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Research Article | Open Access

Correlation between multi-factor phase diagrams and complex electrocaloric behaviors in PNZST antiferroelectric ceramic system

Junjie Lia,bRuowei YinaJianting LicXiaopo SuaYanjing SuaLijie QiaoaYang Baia( )
Beijing Advanced Innovation Center for Materials Genome Engineering, Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
Sichuan Province Key Laboratory of Information Materials and Devices Application, College of Optoelectronic Engineering, Chengdu University of Information Technology, Chengdu 610225, China
Faculty of Mechanical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China
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Abstract

Ferroelectric (FE) phase transition with a large polarization change benefits to generate large electrocaloric (EC) effect for solid-sate and zero-carbon cooling application. However, most EC studies only focus on the single-physical factor associated phase transition. Herein, we initiated a comprehensive discussion on phase transition in Pb0.99Nb0.02[(Zr0.6Sn0.4)1−xTix]0.98O3 (PNZST100x) antiferroelectric (AFE) ceramic system under the joint action of multi-physical factors, including composition, temperature, and electric field. Due to low energy barrier and enhanced zero-field entropy, the multi-phase coexistence point (x = 0.12) in the composition–temperature phase diagram yields a large positive EC peak of maximum temperature change (ΔTmax) = 2.44 K (at 40 kV/cm). Moreover, the electric field–temperature phase diagrams for four representative ceramics provide a more explicit guidance for EC evolution behavior. Besides the positive EC peaks near various phase transition temperatures, giant positive EC effects are also brought out by the electric field-induced phase transition from tetragonal AFE (AFET) to low-temperature rhombohedral FE (FER), which is reflected by a positive-slope boundary in the electric field–temperature phase diagram, while significant negative EC responses are generated by the phase transition from AFET to high-temperature multi-cell cubic paraelectric (PEMCC) with a negative-slope phase boundary. This work emphasizes the importance of phase diagram covering multi-physical factors for high-performance EC material design.

