AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
{{expandStatus?'Exit ':''}}Advanced Search
Noncontact optical thermometers have attracted widespread attention, but existing problems such as single-mode and low-sensitivity thermometers still urgently need to be solved. Herein, a novel multiple-mode thermometer was designed for the polymorphism LaSc3(BO3)4:Eu2+/3+,Li+. X-ray diffraction (XRD) patterns revealed a slight transition between α- and β-phases with the concentrations of the dopants, which is further proved by structure refinements and first-principles calculations. The coexistence of Eu2+ and Eu3+ in the phosphors and their relative percentages were confirmed by X-ray absorption near-edge structure (XANES) spectra. Benefiting from appropriate emissions from Eu2+ and Eu3+ without obvious energy transfer and their opposite changing trends with temperatures under 307 nm excitation, a triple-mode optical thermometer is obtained for this material within the temperature range of 150–450 K. The highest sensitivities of 27.65, 14.05, and 7.68 %·K−1 are achieved based on two fluorescence intensity ratio (FIR) modes of Eu2+ and Eu3+ (5d–4f/5D0–7F2,4) and the fluorescence lifetime (FL) mode of Eu2+, respectively. To the best of our knowledge, the former is almost the highest in Eu2+ and Eu3+ co-doped thermometers. These results indicate that this material may be used as an excellent multiple-mode optical thermometer.
Wang XD, Wolfbeis OS, Meier RJ. Luminescent probes and sensors for temperature. Chem Soc Rev 2013, 42: 7834–7869.
Brites CDS, Balabhadra S, Carlos LD. Lanthanide-based thermometers: At the cutting-edge of luminescence thermometry. Adv Opt Mater 2019, 7: 1801239.
Suo H, Zhao XQ, Zhang ZY, et al. Rational design of ratiometric luminescence thermometry based on thermally coupled levels for bioapplications. Laser Photonics Rev 2021, 15: 2000319.
Ansari AA, Parchur AK, Nazeeruddin MK, et al. Luminescent lanthanide nanocomposites in thermometry: Chemistry of dopant ions and host matrices. Coordin Chem Rev 2021, 444: 214040.
Xue J, Li L, Runowski M, et al. Precisely manipulating the self-reduction of manganese in MgGa2O4 through lithium incorporation for optical thermometry and anti-counterfeiting. Adv Opt Mater 2023, 11: 2300600.
Chen DH, Haldar R, Wöll C. Stacking lanthanide-MOF thin films to yield highly sensitive optical thermometers. ACS Appl Mater Inter 2023, 15: 19665–19671.
Wang Q, Liao M, Lin QM, et al. A review on fluorescence intensity ratio thermometer based on rare-earth and transition metal ions doped inorganic luminescent materials. J Alloys Compd 2021, 850: 156744.
Zhong L, Jiang S, Wang XH, et al. Dual-mode optical thermometry based on intervalence charge transfer excitations in Tb3+/Pr3+ co-doped CaNb2O6 phosphors. Ceram Int 2022, 48: 30005–30011.
van Swieten TP, Yu D, Yu T, et al. A Ho3+-based luminescent thermometer for sensitive sensing over a wide temperature range. Adv Opt Mater 2021, 9: 2001518.
Liu X, Mi X, Guo Y, et al. Highly sensitive and near-infrared excitable optical thermometer based on CaGdAl3O7:Tm3+,Yb3+,Zn2+. J Alloys Compd 2022, 929: 167240.
Xue J, Yu Z, Noh HM, et al. Designing multi-mode optical thermometers via the thermochromic LaNbO4:Bi3+/Ln3+ (Ln = Eu, Tb, Dy, Sm) phosphors. Chem Eng J 2021, 415: 128977.
Zhou LY, Chen YL, Shen YY, et al. Designing optical thermometers using down/upconversion Ca14Al10Zn6O35:Ti4+,Eu3+/Yb3+,Er3+ thermosensitive phosphors. Inorg Chem 2022, 61: 10667–10677.
