AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (2.4 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Multi-phase (Zr,Ti,Cr)B2 solid solutions: Preparation, multi-scale microstructure, and local properties

Laura Silvestronia( ), Nicola Gillib, Alex Sangiorgia, Alessandro Corozzia, Suzana Filipovićc, Nina Obradovićc, Laia Ortiz-Membradod, Emilio Jiménez-Piquéd, William G. Fahrenholtze
CNR-ISSMC, Institute of Science, Technology and Sustainability for Ceramics (former ISTEC), Via Granarolo 64, 48018 Faenza, Italy
CNR-IMM, Institute for Microelectronics and Microsystems, Via Gobetti 101, 40129 Bologna, Italy
Institute of Technical Sciences of SASA, Knez Mihailova 35/IV, 11000 Belgrade, Serbia
Department of Materials Science and Engineering, EEBE, Univ. Politècnica de Catalunya-BarcelonaTECH. Avda. Eduard Maristany 16, 08019 Barcelona, Spain
Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65049, USA
Show Author Information

Graphical Abstract

Abstract

Multi-phase ceramics based on ZrB2, TiB2 and doped with CrB2 and SiC were prepared by powder metallurgy and hot pressing to explore the possibility of obtaining multi-scale microstructures by super-saturation of complex (Zr,Ti,Cr)B2 solid solutions. Core–shell structures formed in TiB2 grains, whereas ZrB2 appeared to form a homogeneous solid solution with the other metals. Precipitation of nano-inclusions within both micron-sized borides was assessed by transmission electron microscopy and thermodynamics elucidated the preferential formation of boride inclusions due to the specific sintering atmosphere. In addition, atomic size factors explicated the precipitation of CrB2 nano-particles into ZrB2-rich grains and of ZrB2 nano-particles into TiB2-rich grains. The hardness of the constituent phases measured by nanoindentation ranged from 36 to 43 GPa.