References

[1]
Grocholski B. Cooling in a warming world. Science 2020, 370: 776–777.
[2]
Shi JY, Han DL, Li ZC, et al. Electrocaloric cooling materials and devices for zero-global-warming-potential, high-efficiency refrigeration. Joule 2019, 3: 1200–1225.
[3]
Ma RJ, Zhang ZY, Tong K, et al. Highly efficient electrocaloric cooling with electrostatic actuation. Science 2017, 357: 1130–1134.
[4]
Torelló A, Lheritier P, Usui T, et al. Giant temperature span in electrocaloric regenerator. Science 2020, 370: 125–129.
[5]
Wang YD, Zhang ZY, Usui T, et al. A high-performance solid-state electrocaloric cooling system. Science 2020, 370: 129–133.
[6]
Meng Y, Pu JH, Pei QB. Electrocaloric cooling over high device temperature span. Joule 2021, 5: 780–793.
[7]
Nair B, Usui T, Crossley S, et al. Large electrocaloric effects in oxide multilayer capacitors over a wide temperature range. Nature 2019, 575: 468–472.
[8]
Qian XS, Han DL, Zheng LR, et al. High-entropy polymer produces a giant electrocaloric effect at low fields. Nature 2021, 600: 664–669.
[9]
Hanani Z, Merselmiz S, Danine A, et al. Enhanced dielectric and electrocaloric properties in lead-free rod-like BCZT ceramics. J Adv Ceram 2020, 9: 210–219.
[10]
Niu X, Jian XD, Chen XY, et al. Enhanced electrocaloric effect at room temperature in Mn2+ doped lead-free (BaSr)TiO3 ceramics via a direct measurement. J Adv Ceram 2021, 10: 482–492.
[11]
Bai Y, Ding K, Zheng GP, et al. The electrocaloric effect around the orthorhombic–tetragonal first-order phase transition in BaTiO3. AIP Adv 2012, 2: 022162.
[12]
Moya X, Stern-Taulats E, Crossley S, et al. Giant electrocaloric strength in single-crystal BaTiO3. Adv Mater 2013, 25: 1360–1365.
[13]
Han F, Bai Y, Qiao LJ, et al. A systematic modification of the large electrocaloric effect within a broad temperature range in rare-earth doped BaTiO3 ceramics. J Mater Chem C 2016, 4: 1842–1849.
[14]
Li F, Li K, Long MS, et al. Ferroelectric-relaxor crossover induce large electrocaloric effect with ultrawide temperature span in NaNbO3-based lead-free ceramics. Appl Phys Lett 2021, 118: 043902.
[15]
Dey K, Indra A, Chatterjee A, et al. Chemical-pressure-driven orthorhombic distortion and significant enhancement of ferroelectric polarization in Ca1−xLaxBaCo4O7 (x ≤ 0.05). Phys Rev B 2017, 96: 184428.
[16]
Huang YL, Zhao CL, Zhong SZ, et al. Highly tunable multifunctional BaTiO3-based ferroelectrics via site selective doping strategy. Acta Mater 2021, 209: 116792.
[17]
Li JN, Zhang DW, Qin SQ, et al. Large room-temperature electrocaloric effect in lead-free BaHfxTi1−xO3 ceramics under low electric field. Acta Mater 2016, 115: 58–67.
[18]
Qian XS, Ye HJ, Zhang YT, et al. Giant electrocaloric response over a broad temperature range in modified BaTiO3 ceramics. Adv Funct Mater 2014, 24: 1300–1305.
[19]
Pramanick A, Dmowski W, Egami T, et al. Stabilization of polar nanoregions in Pb-free ferroelectrics. Phys Rev Lett 2018, 120: 207603.
[20]
Luo ZD, Zhang DW, Liu Y, et al. Enhanced electrocaloric effect in lead-free BaTi1−xSnxO3 ceramics near room temperature. Appl Phys Lett 2014, 105: 102904.
[21]
Sanlialp M, Luo ZD, Shvartsman VV, et al. Direct measurement of electrocaloric effect in lead-free Ba(SnxTi1−x)O3 ceramics. Appl Phys Lett 2017, 111: 173903.
[22]
Bai Y, Wei D, Qiao LJ. Control multiple electrocaloric effect peak in Pb(Mg1/3Nb2/3)O3–PbTiO3 by phase composition and crystal orientation. Appl Phys Lett 2015, 107: 192904.
[23]
Li JT, Yin RW, Su XP, et al. Complex phase transitions and associated electrocaloric effects in different oriented PMN–30PT single crystals under multi-fields of electric field and temperature. Acta Mater 2020, 182: 250–256.
[24]
Xu ZP, Fan ZM, Liu XM, et al. Impact of phase transition sequence on the electrocaloric effect in Pb(Nb,Zr,Sn,Ti)O3 ceramics. Appl Phys Lett 2017, 110: 082901.
[25]
Li JJ, Li JT, Wu HH, et al. Giant electrocaloric effect and ultrahigh refrigeration efficiency in antiferroelectric ceramics by morphotropic phase boundary design. ACS Appl Mater Inter 2020, 12: 45005–45014.
[26]
Novak N, Weyland F, Patel S, et al. Interplay of conventional with inverse electrocaloric response in (Pb,Nb)(Zr,Sn,Ti)O3 antiferroelectric materials. Phys Rev B 2018, 97: 094113.
[27]