Zhang H, Gao ZY, Li GG, et al. A ratiometric optical thermometer with multi-color emission and high sensitivity based on double perovskite LaMg0.402Nb0.598O3:Pr3+ thermochromic phosphors. Chem Eng J 2020, 380: 122491.
Ding H, Lv GQ, Cai X, et al. An optoelectronic thermometer based on microscale infrared-to-visible conversion devices. Light Sci Appl 2022, 11: 130.
Chen ZL, Du SM, Zhu KM, et al. Mn4+-activated double-perovskite-type Sr2LuNbO6 multifunctional phosphor for optical probing and lighting. ACS Appl Mater Inter 2023, 15: 28193–28203.
Peng M, Kaczmarek AM, van Hecke K. Ratiometric thermometers based on rhodamine B and fluorescein dye-incorporated (nano) cyclodextrin metal–organic frameworks. ACS Appl Mater Inter 2022, 14: 14367–14379.
Xu CW, Li CX, Deng DG, et al. A dual-mode optical thermometer with high sensitivity based on BaAl12O19:Sm2+/SrAl12O19:Sm3+ solid solution phosphors. Inorg Chem 2022, 61: 7989–7999.
Wei RF, Lu FM, Wang L, et al. Splendid four-mode optical thermometry design based on thermochromic Cs3GdGe3O9:Er3+ phosphors. J Mater Chem C 2022, 10: 9492–9498.
Yuan J, Zhao GS, Ren SQ, et al. Multimode fluorescence intensity ratio thermometer based on synergistic luminescence from Eu3+ to Mn4+ of SrTiO3:Eu3+–uTiOt3:Mn4+ nanocomposites. Ceram Int 2023, 49: 17699–17708.
Zhang XG, Zhu ZP, Guo ZY, et al. A ratiometric optical thermometer with high sensitivity and superior signal discriminability based on Na3Sc2P3O12:Eu2+,Mn2+ thermochromic phosphor. Chem Eng J 2019, 356: 413–422.
Fan ZT, Bi SL, Seo HJ. Tunable emission via dual-site occupancy in Ba2CaB2Si4O14:Bi3+,Sm3+ phosphors. J Alloys Compd 2022, 916: 165347.
Jahanbazi F, Mao YB. Recent advances on metal oxide-based luminescence thermometry. J Mater Chem C 2021, 9: 16410–16439.
Tian Y, Tian Y, Huang P, et al. Effect of Yb3+ concentration on upconversion luminescence and temperature sensing behavior in Yb3+/Er3+ co-doped YNbO4 nanoparticles prepared via molten salt route. Chem Eng J 2016, 297: 26–34.
Suo H, Zhao XQ, Zhang ZY, et al. Ultra-sensitive optical nano-thermometer LaPO4:Yb3+/Nd3+ based on thermo-enhanced NIR-to-NIR emissions. Chem Eng J 2020, 389: 124506.
Liu W, Zhao D, Zhang RJ, et al. Fluorescence lifetime-based luminescent thermometry material with lifetime varying over a factor of 50. Inorg Chem 2022, 61: 16468–16476.
Chen JY, Chen JQ, Li LJ, et al. A four-mode high-sensitive optical thermometer based on Ca3LiZnV3O12:Sm3+ phosphors. Mater Today Chem 2023, 29: 101409.
Chen JQ, Chen JY, Zhang WN, et al. Three-mode optical thermometer based on Ca3LiMgV3O12:Sm3+ phosphors. Ceram Int 2023, 49: 16252–16259.
Ayachi F, Saidi K, Dammak M, et al. Dual-mode luminescence of Er3+/Yb3+ codoped LnP0.5V0.5O4 (Ln = Y, Gd, La) for highly sensitive optical nanothermometry. Mater Today Chem 2023, 27: 101352.
Mi RY, Liu YG, Mei LF, et al. Highly-efficient cyan-emitting phosphor enabling high-color-quality lighting and transparent anticounterfeiting. Chem Eng J 2023, 457: 141377.
Zhang D, Zheng BF, Zheng ZB, et al. Multifunctional Ca9NaZn1− y Mg y (PO4)7:Eu2+ phosphor for full-spectrum lighting, optical thermometry and pressure sensor applications. Chem Eng J 2022, 431: 133805.
