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Research Article | Open Access

(K,Na)NbO3-based lead-free ceramics with enhanced temperature-stable piezoelectricity and efficient red luminescence

Qing Liua,†( ), Er Pana,†, Fucai Liua( ), Jing-Feng Lib
School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 610054, China
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

† Qing Liu and Er Pan contributed equally to this work.

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Graphical Abstract

Abstract

There has been a surge of research interest in the promising lead-free potassium−sodium niobate (KNN)-based ceramics, applications of which could be significantly promoted by improving thermal stability of piezoelectricity. Besides, endowing the KNN-based ceramics with photoluminescence property by rare-earth-ion doping can make them more completive lead-free counterparts in potential applications such as novel multifunctional sensing devices. Herein, a novel KNN-based ceramic material doped with Eu was elaborately designed to simultaneously obtain enhanced temperature-stable piezoelectricity and good luminescence property. By the introduction of diffused phase transition and the modulation of unit cell distortion, a large piezoelectric strain coefficient (d*33) with a small variation (590±59 pm/V) over a wide temperature range (from room temperature to 110 ℃) was realized. The optimal composition also exhibited a considerable piezoelectric coefficient (d33) with small fluctuation (330±33 pC/N) from 20 to 80 ℃. In addition to the enhanced temperature-stable piezoelectricity, the luminescence of these ceramics was slightly enhanced with the elevation of BaZrO3 (BZ) doping contents, which could be attributed to the increased compositional disorder and the decreased unit cell distortion of the matrix material. Moreover, an optical characteristic was more prominent at ultra-low temperatures. This work unprecedentedly provides a novel paradigm for the design of multifunctional KNN-based ceramics with enhanced temperature-stable piezoelectricity and good luminescence property, revealing the great potential of the rare-earth-element-doped KNN material for future applications in the novel multifunctional devices.

Keywords

piezoelectricthermal stabilityrare-earthlead-freepotassium−sodium niobate (KNN)

