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Research Article | Open Access

Tunable polarization-drived high energy storage performances in flexible PbZrO3 films by growing Al2O3 nanolayers

Chao Yina,b, Tiandong Zhanga,b( ), Zhuangzhuang Shia,b, Bowen Zhanga,b, Changhai Zhanga,b, Qingguo Chia,b( )
Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, China
School of Electrical and Electronic Engineering, Harbin University of Science and Technology, Harbin 150080, China
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Graphical Abstract

Abstract

In recent years, PbZrO3 (PZO) films have become favorable electric storage materials due to the unique electric field-induced phase transition behavior, but the severe hysteresis effect leads to low energy storage density and efficiency. In this work, inserting Al2O3 (AO) insulation nanolayers is proposed to tune the polarization behavior of flexible PZO films, anticipating optimization of energy storage performance. The results show that the thickness of the AO nanolayers has a deep influence on the polarization behavior of the PZO films, and PZO/AO/PZO (PAP) sandwiched films with 8 nm AO interlayer deliver relaxor ferroelectric-like polarization instead of antiferroelectric counterpart. To further utilize the AO nanolayers as top/bottom layers, the linear-like polarization and the highest breakdown strength are achieved in the AO/PZO/AO/PZO/AO (APAPA8) multilayer films, leading to both high discharged energy storage density of 35.2 J/cm3 and efficiency of 92.9%, as well as excellent fatigue and bending endurance, good temperatures, and frequency stability. The tunable polarization induced by growing the AO nanolayers makes antiferroelectric PZO films have great potential to be used as energy storage dielectrics.

Keywords

sol–gelflexibleantiferroelectricpolarizationenergy storage

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Journal of Advanced Ceramics
Volume 12 Issue 11,
November 2023
Pages 2123-2133
DOI: 10.26599/JAC.2023.9220814
Cite this article:
Yin C, Zhang T, Shi Z, et al. Tunable polarization-drived high energy storage performances in flexible PbZrO3 films by growing Al2O3 nanolayers. Journal of Advanced Ceramics, 2023, 12(11): 2123-2133. https://doi.org/10.26599/JAC.2023.9220814

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Received: 24 July 2023
Revised: 09 September 2023
Accepted: 03 October 2023
Published: 21 November 2023
© The Author(s) 2023.

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