 333-344. https://doi.org/10.1080/19440049.2011.643459.
A. Fashi, M.R. Yaftian, A. Zamani, Determination of melamine in dairy products using electromembrane-LPME followed by HPLC, Food Chem. 188 (2015) 92-98. https://doi.org/10.1016/j.foodchem.2015.04.132.
J. Lee, E.J. Jeong, J. Kim, Selective and sensitive detection of melamine by intra/inter liposomal interaction of polydiacetylene liposomes, Chem. Comm. 47 (2011) 358-360. https://doi.org/10.1039/c0cc02183k.
Z.C. Yang, C.Q. Ma, J. Gu, et al., Detection of melamine by using carboxyl-functionalized Ag-COF as a novel SERS substrate, Food Chem. 41 (2023) 134078. https://doi.org/10.1016/j.foodchem.2022.134078.
L.I. Ling, G.N. Xiao, Research progress of preparing surface-enhanced Raman scattering active substrates by printing technologies, Spectrosc. Spect. Anal. 39 (2019) 3326-3332. https://doi.org/10.3964/j.issn.1000-0593(2019)11-3326-07.
C. Liu, D. Xu, X. Dong, et al., A review: research progress of SERS-based sensors for agricultural applications, Trends Food Sci. Tech. 128 (2022) 90-101. https://doi.org/10.1016/j.tifs.2022.07.012.
L.P. Xie, H.D.L. Zeng, J.X. Zhu, et al., State of the art in flexible SERS sensors toward label-free and onsite detection: from design to applications, Nano Res. 15 (2022) 4374-4394. https://doi.org/10.1007/s12274-021-4017-4.
F. Stevens, D. Beghuin, M. Delgrange, et al., Raman Fourier transforms imaging: application to melamine and melamine-milk powder mixtures analysis, J. Raman Spectrosc. 53 (2022) 1947-1958. https://doi.org/10.1002/jrs.6415.
B.T. Huy, Q.T. Pham, N.T.T. An, et al., Development of a simple method for sensing melamine by SERS effect of Ag particles, J. Lumin. 188 (2017) 436-440. https://doi.org/10.1016/j.jlumin.2017.05.009.
G.N. Xiao, L. Li, A.M. Yan, et al., Direct detection of melamine in infant formula milk powder solution based on SERS effect of silver film over nanospheres, Spectrochim. Acta Mol. 233 (2019) 117269. https://doi.org/10.1016/j.saa.2019.117269.
M. Verma, T.K. Naqvi, S.K. Tripathi, et al., Paper based low-cost flexible SERS sensor for food adulterant detection, Environ. Technol. Innov. 24 (2021) 102033. https://doi.org/10.1016/j.eti.2021.102033.
N. Singh, H. Siddiqui, S. Kumar, et al., Electrochemical 3D printed silver nanoparticles for pharmaceutical drugs investigations, Mater. Lett. 307 (2022) 130976. https://doi.org/10.1016/j.matlet.2021.130976.
A. Eshkeiti, B.B. Narakathu, A.S.G. Reddy, et al., Detection of heavy metal compounds using a novel inkjet printed surface enhanced Raman spectroscopy (SERS) substrate, Sens. Actuators B Chem. 171/172 (2012) 705-711. https://doi.org/10.1016/j.snb.2012.05.060.
S. Emamian, A. Eshkeiti, B.B. Narakathu, et al., Gravure printed flexible surface enhanced Raman spectroscopy (SERS) substrate for detection of 2,4-dinitrotoluene (DNT) vapor, Sens. Actuators B Chem. 217 (2015) 129-135. https://doi.org/10.1016/j.snb.2014.10.069.
R. Alder, J. Hong, E. Chow, et al., Application of plasma-printed paper-based SERS substrate for cocaine detection, Sensors 21(3) (2021) 810. https://doi.org/10.3390/s21030810.