References

[1]
Jaffe B, Cook WR, Jaffe H. Piezoelectric Ceramics. London, UK: Academic Press, 1971.
Crossref
[2]
Gao XY, Cheng ZX, Chen ZB, et al. The mechanism for the enhanced piezoelectricity in multi-elements doped (K,Na)NbO3 ceramics. Nat Commun 2021, 12: 881.
Crossref Google Scholar
[3]
Wang XP, Wu JG, Xiao DQ, et al. Giant piezoelectricity in potassium−sodium niobate lead-free ceramics. J Am Chem Soc 2014, 136: 2905–2910.
Crossref Google Scholar
[4]
Zheng T, Wu HJ, Yuan Y, et al. The structural origin of enhanced piezoelectric performance and stability in lead free ceramics. Energy Environ Sci 2017, 10: 528–537.
Crossref Google Scholar
[5]
Rödel J, Li JF. Lead-free piezoceramics: Status and perspectives. MRS Bull 2018, 43: 576–580.
Crossref Google Scholar
[6]
Zheng T, Yu YG, Lei HB, et al. Compositionally graded KNN-based multilayer composite with excellent piezoelectric temperature stability. Adv Mater 2022, 34: 2109175.
Crossref Google Scholar
[7]
Zhang MH, Zhang QH, Yu TT, et al. Enhanced electric-field-induced strains in (K,Na)NbO3 piezoelectrics from heterogeneous structures. Mater Today 2021, 46: 44–53.
Crossref Google Scholar
[8]
Li RC, Sun XX, Lv X, et al. Manipulating temperature stability in KNN-based ceramics via defect design. Acta Mater 2021, 218: 117229.
Crossref Google Scholar
[9]
Liu Q, Zhang YC, Gao J, et al. Practical high-performance lead-free piezoelectrics: Structural flexibility beyond utilizing multiphase coexistence. Natl Sci Rev 2020, 7: 355–365.
Crossref Google Scholar
[10]
Cen ZY, Dong ZH, Xu Z, et al. Improving fatigue properties, temperature stability and piezoelectric properties of KNN-based ceramics via sintering in reducing atmosphere. J Eur Ceram Soc 2021, 41: 4462–4472.
Crossref Google Scholar
[11]
Xu K, Li J, Lv X, et al. Superior piezoelectric properties in potassium−sodium niobate lead-free ceramics. Adv Mater 2016, 28: 8519−8523.
Crossref Google Scholar
[12]
Lv X, Wu JG, Zhang XX. A new concept to enhance piezoelectricity and temperature stability in KNN ceramics. Chem Eng J 2020, 402: 126215.
Crossref Google Scholar
[13]
Cen ZY, Bian SS, Xu Z, et al. Simultaneously improving piezoelectric properties and temperature stability of Na0.5K0.5NbO3 (KNN)-based ceramics sintered in reducing atmosphere. J Adv Ceram 2021, 10: 820–831.
Crossref Google Scholar
[14]
Wang T, Wu C, Xing J, et al. Enhanced piezoelectricity and temperature stability in LaFeO3-modified KNN-based lead-free ceramics. J Am Ceram Soc 2019, 102: 6126–6136.
Crossref Google Scholar
[15]
Yu YG, Shi XM, Xue HY, et al. Electric-field-insensitive temperature stability of strain in KNN multilayer composite ceramics. ACS Appl Mater Inter 2022, 14: 26949–26957.
Crossref Google Scholar
[16]
Song AZ, Liu YX, Feng TY, et al. Simultaneous enhancement of piezoelectricity and temperature stability in KNN-based lead-free ceramics via layered distribution of dopants. Adv Funct Mater 2022, 32: 2204385.
Crossref Google Scholar
[17]
Li P, Zhai JW, Shen B, et al. Ultrahigh piezoelectric properties in textured (K,Na)NbO3-based lead-free ceramics. Adv Mater 2018, 30: 1705171.
Crossref Google Scholar
[18]
Liu Q, Li JF, Zhao L, et al. Niobate-based lead-free piezoceramics: A diffused phase transition boundary leading to temperature-insensitive high piezoelectric voltage coefficients. J Mater Chem C 2018, 6: 1116–1125.
Crossref Google Scholar
[19]
Huang YL, Zhao CL, Wu B, et al. Diffused and successive phase transitions of (K,Na)NbO3-based ceramics with high strain and temperature insensitivity. J Am Ceram Soc 2019, 102: 2648–2657.
Crossref Google Scholar
[20]
Liu WP, Wang HL, Hu WD, et al. Understanding the origin of the high piezoelectric performance of KNN-based ceramics from the perspective of lattice distortion. Ceram Int 2022, 48: 9731–9738.
