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Research Article | Open Access

Anisotropic alumina ceramics with isotropic optical properties

Akio IKESUE()Yan Lin AUNG
World Lab. Co., Ltd., Nagoya 456-8587, Japan
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Abstract

Excellent mechanical and isotropic optical properties are achieved simultaneously from fully dense polycrystalline advanced alumina ceramics with a hexagonal crystal structure, which are optically anisotropic. A small amount (240 ppm) of ZrO2 additive is used to synthesize the transparent alumina ceramics with an average grain size of 0.7 µm, and locally detected optical distortion (birefringence) is extremely minimized, less than 20 nm/pass. Total transmittance (86%) of the alumina ceramics (thickness = 0.3 mm) in ultraviolet (UV) to infrared (IR) regions is similar to that of commercial c-axis sapphire single crystals produced by Czochralski (CZ) method, while the extinction ratio in the visible wavelength area is over 25 dB. Like glass and the c-axis sapphire single crystals, the alumina ceramics can clearly display texts and images on liquid crystal display (LCD) screens. A grain boundary phase of nano-sized Al2O3–ZrO2 composition (amorphous) is formed at the grain boundary of the advanced alumina ceramics, which enhances four-point bending strength and fracture toughness (KIC) simultaneously to 921 MPa and 6.8 MPa·m0.5, respectively, and hence the mechanical properties are superior to those of the sapphire single crystals.

References

[1]
Coble RL. General Electric announces new type of ceramic material. Am Ceram Soc Bull 1959, 38: 507.
[2]
Coble RL. Sintering crystalline solids. II. Experimental test of diffusion models in powder compacts. J Appl Phys 1961, 32: 793799.
[3]
Burke JE. Lucalox alumina: The ceramic that revolutionized outdoor lighting. MRS Bull 1996, 21: 6168.
[4]
Apetz R, van Bruggen MPB. Transparent alumina: A light-scattering model. J Am Ceram Soc 2003, 86: 480486.
[5]
Krell A, Blank P, Ma HW, et al. Transparent sintered corundum with high hardness and strength. J Am Ceram Soc 2003, 86: 1218.
[6]
Penilla EH, Devia-Cruz LF, Duarte MA, et al. Gain in polycrystalline Nd-doped alumina: Leveraging length scales to create a new class of high-energy, short pulse, tunable laser materials. Light Sci Appl 2018, 7: 33.
[7]
Mao XJ, Wang SW, Shimai S, et al. Transparent polycrystalline alumina ceramics with orientated optical axes. J Am Ceram Soc 2008, 91: 34313433.
[8]
Ashikaga T, Kim BN, Kiyono H, et al. Effect of crystallographic orientation on transparency of alumina prepared using magnetic alignment and SPS. J Eur Ceram Soc 2018, 38: 27352741.
[9]
Rayleigh L. XXXIV. On the transmission of light through an atmosphere containing small particles in suspension, and on the origin of the blue of the sky. Lond Edinb Dublin Philos Mag J Sci 1899, 47: 375384.
[10]
Ikesue A, Kinoshita T, Kamata K, et al. Fabrication and optical properties of high-performance polycrystalline Nd:YAG ceramics for solid-state lasers. J Am Ceram Soc 1995, 78: 10331040.
[11]
Ikesue A, Aung YL. Ceramic laser materials. Nat Photonics 2008, 2: 721727.
[12]
Lupei V, Lupei A, Boulon G, et al. Assessment of the distribution of the Yb3+ ions in Sc2O3 ceramics from cooperative absorption and emission. J Alloys Compd 2008, 451: 179181.
[13]
Aung YL, Ikesue A. Development of optical grade (TbxY1−x)3Al5O12 ceramics as Faraday rotator material. J Am Ceram Soc 2017, 100: 40814087.
[14]
Ikesue A, Aung YL, Makikawa S, et al. Polycrystalline (TbxY1−x)2O3 Faraday rotator. Opt Lett 2017, 42: 43994401.
[15]
Aung YL, Ikesue A, Yasuhara R, et al. Optical properties of improved Tb2Hf2O7 pyrochlore ceramics. J Alloys Compd 2020, 822: 153564.
[16]
Ikesue A, Aung YL. Advanced spinel ceramics with highest VUV–vis transparency. J Eur Ceram Soc 2020, 40: 24322438.
[17]
Ikesue A, Aung YL, Lupei V. Ceramic Lasers. Cambridge, UK: Cambridge University Press, 2013: 67.
[18]
Ikesue A, Yoshida K, Yamamoto T, et al. Optical scattering centers in polycrystalline Nd:YAG laser. J Am Ceram Soc 2005, 80: 15171522.
[19]
Goldstein A, Krell A. Transparent ceramics at 50: Progress made and further prospects. J Am Ceram Soc 2016, 99: 31733197.
[20]
Hayashi K, Kobayashi O, Toyoda S, et al. Transmission optical properties of polycrystalline alumina with submicron grains. Mater Trans, JIM 1991, 32: 10241029.
[22]
Von Helden S, Krüger M, Malzbender J. Strength of transparent ceramic composites with spinel. J Mater Sci 2019, 54: 1466614676.
Journal of Advanced Ceramics
Pages 72-81
Cite this article:
IKESUE A, AUNG YL. Anisotropic alumina ceramics with isotropic optical properties. Journal of Advanced Ceramics, 2023, 12(1): 72-81. https://doi.org/10.26599/JAC.2023.9220667
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