AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
{{expandStatus?'Exit ':''}}Advanced Search
Two-dimensional (2D) nanomaterials, such as graphene, MoS2, and MAX, have attracted increasing research attention in recent years due to their unique structural and performance advantages. However, their complex production processes and equipment requirements are significant issues affecting their widespread use. Here, with an exfoliation strategy using three-roll milling, we present a simple, cost-effective, and extensible method to produce multilayer graphene, BN, MoS2, and Ti3AlC2 nanosheets. The roller and phenolic resin created three kinds of forces on the layered 2D materials, i.e., shear forces, compressive forces, and adhesive forces, which exfoliated layered materials from their edges and surfaces into nanosheets. Subsequently, the exfoliated materials were ultrasonically washed with alcohol, treated with ultrasonic vibration, and centrifuged to obtain 2D nanomaterials. The easy operation and high yield are attractive for research based on the construction of high-performance 2D nanosheet-based devices at low cost. Herein, the obtained multilayer graphene and MoS2 nanosheets were used as anode materials of sodium/potassium-ion batteries, respectively, to test their electrochemical properties. Better performances are obtained compared with their primary bulk materials.
Novoselov KS, Geim AK, Morozov SV, et al. Electric field effect in atomically thin carbon films. Science 2004, 306: 666–669.
Zhang L, Hu ZH, Huang JT, et al. Experimental and DFT studies of flower-like Ni-doped Mo2C on carbon fiber paper: A highly efficient and robust HER electrocatalyst modulated by Ni(NO3)2 concentration. J Adv Ceram 2022, 11: 1294–1306.
Zhang GH, Li XJ, Wei DH, et al. Synergistic engineering of structural and electronic regulation of In2Se3 for ultrastable Li-ion battery. Chem Eng J 2023, 453: 139841.
Gao HQ, Hu MG, Ding JF, et al. Investigation of contact electrification between 2D MXenes and MoS2 through density functional theory and triboelectric probes. Adv Funct Mater 2023, 33: 2213410.
Qin YF, Zhao ZJ, Wang T, et al. Efficient lithium/sodium-ion storage by core–shell carbon nanospheres@TiO2 decorate by epitaxial WSe2 nanosheets derived from bimetallic polydopamine composites. Small 2023, 19: 2204980.
Cui QL, Luo ZY, Cui QR, et al. Robust and high photoluminescence in WS2 monolayer through in situ defect engineering. Adv Funct Mater 2021, 31: 2105339.
Ding GL, Chen RS, Xie P, et al. Filament engineering of two-dimensional h-BN for a self-power mechano−nociceptor system. Small 2022, 18: 2200185.
Qian RC, Dong BB, Hao SS, et al. Robust all-inorganic hydrophobic BN nanosheets coated β-sialon membrane for membrane distillation. J Eur Ceram Soc 2022, 42: 2672–2677.
Lee C, Park SM, Kim S, et al. Field-induced orientational switching produces vertically aligned Ti3C2T x MXene nanosheets. Nat Commun 2022, 13: 5615.
Duan XJ, Fang Z, Yang T, et al. Maximizing the mechanical performance of Ti3AlC2-based MAX phases with aid of machine learning. J Adv Ceram 2022, 11: 1307–1318.
Zhang HM, Dai FZ, Xiang HM, et al. Phase pure and well crystalline Cr2AlB2: A key precursor for two-dimensional CrB. J Mater Sci Technol 2019, 35: 1593–1600.
Zhang J, Wang F, Shenoy VB, et al. Towards controlled synthesis of 2D crystals by chemical vapor deposition (CVD). Mater Today 2020, 40: 132–139.
Syari’ati A, Kumar S, Zahid A, et al. Photoemission spectroscopy study of structural defects in molybdenum disulfide (MoS2) grown by chemical vapor deposition (CVD). Chem Com 2019, 55: 10384–10387.
Ding W, Hu L, Dai JM, et al. Highly ambient-stable 1T–MoS2 and 1T–WS2 by hydrothermal synthesis under high magnetic fields. ACS Nano 2019, 13: 1694–1702.
Li B, Gu P, Feng YC, et al. Ultrathin nickel–cobalt phosphate 2D nanosheets for electrochemical energy storage under aqueous/solid-state electrolyte. Adv Funct Mater 2017, 27: 1605784.
Nersisyan HH, Lee JH, Ding JR, et al. Combustion synthesis of zero-, one-, two- and three-dimensional nanostructures: Current trends and future perspectives. Prog Energy Combust Sci 2017, 63: 79–118.
Somani PR, Somani SP, Umeno M. Planer nano-graphenes from camphor by CVD. Chem Phys Lett 2006, 430: 56–59.