Crossref Google Scholar
[21]
Damjanovic D. Comments on origins of enhanced piezoelectric properties in ferroelectrics. IEEE T Ultrason Ferr 2009, 56: 1574–1585.
Crossref Google Scholar
[22]
Lin JF, Zhai JW, Wu X, et al. Simultaneously improved transparency, photochromic contrast and Curie temperature via rare-earth ion modification in KNN-based ceramics. Inorg Chem Front 2021, 8: 2027–2035.
Crossref Google Scholar
[23]
Zhang QW, Chen K, Wang LL, et al. A highly efficient, orange light-emitting (K0.5Na0.5)NbO3:Sm3+/Zr4+ lead-free piezoelectric material with superior water resistance behavior. J Mater Chem C 2015, 3: 5275–5284.
Crossref Google Scholar
[24]
Yamamoto Y, Harada S, Yamamoto D, et al. Printed multifunctional flexible device with an integrated motion sensor for health care monitoring. Sci Adv 2016, 2: e1601473.
Crossref Google Scholar
[25]
Lin C, Wang HJ, Wang P, et al. Smart white lighting and multi-mode optical modulations via photochromism in Dy-doped KNN-based transparent ceramics. J Am Ceram Soc 2021, 104: 903–916.
Crossref Google Scholar
[26]
Liu Y, Bai GX, Lyu YX, et al. Ultrabroadband tuning and fine structure of emission spectra in lanthanide Er-doped ZnSe nanosheets for display and temperature sensing. ACS Nano 2020, 14: 16003–16012.
Crossref Google Scholar
[27]
Wu J, Wu Z, Qian WQ, et al. Electric-field-treatment-induced enhancement of photoluminescence in Er3+-doped (Ba0.95Sr0.05)(Zr0.1Ti0.9)O3 piezoelectric ceramic. Mater Lett 2016, 184: 131–133.
Crossref Google Scholar
[28]
Cui RY, Tang K, Zhu DC, et al. Sm3+-doped KNNS ferroelectric ceramics with enhanced photoluminescence by polarization-field-modulation. J Mater Sci: Mater Electron 2020, 31: 480–487.
Crossref Google Scholar
[29]
Zhai YZ, Du J, Chen C, et al. The photoluminescence and piezoelectric properties of Eu2O3 doped KNN-based ceramics. J Alloys Compd 2020, 829: 154518.
Crossref Google Scholar
[30]
Liu Q, Zhang YC, Gao J, et al. High-performance lead-free piezoelectrics with local structural heterogeneity. Energy Environ Sci 2018, 11: 3531–3539.
Crossref Google Scholar
[31]
Shvartsman VV, Kleemann W, Dec J, et al. Diffuse phase transition in BaTi1−xSnxO3 ceramics: An intermediate state between ferroelectric and relaxor behavior. J Appl Phys 2006, 99: 124111.
Crossref Google Scholar
[32]
Liu C, Xiao DQ, Huang T, et al. Composition induced rhombohedral−tetragonal phase boundary in BaZrO3 modified (K0.445Na0.50Li0.055)NbO3 lead-free ceramics. Mater Lett 2014, 120: 275–278.
Crossref Google Scholar
[33]
Liu Q, Zhu FY, Zhao L, et al. Further enhancing piezoelectric properties by adding MnO2 in AgSbO3-modified (Li,K,Na)(Nb,Ta)O3 lead-free piezoceramics. J Am Ceram Soc 2016, 99: 3670–3676.
Crossref Google Scholar
[34]
Liu Q, Zhang YC, Zhao L, et al. Simultaneous enhancement of piezoelectricity and temperature stability in (K,Na)NbO3-based lead-free piezoceramics by incorporating perovskite zirconates. J Mater Chem C 2018, 6: 10618–10627.
Crossref Google Scholar
[35]
Duong TA, Erkinov F, Aripova M, et al. Ferroelectric-to-relaxor crossover in KNN-based lead-free piezoceramics. Ceram Int 2021, 47: 4925–4932.
Crossref Google Scholar
[36]
Weyland F, Acosta M, Koruza J, et al. Criticality: Concept to enhance the piezoelectric and electrocaloric properties of ferroelectrics. Adv Funct Mater 2016, 26: 7326–7333.
Crossref Google Scholar
[37]
Saito Y, Takao H, Tani T, et al. Lead-free piezoceramics. Nature 2004, 432: 84–87.
Crossref Google Scholar
[38]
Damjanovic D, Demartin M. Contribution of the irreversible displacement of domain walls to the piezoelectric effect in barium titanate and lead zirconate titanate ceramics. J Phys Condens Matter 1997, 9: 4943–4953.