G.J. Weng, Y. Yang, J. Zhao, et al., Preparation and SERS performance of AuNP/paper strips based on inkjet printing and seed mediated growth: the effect of silver ions, Solid State Commun. 272 (2018) 67-73. https://doi.org/10.1016/j.ssc.2018.01.014.
L.L. Qu, Q.X. Song, Y.T. Li, et al., Fabrication of bimetallic microfluidic surface-enhanced Raman scattering sensors on paper by screen printing, Anal. Chim. Acta 792 (2013) 86-92. https://doi.org/10.1016/j.aca.2013.07.017.
L. Li, S.Y. Yang, J.L. Duan, et al., Fabrication and SERS performance of silver nanoarrays by inkjet printing silver nanoparticles ink on the gratings of compact disc recordable, Spectrochim. Acta A Mol. 225 (2020) 117598. https://doi.org/10.1016/j.saa.2019.117598.
M. Caldara, J.W. Lowdon, J. Royakkers, et al., A molecularly imprinted polymer-based thermal sensor for the selective detection of melamine in milk samples, Foods 11 (2022) 2906. https://doi.org/10.3390/foods11182906.
F.Y. Zeng, W.D. Duan, B. Zhu, et al., Paper-based versatile surface-enhanced Raman spectroscopy chip with smartphone-based Raman analyzer for point-of-care application, Anal. Chem. 91 (2019) 64-70. https://doi.org/10.1021/acs.analchem.8b04441.
J.J. Luo, Z.K. Wang, Y. Li, et al., Durable and flexible Ag-nanowire-embedded PDMS films for the recyclable swabbing detection of malachite green residue in fruits and fingerprints, Sens. Actuators B Chem. 347 (2021) 130602. https://doi.org/10.1016/j.snb.2021.130602.
L.M. Li, W.S. Chin, Rapid and sensitive SERS detection of melamine in milk using Ag nanocube array substrate coupled with multivariate analysis, Food Chem. 357 (2021) 129717. https://doi.org/10.1016/j.foodchem.2021.129717.
L.L. Tay, S. Poirier, A. Ghaemi, et al., Paper-based surface-enhanced Raman spectroscopy sensors for field applications, J. Raman Spectrosc. 52 (2020) 563-572. https://doi.org/10.1002/jrs.6017.
Y. Sun, X.D. Zhai, Y.W. Xu, et al., Facile fabrication of three-dimensional gold nanodendrites decorated by silver nanoparticles as hybrid SERS-active substrate for the detection of food contaminants, Food Contr. 122 (2021) 107772. https://doi.org/10.1016/j.foodcont.2020.107772.
M.L. Mekonnen, W.N. Su, C.H. Chen, et al., Ag@SiO2 nanocubes loaded miniaturized filter paper as hybrid flexible plasmonic SERS substrate for trace melamine detection, Anal. Methods 9 (2017) 6823-6829. https://doi.org/10.1039/C7AY02192E.
R.P. Li, G.H. Yang, J.L. Yang, et al., Determination of melamine in milk using surface plasma effect of aggregated Au@SiO2 nanoparticles by SERS technique, Food Contr. 68 (2016) 14-19. https://doi.org/10.1016/j.foodcont.2016.03.009.
Y.X. Hu, S.L. Feng, F. Gao, et al., Detection of melamine in milk using molecularly imprinted polymers-surface enhanced Raman spectroscopy, Food Chem. 176 (2015) 123-129. https://doi.org/10.1016/j.foodchem.2014.12.051.
Y. Zhou, R. Ding, P. Joshi, et al., Quantitative surface-enhanced Raman measurements with embedded internal reference, Anal. Chim. Acta 874 (2015) 49-53. https://doi.org/10.1016/j.aca.2015.03.016.
Z.Y. Xiong, X.W. Chen, P. Liou, et al., Development of nanofibrillated cellulose coated with gold nanoparticles for measurement of melamine by SERS, Cellulose 24 (2017) 2801-2811. https://doi.org/10.1007/s10570-017-1297-7.
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