AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (1.4 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Tunable polarization-drived high energy storage performances in flexible PbZrO3 films by growing Al2O3 nanolayers

Chao Yina,b, Tiandong Zhanga,b( ), Zhuangzhuang Shia,b, Bowen Zhanga,b, Changhai Zhanga,b, Qingguo Chia,b( )
Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, China
School of Electrical and Electronic Engineering, Harbin University of Science and Technology, Harbin 150080, China
Show Author Information

Graphical Abstract

Abstract

In recent years, PbZrO3 (PZO) films have become favorable electric storage materials due to the unique electric field-induced phase transition behavior, but the severe hysteresis effect leads to low energy storage density and efficiency. In this work, inserting Al2O3 (AO) insulation nanolayers is proposed to tune the polarization behavior of flexible PZO films, anticipating optimization of energy storage performance. The results show that the thickness of the AO nanolayers has a deep influence on the polarization behavior of the PZO films, and PZO/AO/PZO (PAP) sandwiched films with 8 nm AO interlayer deliver relaxor ferroelectric-like polarization instead of antiferroelectric counterpart. To further utilize the AO nanolayers as top/bottom layers, the linear-like polarization and the highest breakdown strength are achieved in the AO/PZO/AO/PZO/AO (APAPA8) multilayer films, leading to both high discharged energy storage density of 35.2 J/cm3 and efficiency of 92.9%, as well as excellent fatigue and bending endurance, good temperatures, and frequency stability. The tunable polarization induced by growing the AO nanolayers makes antiferroelectric PZO films have great potential to be used as energy storage dielectrics.

Keywords

sol–gelflexibleantiferroelectricpolarizationenergy storage

Electronic Supplementary Material

Download File(s)
JAC0814_ESM.pdf (952 KB)