Crossref Google Scholar
[39]
Lin DM, Kwok KW, Chan HLW. Piezoelectric and ferroelectric properties of KxNa1−xNbO3 lead-free ceramics with MnO2 and CuO doping. J Alloys Compd 2008, 461: 273–278.
Crossref Google Scholar
[40]
Zheng LM, Yang LY, Li YR, et al. Origin of improvement in mechanical quality factor in acceptor-doped relaxor-based ferroelectric single crystals. Phys Rev Appl 2018, 9: 064028.
Crossref Google Scholar
[41]
Jing YJ, Zheng LM, Liu FY, et al. A large and anisotropic enhancement of the mechanical quality factor in ternary relaxor-PbTiO3 single crystals. Appl Phys Lett 2021, 118: 182902.
Crossref Google Scholar
[42]
Bennett J, Shrout TR, Zhang SJ, et al. Temperature dependence of the intrinsic and extrinsic contributions in BiFeO3−(K0.5Bi0.5)TiO3−PbTiO3 piezoelectric ceramics. J Appl Phys 2014, 116: 094102.
Google Scholar
[43]
Sluka T, Tagantsev AK, Damjanovic D, et al. Enhanced electromechanical response of ferroelectrics due to charged domain walls. Nat Commun 2012, 3: 748.
Crossref Google Scholar
[44]
Li F, Lin DB, Chen ZB, et al. Ultrahigh piezoelectricity in ferroelectric ceramics by design. Nat Mater 2018, 17: 349–354.
Crossref Google Scholar
[45]
Li F, Zhang SJ, Yang TN, et al. The origin of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution crystals. Nat Commun 2016, 7: 13807.
Crossref Google Scholar
[46]
Acosta M, Schmitt LA, Molina-Luna L, et al. Core-shell lead-free piezoelectric ceramics: Current status and advanced characterization of the Bi1/2Na1/2TiO3−SrTiO3 system. J Am Ceram Soc 2015, 98: 3405–3422.
Crossref Google Scholar
[47]
Li W, Hao JG, Li W, et al. Electrical properties and luminescence properties of 0.96(K0.48Na0.52)(Nb0.95Sb0.05)− 0.04Bi0.5(Na0.82K0.18)0.5ZrO3−xSm lead-free ceramics. J Adv Ceram 2020, 9: 72–82.
Crossref Google Scholar
[48]
Li W, Wang D, Li XF, et al. Optical temperature sensing properties and thermoluminescence behavior in Er-modified potassium sodium niobate-based multifunctional ferroelectric ceramics. J Mater Chem C 2022, 10: 11891–11902.
Crossref Google Scholar
[49]
Li W, Hao JG, Fu P, et al. High-temperature and long-term stability of Ho-doped potassium sodium niobate-based multifunctional ceramics. Ceram Int 2021, 47: 13391–13401.
Crossref Google Scholar
[50]
Wang JJ, He B, Du Y, et al. Improved electrical properties and luminescence properties of lead-free KNN ceramics via phase transition. J Mater Sci-Mater El 2021, 32: 28819–28829.
Crossref Google Scholar
[51]
Wang K, Yao FZ, Jo W, et al. Temperature-insensitive (K,Na)NbO3-based lead-free piezoactuator ceramics. Adv Funct Mater 2013, 23: 4079–4086.
Crossref Google Scholar
[52]
He K, Zhang LB, Liu Y, et al. Lanthanide ions doped nonhygroscopic La2Mo3O12 microcrystals based on multimode luminescence for optical thermometry. J Alloys Compd 2022, 890: 161918.
Crossref Google Scholar
[53]
Zhao YJ, Bai GX, Huang YQ, et al. Stimuli responsive lanthanide ions doped layered piezophotonic microcrystals for optical multifunctional sensing applications. Nano Energy 2021, 87: 106177.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 12 Issue 2,
February 2023
Pages 373-385
DOI: 10.26599/JAC.2023.9220690
Cite this article:
Liu Q, Pan E, Liu F, et al. (K,Na)NbO3-based lead-free ceramics with enhanced temperature-stable piezoelectricity and efficient red luminescence. Journal of Advanced Ceramics, 2023, 12(2): 373-385. https://doi.org/10.26599/JAC.2023.9220690

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Received: 06 July 2022
Revised: 15 October 2022
Accepted: 31 October 2022
Published: 17 January 2023
© The Author(s) 2022.

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