Jia S, Chen W, Zhang J, et al. CVD growth of high-quality and large-area continuous h-BN thin films directly on stainless-steel as protective coatings. Mater Today Nano 2021, 16: 100135.
Li SY, Chen XQ, Liu FM, et al. Enhanced performance of a CVD MoS2 photodetector by chemical in situ n-type doping. ACS Appl Mater 2019, 11: 11636–11644.
Sun YH, Sun YF, Wang RM, et al. Probing the interlayer mechanical coupling of 2D layered materials—A review. Prog Nat Sci-Mater 2022, 32: 528–537.
Zhang X, Tan QH, Wu JB, et al. Review on the Raman spectroscopy of different types of layered materials. Nanoscale 2016, 8: 6435–6450.
Novoselov KS, Jiang D, Schedin F, et al. Two-dimensional atomic crystals. Proc Natl Acad Sci 2005, 102: 10451–10453.
Yao YG, Lin ZY, Li Z, et al. Large-scale production of two-dimensional nanosheets. J Mater Chem 2012, 22: 13494–13499.
Zeng ZY, Sun T, Zhu JX, et al. An effective method for the fabrication of few-layer-thick inorganic nanosheets. Angew Chem Int Ed 2012, 51: 9052–9056.
Paton KR, Varrla E, Backes C, et al. Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids. Nat Mater 2014, 13: 624–630.
Tang KW, Qi WH, Wei YR, et al. High-throughput calculation of interlayer van der Waals forces validated with experimental measurements. Research 2022, 2022: 9765121.
Qin HM, Deng CR, Lu SJ, et al. Enhanced mechanical property, thermal and electrical conductivity of natural rubber/graphene nanosheets nanocomposites. Polym Composite 2020, 41: 1299–1309.
Xing T, Mateti S, Li LH, et al. Gas protection of two-dimensional nanomaterials from high-energy impacts. Sci Rep-UK 2016, 6: 35532.
Liu MQ, Huang JT, Meng HT, et al. A novel approach to prepare ultra-low-carbon MgO−C refractories by using graphite nanoplatelets exfoliated by three-row milling in phenolic resin. J Euro Ceram Soc 2023, 43: 4198–4208.
Li SC, Lu XL, Lou YD, et al. The synthesis and characterization of h-BN nanosheets with high yield and crystallinity. ACS Omega 2021, 6: 27814–27822.
Cai QR, Li LH, Yu YL, et al. Boron nitride nanosheets as improved and reusable substrates for gold nanoparticles enabled surface enhanced Raman spectroscopy. Phys Chem Chem Phys 2015, 17: 7761–7766.
Corro ED, Taravillo M, Baonza VG. Nonlinear strain effects in double-resonance Raman bands of graphite, graphene, and related materials. Phys Rev B 2012, 85: 033407.
Yao BX, Li SB, Zhang WW, et al. Self-healing behavior of Ti2AlC at a low oxygen partial pressure. J Adv Ceram 2022, 11: 1687–1695.
Zhang YB, Qin JD, Lowe SE, et al. Enhanced electrochemical production and facile modification of graphite oxide for cost-effective sodium ion battery anodes. Carbon 2021, 177: 71–78.
Liu WJ, Yuan M, Lian JB, et al. Embedding partial sulfurization of iron–cobalt oxide nanoparticles into carbon nanofibers as an efficient electrode for the advanced asymmetric supercapacitor. Tungsten 2023, 5: 118–129.
Chen Z, Augustyn V, Jia XL, et al. High-performance sodium-ion pseudocapacitors based on hierarchically porous nanowire composites. ACS Nano 2012, 6: 4319–4327.
Augustyn V, Come J, Lowe MA, et al. High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat Mater 2013, 12: 518–522.
Xu XD, Zeng HL, Han DZ, et al. Nitrogen and sulfur co-doped graphene nanosheets to improve anode materials for sodium-ion batteries. ACS Appl Mater Inter 2018, 10: 37172–37180.
Xue YH, Zhang Q, Wang WJ, et al. Opening two-dimensional materials for energy conversion and storage: A concept. Adv Energy Mater 2017, 7: 1602684.
Li SS, Zhou WY, Li YX, et al. Noble-metal-free Co0.6Fe2.4O4 nanocubes self-assembly monolayer for highly sensitive electrochemical detection of As(III) based on surface defects. Anal Chem 2018, 90: 1263–1272.
Wu LC, Fu HW, Li S, et al. Phase-engineered cathode for super-stable potassium storage. Nat Commun 2023, 14: 644.
1480
Views
312
Downloads
23
Crossref
21
Web of Science
23
Scopus
0
CSCD
Altmetrics
This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, http://creativecommons.org/licenses/by/4.0/).
京公网安备11010802044758号