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Research Article | Open Access

Online preparation of high-quality BN coatings with atomic diffusion based on carbon-free water-soluble precursor

Yiang DuBing Wang( )Yunbo ZhangQuzhi SongFuwen WangCheng HanXiaoshan ZhangYingde Wang( )
Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China
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Abstract

Efficient and environmentally friendly production of high-quality continuous fiber coatings using current preparation methods is highly challenging due to issues such as scale and batch processing restrictions, low deposition rate, high energy consumption, and utilization of multiple environmentally hazardous steps. To address these challenges, we propose a stable and efficient wet chemical deposition coating method for high-throughput online continuous preparation of boron nitride (BN) coatings on ceramic fibers under an ambient environment. Our process involves surface modification, in-situ wet chemical deposition, and heat treatment, and all seamlessly connecting with the ceramic fiber preparation process through continuous stretching. Hydrophilic groups were introduced via surface modification enhancing wettability of the fiber surface with impregnating solution. An in-situ reaction and atom migration improve uniformity and binding of the coating. As a result, outstanding impregnation and adhesion properties are achieved. A comprehensive analysis to evaluate the impact of the BN coatings was conducted, which demonstrates that the BN-coated fibers exhibit a remarkable 36% increase in tensile strength, a 133% increase in fracture toughness, and enhanced temperature resistance of up to 1600 ℃. It provides a secure and efficient platform for cost-effective production of functional and high-quality coatings through targeted surface modification and rapid stretching impregnation.

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Journal of Advanced Ceramics
Pages 272-281
Cite this article:
Du Y, Wang B, Zhang Y, et al. Online preparation of high-quality BN coatings with atomic diffusion based on carbon-free water-soluble precursor. Journal of Advanced Ceramics, 2024, 13(3): 272-281. https://doi.org/10.26599/JAC.2024.9220851

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Received: 18 November 2023
Revised: 16 December 2023
Accepted: 01 January 2024
Published: 11 March 2024
© The Author(s) 2024.

This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, http://creativecommons.org/licenses/by/4.0/).

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