Keywords

boridecore–shellsolid solutionnanoindentationsintering

References

[1]
Fahrenholtz WG, Wuchina EJ, Lee WE, et al. Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2014.
Crossref
[2]
Guo SQ. Densification of ZrB2-based composites and their mechanical and physical properties: A review. J Eur Ceram Soc 2009, 29: 995–1011.
Crossref Google Scholar
[3]
Golla BR, Bhandari T, Mukhopadhyay A, et al. Titanium diboride. In: Ultra-High Temperature Ceramics. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2014: 316–360.
Crossref
[4]
Wuchina E, Opila E, Opeka M, et al. UHTCs: Ultra-high temperature ceramic materials for extreme environment applications. Electrochem Soc Interface 2007, 16: 30–36.
Crossref Google Scholar
[5]
Savino R, Mungiguerra S, Di Martino GD. Testing ultra-high-temperature ceramics for thermal protection and rocket applications. Adv Appl Ceram 2018, 117: s9–s18.
Crossref Google Scholar
[6]
Ping H, Wang GL, Zhi W. Oxidation mechanism and resistance of ZrB2–SiC composites. Corros Sci 2009, 51: 2724–2732.
Crossref Google Scholar
[7]
Fahrenholtz WG. Thermodynamic analysis of ZrB2–SiC oxidation: Formation of a SiC-depleted region. J Am Ceram Soc 2007, 90: 143–148.
Crossref Google Scholar
[8]
Feng L, Fahrenholtz WG, Hilmas GE, et al. Superhard single-phase (Ti,Cr)B2 ceramics. J Am Ceram Soc 2022, 105: 5032–5038.
Crossref Google Scholar
[9]
Feng L, Monteverde F, Fahrenholtz WG, et al. Superhard high-entropy AlB2-type diboride ceramics. Scripta Mater 2021, 199: 113855.
Crossref Google Scholar
[10]
Silvestroni L, Kleebe HJ, Fahrenholtz WG, et al. Super-strong materials for temperatures exceeding 2000 ℃. Sci Rep 2017, 7: 40730.
Crossref Google Scholar
[11]
Silvestroni L, Gilli N, Migliori A, et al. A simple route to fabricate strong boride hierarchical composites for use at ultra-high temperature. Compos B Eng 2020, 183: 107618.
Crossref Google Scholar
[12]
Gilli N, Watts J, Fahrenholtz WG, et al. Design of ultra-high temperature ceramic nano-composites from multi-scale length microstructure approach. Compos B Eng 2021, 226: 109344.
Crossref Google Scholar
[13]
Silvestroni L, Failla S, Vinokurov V, et al. Core–shell structure: An effective feature for strengthening ZrB2 ceramics. Scripta Mater 2019, 160: 1–4.
Crossref Google Scholar
[14]
Silvestroni L, Stricker K, Sciti D, et al. Understanding the oxidation behavior of a ZrB2–MoSi2 composite at ultra-high temperatures. Acta Mater 2018, 151: 216–228.
Crossref Google Scholar
[15]
Silvestroni L, Kleebe HJ. Critical oxidation behavior of Ta-containing ZrB2 composites in the 1500–1650 ℃ temperature range. J Eur Ceram Soc 2017, 37: 1899–1908.
Crossref Google Scholar
[16]
Silvestroni L, Sciti D, Monteverde F, et al. Microstructure evolution of a W-doped ZrB2 ceramic upon high-temperature oxidation. J Am Ceram Soc 2017, 100: 1760–1772.
Crossref Google Scholar
[17]
Silvestroni L, Mungiguerra S, Sciti D, et al. Effect of hypersonic flow chemical composition on the oxidation behavior of a super-strong UHTC. Corros Sci 2019, 159: 108125.
Crossref Google Scholar
[18]
Bannykh D, Utkin A, Baklanova N. The peculiarities in oxidation behavior of the ZrB2–SiC ceramics with chromium additive. Int J Refract Met Hard Mater 2019, 84: 105023.
Crossref Google Scholar
[19]
Grigoriev O, Neshpor I, Vedel D, et al. Influence of chromium diboride on the oxidation resistance of ZrB2–MoSi2 and ZrB2–SiC ceramics. J Eur Ceram Soc 2021, 41: 2207–2214.
Crossref Google Scholar
[20]
Murthy TSRC, Sonber JK, Subramanian C, et al. Effect of CrB2 addition on densification, properties and oxidation resistance of TiB2. Int J Refract Met Hard Mater 2009, 27: 976–984.
Crossref Google Scholar
[21]
Harrington GJK, Hilmas GE, Fahrenholtz WG. Effect of carbon and oxygen on the densification and microstructure of hot pressed zirconium diboride. J Am Ceram Soc 2013, 96: 3622–3630.
Crossref Google Scholar
[22]
Oliver WC, Pharr GM. An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J Mater Res 1992, 7: 1564–1583.
Crossref Google Scholar
[23]
Spoor PS, Maynard JD, Pan MJ, et al. Elastic constants and crystal anisotropy of titanium diboride. Appl Phys Lett 1997, 70: 1959–1961.
Crossref Google Scholar
[24]
Pavlikov VN, Yurchenko VA, Tresvyatskii SG. Fig. 06456—System B2O3–TiO2. Russ J Inorg Chem 1976, 21: 233–236.
Google Scholar
[25]
Munro RG. Material properties of titanium diboride. J Res Natl Inst Stand Technol 2000, 105: 709–720.
Crossref Google Scholar
[26]
Okamoto NL, Kusakari M, Tanaka K, et al. Anisotropic elastic constants and thermal expansivities in monocrystal CrB2, TiB2, and ZrB2. Acta Mater 2010, 58: 76–84.
Crossref Google Scholar
[27]
Smith SMI, Feng L, Fahrenholtz WG, et al. Thermal and electrical properties of spark plasma sintered (Ti,Cr)B2 ceramics. J Am Ceram Soc 2023, 106: 632–638.
Crossref Google Scholar
[28]
Sciti D, Silvestroni L, Medri V, et al. Sintering and densification mechanisms of ultra-high temperature ceramics. In: Ultra-High Temperature Ceramics. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2014: 112–143.
Crossref
[29]
Fahrenholtz WG, Hilmas GE, Zhang SC, et al. Pressureless sintering of zirconium diboride: Particle size and additive effects. J Am Ceram Soc 2008, 91: 1398–1404.
Crossref Google Scholar
[30]
Villars P, Prince A, Okamoto H. ASM International, Ohio.
[31]
Post B, Glaser FW, Moskowitz D. Transition metal diborides. Acta Metall 1954, 2: 20–25.
Crossref Google Scholar
[32]
Otani S, Aizawa T, Kieda N. Solid solution ranges of zirconium diboride with other refractory diborides: HfB2, TiB2, TaB2, NbB2, VB2 and CrB2. J Alloys Compd 2009, 475: 273–275.
Crossref Google Scholar
[33]
Fotsing ER. Phase transformation kinetics and microstructure of carbide and diboride based ceramics. Dissertation. Technische Universität Clausthal, 2005.
[34]
Telle R. The quasi ternary system TiB2–CrB2–WB2 between 1500 and 1900 ℃ and the related quasi binary subsystems. J Eur Ceram Soc 2019, 39: 3677–3683.
Crossref Google Scholar
[35]
Telle R. A new ternary phase in the system TiB2–CrB2–WB2. Solid State Sci 2020, 101: 106120.
Crossref Google Scholar
[36]
Wang YJ, Yan QZ. Microstructure and strengthening mechanism of grain boundary strengthened W–ZrB2 alloy. J Mater Res Technol 2020, 9: 4007–4015.
Crossref Google Scholar
[37]
Silvestroni L, Failla S, Gilli N, et al. Disclosing small scale length properties in core–shell structured B4C–TiB2 composites. Mater Des 2021, 197: 109204.
Crossref Google Scholar
[38]
Roa JJ, Jimenez-Pique E, Verge C, et al. Intrinsic hardness of constitutive phases in WC–Co composites: Nanoindentation testing, statistical analysis, WC crystal orientation effects and flow stress for the constrained metallic binder. J Eur Ceram Soc 2015, 35: 3419–3425.
Crossref Google Scholar
[39]
Roa JJ, Sudharshan Phani P, Oliver WC, et al. Mapping of mechanical properties at microstructural length scale in WC–Co cemented carbides: Assessment of hardness and elastic modulus by means of high speed massive nanoindentation and statistical analysis. Int J Refract Met Hard Mater 2018, 75: 211–217.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 12 Issue 2,
February 2023
Pages 414-431
DOI: 10.26599/JAC.2023.9220695
Cite this article:
Silvestroni L, Gilli N, Sangiorgi A, et al. Multi-phase (Zr,Ti,Cr)B2 solid solutions: Preparation, multi-scale microstructure, and local properties. Journal of Advanced Ceramics, 2023, 12(2): 414-431. https://doi.org/10.26599/JAC.2023.9220695

2386

Views

478

Downloads

13

Crossref

11

Web of Science

12

Scopus

0

CSCD

Altmetrics
Received: 23 August 2022
Revised: 10 November 2022
Accepted: 10 November 2022
Published: 11 January 2023
© The Author(s) 2022.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return