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Research Article | Open Access

From binary to ternary and back to binary: Transition of electromagnetic wave shielding to absorption among MAB phase Ni3ZnB2 and corresponding binary borides Nin+1Bn (n = 1, 3)

Chengwen Wua, Fan Zhanga,b, Qin Zhia, Bo Songa( ), Yongqiang Chena, Hailong Wanga, Rui Zhanga,c, Hongxia Lia,d, Bingbing Fana( )
School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
Henan Vocational College of Information and Statistics, Zhengzhou 450008, China
School of Material Science and Engineering, Luoyang Institute of Science and Technology, Luoyang 471023, China
State Key Laboratory of Advanced Refractories, Sinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471039, China
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Graphical Abstract

Abstract

Due to chemical inertness of nickel and boron, the preparation of nickel borides and corresponding layered ternary transition metal borides Ni3ZnB2 (MAB phase) has always required high-temperature and/or high-pressure conditions. Yet, an innovative and efficient approach to preparing Ni3ZnB2 at only 600 ℃ and without applied pressure is presented in this study. It is discovered that by simply adjusting the temperature, a phase transition from Ni3ZnB2 to Ni4B3 with a layered structure could be induced. This transition between the binary-component and the ternary-component brings about significant variation in electromagnetic wave (EMW) shielding/absorption performance of prepared borides. For instance, Ni2B has good EMW shielding performance (42.54 dB in X band) and Ni3ZnB2 is of weak EMW shielding (13.43 dB in X band); Ni3ZnB2 has poor EMW absorption performance (−5 dB) while Ni4B3 has excellent EMW absorption performance (−45.19 dB) at a thickness of 2.7 mm with effective absorption bandwidth (10.4 GHz).

Keywords

nickel boridesNi3ZnB2electromagnetic wave (EMW) shielding propertieselectromagnetic wave absorbing properties

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Journal of Advanced Ceramics
Volume 12 Issue 11,
November 2023
Pages 2101-2111
DOI: 10.26599/JAC.2023.9220812
Cite this article:
Wu C, Zhang F, Zhi Q, et al. From binary to ternary and back to binary: Transition of electromagnetic wave shielding to absorption among MAB phase Ni3ZnB2 and corresponding binary borides Nin+1Bn (n = 1, 3). Journal of Advanced Ceramics, 2023, 12(11): 2101-2111. https://doi.org/10.26599/JAC.2023.9220812

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Received: 05 August 2023
Revised: 05 September 2023
Accepted: 29 September 2023
Published: 27 November 2023
© The Author(s) 2023.

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