Xiang Y, Liu ZY, Gao Y, et al. Novel double perovskite Ca2Gd0.5Nb1− x W5 x /6O6:0.5Eu3+ red phosphors with excellent thermal stability and high color purity for white LEDs. Chem Eng J 2023, 456: 140901.
Xiang YF, Zhang HZ, Li JP, et al. Layered structure-induced quenching delay toward highly efficient and thermally stable red emission in Eu3+-activated borotellurate phosphors. J Mater Chem C 2024, 12: 2037–2047.
Zhu J, Yang TS, Li H, et al. Cationic composition engineering in double perovskite XLaLiTeO6: Eu3+ (X = Ba, Sr, Ca, and Mg) toward efficient and thermally stable red luminescence for domestic white-LEDs. J Mater Chem C 2023, 11: 11017–11026.
Binnemans K. Interpretation of europium(III) spectra. Coordin Chem Rev 2015, 295: 1–45.
Pan Y, Xie XJ, Huang QW, et al. Inherently Eu2+/Eu3+ codoped Sc2O3 nanoparticles as high-performance nanothermometers. Adv Mater 2018, 30: 1705256.
Huang S, Shang MM, Yan Y, et al. Regulation of local site structures to stabilize mixed-valence Eu2+/3+ under a reducing atmosphere for multicolor photoluminescence. Inorg Chem 2022, 61: 1756–1764.
Li S, Qiu ZX, Mo YH, et al. Self-reduction-induced BaMgP2O7:Eu2+/3+: A multi-stimuli-responsive phosphor for X-ray detection, anti-counterfeiting and optical thermometry. Dalton T 2022, 51: 6622–6630.
Yu H, Su WT, Chen LF, et al. Excellent temperature sensing characteristics of europium ions self-reduction Sr3P4O13 phosphors for ratiometric luminescence thermometer. J Alloys Compd 2019, 806: 833–840.
Kolesnikov IE, Afanaseva EV, Kurochkin MA, et al. Mixed-valent MgAl2O4:Eu2+/Eu3+ phosphor for ratiometric optical thermometry. Physica B 2022, 624: 413456.
Wang Y, Xiao J, Zhu HY, et al. Structural phase transition in monolayer MoTe2 driven by electrostatic doping. Nature 2017, 550: 487–491.
Ananias D, Paz FAA, Yufit DS, et al. Photoluminescent thermometer based on a phase-transition lanthanide silicate with unusual structural disorder. J Am Chem Soc 2015, 137: 3051–3058.
Yang N, Li JH, Zhang ZW, et al. Delayed concentration quenching of luminescence caused by Eu3+-induced phase transition in LaSc3(BO3)4. Chem Mater 2020, 32: 6958–6967.
Blöchl PE. Projector augmented-wave method. Phys Rev B 1994, 50: 17953–17979.
Perdew JP, Burke K, Ernzerhof M. Generalized gradient approximation made simple. Phys Rev Lett 1996, 77: 3865–3868.
Kresse G, Furthmüller J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Com Mater Sci 1996, 6: 15–50.
He MY, Wang G, Lin ZB, et al. Structure of medium temperature phase β-LaSc3(BO3)4 crystal. Mater Res Innov 1999, 2: 345–348.
Wang G, He MY, Chen WZ, et al. Structure of low temperature phase γ-LaSc3(BO3)4 crystal. Mater Res Innov 1999, 2: 341–344.
Shannon RD. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A 1976, A32: 751–767.
Qiao JW, Amachraa M, Molokeev M, et al. Engineering of K3YSi2O7 to tune photoluminescence with selected activators and site occupancy. Chem Mater 2019, 31: 7770–7778.
Yang ZY, Zhao YF, Zhou YY, et al. Giant red-shifted emission in (Sr,Ba)Y2O4:Eu2+ phosphor toward broadband near-infrared luminescence. Adv Funct Mater 2021, 32: 2103927.