Li JJ, Su XP, Wu HH, et al. Electric hysteresis and validity of indirect electrocaloric characterization in antiferroelectric ceramics. Scripta Mater 2022, 216: 114763.
[28]
Pan WY, Zhang QM, Bhalla A, et al. Field-forced antiferroelectric-to-ferroelectric switching in modified lead zirconate titanate stannate ceramics. J Am Ceram Soc 1989, 72: 571–578.
[29]
Li JJ, Yin RW, Su XP, et al. Composition-induced non-ergodic–ergodic transition and electrocaloric evolution in Pb1−1.5xLaxZr0.8Ti0.2O3 relaxor ferroelectric ceramics. IET Nanodielectrics 2019, 2: 123–128.
[30]
Li JJ, Li JT, Qin SQ, et al. Effects of long- and short-range ferroelectric order on the electrocaloric effect in relaxor ferroelectric ceramics. Phys Rev Appl 2019, 11: 044032.
[31]
Liu H, Fan LL, Sun SD, et al. Electric-field-induced structure and domain texture evolution in PbZrO3-based antiferroelectric by in-situ high-energy synchrotron X-ray diffraction. Acta Mater 2020, 184: 41–49.
[32]
Zhuo FP, Li Q, Gao JH, et al. Structural phase transition, depolarization and enhanced pyroelectric properties of (Pb1−1.5xLax)(Zr0.66Sn0.23Ti0.11)O3 solid solution. J Mater Chem C 2016, 4: 7110–7118.
[33]
Mohapatra P, Fan ZM, Cui J, et al. Relaxor antiferroelectric ceramics with ultrahigh efficiency for energy storage applications. J Eur Ceram Soc 2019, 39: 4735–4742.
[34]
Zhao L, Liu Q, Gao J, et al. Lead-free antiferroelectric silver niobate tantalate with high energy storage performance. Adv Mater 2017, 29: 1701824.
[35]
Zhuo FP, Li Q, Li YY, et al. Field induced phase transitions and energy harvesting performance of (Pb,La)(Zr,Sn,Ti)O3 single crystal. J Appl Phys 2017, 121: 064104.
[36]
Ciuchi IV, Chung CC, Fancher CM, et al. Field-induced antiferroelectric to ferroelectric transitions in (Pb1−xLax) (Zr0.90Ti0.10)1−x/4O3 investigated by in situ X-ray diffraction. J Eur Ceram Soc 2017, 37: 4631–4636.
[37]
Zhuo FP, Damjanovic D, Li Q, et al. Giant shape memory and domain memory effects in antiferroelectric single crystals. Mater Horiz 2019, 6: 1699–1706.
[38]
Young SE, Guo HZ, Ma C, et al. Thermal analysis of phase transitions in perovskite electroceramics. J Therm Anal Calorim 2014, 115: 587–593.
[39]
Wang HS, Liu YC, Yang TQ, et al. Ultrahigh energy-storage density in antiferroelectric ceramics with field-induced multiphase transitions. Adv Funct Mater 2019, 29: 1807321.
[40]
Liu YC, Liu SP, Yang TQ, et al. Achieving high energy storage density of PLZS antiferroelectric within a wide range of components. J Mater Sci 2021, 56: 6073–6082.
[41]
Li JJ, Li ZH, He JJ, et al. Near-room-temperature large electrocaloric effect in barium titanate single crystal based on the electric field–temperature phase diagram. Phys Status Solidi-RRL 2021, 15: 2100251.
[42]
Zhang HZ, Zhou J, Shen J, et al. Electric field–temperature phase diagram of Bi1/2(Na0.8K0.2)1/2TiO3 relaxor ferroelectrics with Fe doping. J Appl Phys 2019, 126: 064102.
[43]
Vales-Castro P, Faye R, Vellvehi M, et al. Origin of large negative electrocaloric effect in antiferroelectric PbZrO3. Phys Rev B 2021, 103: 054112.
[44]
Li JJ, Wu HH, Li JT, et al. Room-temperature symmetric giant positive and negative electrocaloric effect in PbMg0.5W0.5O3 antiferroelectric ceramic. Adv Funct Mater 2021, 31: 2101176.
[45]
Viehland D, Forst D, Li JF. Compositional heterogeneity and the origins of the multicell cubic state in Sn-doped lead zirconate titanate ceramics. J Appl Phys 1994, 75: 4137–4143.
[46]
Xu Z, Viehland D, Yang P, et al. Hot-stage transmission electron microscopy studies of phase transformations in tin-modified lead zirconate titanate. J Appl Phys 1993, 74: 3406–3413.
[47]
Geng LD, Jin YM, Tan DQ, et al. Computational study of nonlinear dielectric composites with field-induced antiferroelectric–ferroelectric phase transition. J Appl Phys 2018, 124: 164109.
Journal of Advanced Ceramics
Pages 463-473
Cite this article:
Li J, Yin R, Li J, et al. Correlation between multi-factor phase diagrams and complex electrocaloric behaviors in PNZST antiferroelectric ceramic system. Journal of Advanced Ceramics, 2023, 12(3): 463-473. https://doi.org/10.26599/JAC.2023.9220696

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Received: 05 October 2022
Revised: 28 October 2022
Accepted: 12 November 2022
Published: 09 February 2023
© The Author(s) 2022.

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