References

[1]
Cheng HB, Zhai X, Ouyang J, et al. Achieving a high energy storage density in Ag(Nb,Ta)O3 antiferroelectric films via nanograin engineering. J Adv Ceram 2023, 12: 196–206.
Crossref Google Scholar
[2]
Fan XH, Wang J, Yuan H, et al. Multi-scale synergic optimization strategy for dielectric energy storage ceramics. J Adv Ceram 2023, 12: 649–680.
Crossref Google Scholar
[3]
Zhang TD, Yang LY, Zhang CH, et al. Polymer dielectric films exhibiting superior high-temperature capacitive performance by utilizing an inorganic insulation interlayer. Mater Horiz 2022, 9: 1273–1282.
Crossref Google Scholar
[4]
Jiang J, Bitla Y, Huang CW, et al. Flexible ferroelectric element based on van der Waals heteroepitaxy. Sci Adv 2017, 3: e1700121.
Crossref Google Scholar
[5]
Pei JY, Zhong SL, Zhao Y, et al. All-organic dielectric polymer films exhibiting superior electric breakdown strength and discharged energy density by adjusting the electrode–dielectric interface with an organic nano-interlayer. Energy Environ Sci 2021, 14: 5513–5522.
Crossref Google Scholar
[6]
Peddigari M, Park JH, Han JH, et al. Flexible self-charging, ultrafast, high-power-density ceramic capacitor system. ACS Energy Lett 2021, 6: 1383–1391.
Crossref Google Scholar
[7]
Yin C, Zhang TD, Zhang BW, et al. High energy storage performance for flexible PbZrO3 thin films by seed layer engineering. Ceram Int 2022, 48: 23840–23848.
Crossref Google Scholar
[8]
Zhang TD, Yang LY, Ruan JY, et al. Improved high-temperature energy storage performance of PEI dielectric films by introducing an SiO2 insulating layer. Macromol Mater Eng 2021, 306: 2100514.
Crossref Google Scholar
[9]
Feng MJ, Feng Y, Zhang TD, et al. Recent advances in multilayer-structure dielectrics for energy storage application. Adv Sci 2021, 8: e2102221.
Crossref Google Scholar
[10]
Zhang TD, Zhao XW, Zhang CH, et al. Polymer nanocomposites with excellent energy storage performances by utilizing the dielectric properties of inorganic fillers. Chem Eng J 2021, 408: 127314.
Crossref Google Scholar
[11]
Zhang YL, Li WL, Wang ZY, et al. Perovskite Sr1−x(Na0.5Bi0.5)xTi0.99Mn0.01O3 thin films with defect dipoles for high energy-storage and electrocaloric performance. ACS Appl Mater Interfaces 2019, 11: 37947–37954.
Crossref Google Scholar
[12]
Shen BZ, Li Y, Hao XH. Multifunctional all-inorganic flexible capacitor for energy storage and electrocaloric refrigeration over a broad temperature range based on PLZT 9/65/35 thick films. ACS Appl Mater Interfaces 2019, 11: 34117–34127.
Crossref Google Scholar
[13]
Yang CH, Qian J, Han YJ, et al. Design of an all-inorganic flexible Na0.5Bi0.5TiO3-based film capacitor with giant and stable energy storage performance. J Mater Chem A 2019, 7: 22366–22376.
Crossref Google Scholar
[14]
Ko DL, Hsin T, Lai YH, et al. High-stability transparent flexible energy storage based on PbZrO3/muscovite heterostructure. Nano Energy 2021, 87: 106149.
Crossref Google Scholar
[15]
Liang ZS, Ma CR, Shen LK, et al. Flexible lead-free oxide film capacitors with ultrahigh energy storage performances in extremely wide operating temperature. Nano Energy 2019, 57: 519–527.
Crossref Google Scholar
[16]
Yang CH, Lv PP, Qian J, et al. Fatigue-free and bending-endurable flexible Mn-doped Na0.5Bi0.5TiO3–BaTiO3–BiFeO3 film capacitor with an ultrahigh energy storage performance. Adv Energy Mater 2019, 9: 1803949.
Crossref Google Scholar
[17]
Shen BZ, Li Y, Sun NN, et al. Enhanced energy-storage performance of an all-inorganic flexible bilayer-like antiferroelectric thin film via using electric field engineering. Nanoscale 2020, 12: 8958–8968.
Crossref Google Scholar
[18]
Chi QG, Zhou YH, Yin C, et al. A blended binary composite of poly(vinylidene fluoride) and poly(methyl methacrylate) exhibiting excellent energy storage performances. J Mater Chem C 2019, 7: 14148–14158.
Crossref Google Scholar
[19]
Li WL, Zhang TD, Hou YF, et al. Giant piezoelectric properties of BZT–0.5BCT thin films induced by nanodomain structure. RSC Adv 2014, 4: 56933–56937.
Crossref Google Scholar
[20]
Zhang YL, Li WL, Wang ZY, et al. Ultrahigh energy storage and electrocaloric performance achieved in SrTiO3 amorphous thin films via polar cluster engineering. J Mater Chem A 2019, 7: 17797–17805.
Crossref Google Scholar
[21]
Zhang TD, Zhao Y, Li WL, et al. High energy storage density at low electric field of ABO3 antiferroelectric films with ionic pair doping. Energy Storage Mater 2019, 18: 238–245.
Crossref Google Scholar
[22]
Zhang TD, Shi ZZ, Yin C, et al. Tunable polarization-drived superior energy storage performance in PbZrO3 thin films. J Adv Ceram 2023, 12: 930–942.
Crossref Google Scholar
[23]
Zhang TF, Si YY, Li YJ, et al. Research status and prospect of lead zirconate-based antiferroelectric films. Acta Phys Sin 2023, 72: 097704.
Crossref Google Scholar
[24]
Zhang TD, Li WL, Zhao Y, et al. High energy storage performance of opposite double-heterojunction ferroelectricity-insulators. Adv Funct Mater 2018, 28: 1706211.
Crossref Google Scholar
[25]
Zhang TD, Yin C, Zhang CH, et al. Self-polarization and energy storage performance in antiferroelectric-insulator multilayer thin films. Compos B Eng 2021, 221: 109027.
Crossref Google Scholar
[26]
Yin C, Zhang TD, Shi ZZ, et al. High energy storage performance of all-inorganic flexible antiferroelectric-insulator multilayered thin films. ACS Appl Mater Interfaces 2022, 14: 28997–29006.
Crossref Google Scholar
[27]
Sa TL, Qin N, Yang GW, et al. W-doping induced antiferroelectric to ferroelectric phase transition in PbZrO3 thin films prepared by chemical solution deposition. Appl Phys Lett 2013, 102: 172906.