Xie GD, Si JY, Li GH, et al. Environment-dependent Eu2+-activated Ba3CaK(PO4)3 toward white-light emission by chemical cosubstitution of the (BO3)3− anion group. Inorg Chem 2022, 61: 14845–14856.
Wang JB, Zhou XJ, Xiang GT, et al. The explanation of abnormal thermal quenching of the charge transfer band based on thermally coupled levels and applications as temperature sensing probes. Dalton T 2022, 51: 17224–17234.
Zhou XJ, Zhao SC, Li SY, et al. Luminescent properties of Eu3+-doped NaLaCaWO6 red phosphors and temperature sensing derived from the excited state of charge transfer band. J Lumin 2022, 248: 118964.
Yang N, Li Z, Zhang ZW, et al. A highly thermal-stable red-emitting tantalate phosphor for WLED and multiple-mode optical temperature sensor dual-applications. Ceram Int 2024, 50: 6880–6891.
Zhou LH, Lyu ZY, Sun DS, et al. Enhanced thermal stability and energy transfer by crystal-field engineering in a garnet phosphor for thermometry and NIR-LED. Adv Opt Mater 2022, 10: 2201308.
Zhang ZW, Yan J, Zhang QH, et al. Enlarging sensitivity of fluorescence intensity ratio-type thermometers by the interruption of the energy transfer from a sensitizer to an activator. Inorg Chem 2022, 61: 16484–16492.
Dong LP, Zhang L, Jia YC, et al. ZnGa2− y Al y O4:Mn2+,Mn4+ thermochromic phosphors: Valence state control and optical temperature sensing. Inorg Chem 2020, 59: 15969–15976.
Ruan FP, Deng DG, Wu M, et al. Multichannel luminescence of Eu2+/Eu3+ co-activated Ca9Mg1.5(PO4)7 phosphors for self-referencing optical thermometry. J Lumin 2019, 213: 117–126.
Yu H, Ruan FP, Chen LF, et al. Dual-emitting Eu2+/Eu3+ co-doped Ca9Zn1.5(PO4)7 phosphor for self-calibrated optical thermometry. Opt Mater 2020, 100: 109678.
Xue JP, Song MJ, Noh HM, et al. Achieving non-contact optical thermometer via inherently Eu2+/Eu3+-activated SrAl2Si2O8 phosphors prepared in air. J Alloys Compd 2020, 843: 155858.
Guo HJ, Chen YQ, Wang L, et al. Utilizing diametrically opposite thermal quenching luminescence to achieve highly sensitive temperature measurement and anti-counterfeiting. Inorg Chem Front 2024, 11: 799–807.
Meng ZC, Gao Y, Song JA, et al. Tetrahedrally coordinated rigid crystal structure enables partial self-reduction of mixed-valence europium for optical thermometric application. Dalton T 2023, 52: 5443–5452.
Xue JP, Noh HM, Choi BC, et al. Dual-functional of non-contact thermometry and field emission displays via efficient Bi3+→Eu3+ energy transfer in emitting-color tunable GdNbO4 phosphors. Chem Eng J 2020, 382: 122861.
Zhang XB, Xu YH, Wu XD, et al. Optical thermometry and multi-mode anti-counterfeiting based on Bi3+/Ln3+ and Ln3+ doped Ca2ScSbO6 phosphors. Chem Eng J 2024, 481: 148717.
Xiang YF, Yang L, Liao CY, et al. Thermometric properties of Na2Y2TeB2O10:Tb3+ green phosphor based on fluorescence/excitation intensity ratio. J Adv Ceram 2023, 12: 848–860.
Du P, Hua YB, Yu JS. Energy transfer from VO43− group to Sm3+ ions in Ba3(VO4)2:3 xSm3+ microparticles: A bifunctional platform for simultaneous optical thermometer and safety sign. Chem Eng J 2018, 352: 352–359.
Fu Y, Li C, Zhang F, et al. Site preference and the optical thermometry strategy by different temperature response from two sites environment of Mn2+ in K7ZnSc2B15O30. Chem Eng J 2021, 409: 128190.
Liu DX, Zeng CY, Wang J, et al. Site preference induced dual-wavelength Mn2+ upconversion in K2NaScF6:Yb3+,Mn2+ and its application in temperature sensing. Adv Opt Mater 2024, 12: 2302819.
Zhang H, Liang YJ, Yang H, et al. Highly sensitive dual-mode optical thermometry in double-perovskite oxides via Pr3+/Dy3+ energy transfer. Inorg Chem 2020, 59: 14337–14346.
Zheng T, Luo L, Du P, et al. Highly-efficient double perovskite Mn4+-activated Gd2ZnTiO6 phosphors: A bifunctional optical sensing platform for luminescence thermometry and manometry. Chem Eng J 2022, 446: 136839.
Xie CY, Wang P, Lin Y, et al. Temperature-dependent luminescence of a phosphor mixture of Li2TiO3:Mn4+ and Y2O3:Dy3+ for dual-mode optical thermometry. J Alloys Compd 2020, 821: 153467.
Qiu LT, Wang P, Mao JS, et al. Cr3+-doped InTaO4 phosphor for multi-mode temperature sensing with high sensitivity in a physiological temperature range. Inorg Chem Front 2022, 9: 3187–3199.
Wu M, Deng DG, Ruan FP, et al. A spatial/temporal dual-mode optical thermometry based on double-sites dependent luminescence of Li4SrCa(SiO4)2:Eu2+ phosphors with highly sensitive luminescent thermometer. Chem Eng J 2020, 396: 125178.
Wang XL, Jahanbazi F, Wei JL, et al. Charge transfer-triggered Bi3+ near-infrared emission in Y2Ti2O7 for dual-mode temperature sensing. ACS Appl Mater Inter 2022, 14: 36834–36844.
Xia WD, Li L, Hua YB, et al. Realizing dual-mode luminescent thermometry with excellent sensing sensitivity in single-phase samarium(III)-doped antimonite phosphors. J Alloys Compd 2022, 917: 165435.
Song MJ, Wang LT, Wang JC, et al. Constructing double perovskite Eu3+/Mn4+-codoped La2Mg1.33Ta0.67O6 phosphors for high sensitive dual-mode optical thermometers. J Lumin 2022, 252: 119347.
Liao JS, Wang MH, Kong LY, et al. Dual-mode optical temperature sensing behavior of double-perovskite CaGdMgSbO6:Mn4+/Sm3+ phosphors. J Lumin 2020, 226: 117492.
Chen YL, Shen YY, Zhou LY, et al. Temperature-dependent luminescence of Bi3+,Eu3+ co-activated La2MgGeO6 phosphor for dual-mode optical thermometry. J Lumin 2022, 249: 118995.
Zhu YT, Li CX, Deng DG, et al. A high-sensitivity dual-mode optical thermometry based on one-step synthesis of Mn2+:BaAl12O19–Mn4+:SrAl12O19 solid solution phosphors. J Alloys Compd 2021, 853: 157262.
Wu ZJ, Li L, Tian G, et al. High-sensitivity and wide-temperature-range dual-mode optical thermometry under dual-wavelength excitation in a novel double perovskite tellurate oxide. Dalton T 2021, 50: 11412–11421.
Fu J, Zhou LY, Chen YL, et al. Dual-mode optical thermometry based on Bi3+/Sm3+ co-activated BaGd2O4 phosphor with tunable sensitivity. J Alloys Compd 2022, 897: 163034.
Zhu YT, Li CX, Deng DG, et al. High-sensitivity based on Eu2+/Cr3+ co-doped BaAl12O19 phosphors for dual-mode optical thermometry. J Lumin 2021, 237: 118142.
Chen YB, He J, Zhang XG, et al. Dual-mode optical thermometry design in Lu3Al5O12:Ce3+/Mn4+ phosphor. Inorg Chem 2020, 59: 1383–1392.
851
Views
139
Downloads
1
Crossref
1
Web of Science
1
Scopus
0
CSCD
Altmetrics
This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, http://creativecommons.org/licenses/by/4.0/).
京公网安备11010802044758号