Crossref Google Scholar
[28]
Li YZ, Wang ZJ, Bai Y, et al. Enhancement of energy storage density in antiferroelectric PbZrO3 films via the incorporation of gold nanoparticles. J Am Ceram Soc 2019, 102: 5253–5261.
Crossref Google Scholar
[29]
Thatikonda SK, Huang WH, Du XR, et al. Ti-doping induced antiferroelectric to ferroelectric phase transition and electrical properties in Sm–PbZrO3 thin films. Curr Appl Phys 2021, 24: 12–18.
Crossref Google Scholar
[30]
Chen XY, Peng BL, Ding MJ, et al. Giant energy storage density in lead-free dielectric thin films deposited on Si wafers with an artificial dead-layer. Nano Energy 2020, 78: 105390.
Crossref Google Scholar
[31]
Cao WP, Li WL, Bai TRGL, et al. Enhanced electrical properties in lead-free NBT–BT ceramics by series ST substitution. Ceram Int 2016, 42: 8438–8444.
Crossref Google Scholar
[32]
Liu G, Feng Y, Zhang TD, et al. High-temperature all-organic energy storage dielectric with the performance of self-adjusting electric field distribution. J Mater Chem A 2021, 9: 16384–16394.
Crossref Google Scholar
[33]
Dong JF, Hu RC, Xu XW, et al. A facile in situ surface-functionalization approach to scalable laminated high-temperature polymer dielectrics with ultrahigh capacitive performance. Adv Funct Mater 2021, 31: 2102644.
Crossref Google Scholar
[34]
Zhang Y, Li Y, Hao XH, et al. Flexible antiferroelectric thick film deposited on nickel foils for high energy-storage capacitor. J Am Ceram Soc 2019, 102: 6107–6114.
Crossref Google Scholar
[35]
Li YQ, Geng WP, Zhang L, et al. Flexible PLZT antiferroelectric film capacitor for energy storage in wide temperature range. J Alloys Compd 2021, 868: 159129.
Crossref Google Scholar
[36]
Er XK, Chen P, Guo JS, et al. Enhanced energy-storage performance in a flexible film capacitor with coexistence of ferroelectric and polymorphic antiferroelectric domains. J Materiomics 2022, 8: 375–381.
Crossref Google Scholar
[37]
Sun NN, Du JH, Zhao Y, et al. Flexible multilayer lead-free film capacitor with high energy storage performances via heterostructure engineering. J Materiomics 2022, 8: 772–780.
Crossref Google Scholar
[38]
Sun NN, Li Y, Hao XH. High energy-storage all-inorganic Mn-doped Bi0.5Na0.5TiO3–BiNi0.5Zr0.5O3 film capacitor with characteristics of flexibility and plasticity. J Alloys Compd 2021, 879: 160506.
Crossref Google Scholar
[39]
Han YJ, Qian J, Yang CH. Fatigue-free dielectric capacitor with giant energy density based on lead-free Na0.5Bi0.5TiO3-based film. J Mater Sci-Mater El 2019, 30: 21369–21376.
Crossref Google Scholar
[40]
Lv PP, Yang CH, Qian J, et al. Flexible lead-free perovskite oxide multilayer film capacitor based on (Na0.8K0.2)0.5Bi0.5TiO3/Ba0.5Sr0.5(Ti0.97Mn0.03)O3 for high-performance dielectric energy storage. Adv Energy Mater 2020, 10: 1904229.
Google Scholar
[41]
Yang CH, Han YJ, Feng C, et al. Toward multifunctional electronics: Flexible NBT-based film with a large electrocaloric effect and high energy storage property. ACS Appl Mater Interface 2020, 12: 6082–6089.
Crossref Google Scholar
[42]
Qian J, Han YJ, Yang CH, et al. Energy storage performance of flexible NKBT/NKBT–ST multilayer film capacitor by interface engineering. Nano Energy 2020, 74: 104862.
Crossref Google Scholar
[43]
Guo F, Shi ZF, Yang B, et al. Flexible lead-free Na0.5Bi0.5TiO3–EuTiO3 solid solution film capacitors with stable energy storage performances. Scripta Mater 2020, 184: 52–56.
Crossref Google Scholar
[44]
Liang ZS, Liu M, Shen LK, et al. All-inorganic flexible embedded thin-film capacitors for dielectric energy storage with high performance. ACS Appl Mater Interface 2019, 11: 5247–5255.
Crossref Google Scholar
[45]
Liang ZS, Ma CR, Shen LK, et al. Flexible lead-free oxide film capacitors with ultrahigh energy storage performances in extremely wide operating temperature. Nano Energy 2019, 57: 519–527.
Crossref Google Scholar
[46]
Bin CW, Hou X, Xie YD, et al. Ultrahigh energy storage performance of flexible BMT-based thin film capacitors. Small 2022, 18: 2106209.
Crossref Google Scholar
[47]
Bin CW, Hou X, Yang H, et al. Flexible lead-free film capacitor based on BiMg0.5Ti0.5O3–SrTiO3 for high-performance energy storage. Chem Eng J 2022, 445: 136728.
Crossref Google Scholar
[48]
Wang WW, Qian J, Geng CH, et al. Flexible lead-free Ba0.5Sr0.5TiO3/0.4BiFeO3–0.6SrTiO3 dielectric film capacitor with high energy storage performance. Nanomaterials 2021, 11: 3065.
Crossref Google Scholar
[49]
Yang CH, Qian J, Lv PP, et al. Flexible lead-free BFO-based dielectric capacitor with large energy density, superior thermal stability, and reliable bending endurance. J Materiomics 2020, 6: 200–208.
Crossref Google Scholar
[50]
Yang BB, Guo MY, Li CH, et al. Flexible ultrahigh energy storage density in lead-free heterostructure thin-film capacitors. Appl Phys Lett 2019, 115: 243901.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 12 Issue 11,
November 2023
Pages 2123-2133
DOI: 10.26599/JAC.2023.9220814
Cite this article:
Yin C, Zhang T, Shi Z, et al. Tunable polarization-drived high energy storage performances in flexible PbZrO3 films by growing Al2O3 nanolayers. Journal of Advanced Ceramics, 2023, 12(11): 2123-2133. https://doi.org/10.26599/JAC.2023.9220814

1691

Views

269

Downloads

8

Crossref

8

Web of Science

7

Scopus

0

CSCD

Altmetrics
Received: 24 July 2023
Revised: 09 September 2023
Accepted: 03 October 2023
Published: 21 November 2023
© The Author(s) 2023.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return