AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
{{expandStatus?'Exit ':''}}Advanced Search
The coordinated development of new energy vehicles and the energy storage industry has become essential for reducing carbon emissions. The cathode material is the key material that determines the energy density and cost of a power battery, but currently developed and applied cathode materials cannot meet the requirements for high specific capacity, low cost, safety, and good stability. High-entropy materials (HEMs) are a new type of single-phase material composed of multiple principal elements in equimolar or near-equimolar ratios. The interaction between multiple elements can play an important role in improving the comprehensive properties of the material, which is expected to solve the limitations of battery materials in practical applications. Therefore, this review provides a comprehensive overview of the current development status and modification strategies of power batteries (lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs)), proposes a high-entropy design strategy, and analyses the structure–activity relationship between the high-entropy effects and battery performance. Finally, future research topics related to high-entropy cathode materials, including computational guide design, specific synthesis methods, high-entropy electrochemistry, and high-throughput databases, are proposed. This review aims to provide practical guidance for the development of high-entropy cathode materials for next-generation power batteries.
Wei XX, Ban SN, Shi XL, et al. Carbon and energy storage in salt caverns under the background of carbon neutralization in China. Energy 2023, 272: 127120.
Tabelin CB, Dallas J, Casanova S, et al. Towards a low-carbon society: A review of lithium resource availability, challenges and innovations in mining, extraction and recycling, and future perspectives. Miner Eng 2021, 163: 106743.
Nayak PK, Yang LT, Brehm W, et al. From lithium-ion to sodium-ion batteries: Advantages, challenges, and surprises. Angew Chem Int Ed 2018, 57: 102–120.
Wang TY, Su DW, Shanmukaraj D, et al. Electrode materials for sodium-ion batteries: Considerations on crystal structures and sodium storage mechanisms. Electrochem Energy Rev 2018, 1: 200–237.
Zhang LP, Li XL, Yang MR, et al. High-safety separators for lithium-ion batteries and sodium-ion batteries: Advances and perspective. Energy Storage Mater 2021, 41: 522–545.
Li JL, Fleetwood J, Hawley WB, et al. From materials to cell: State-of-the-art and prospective technologies for lithium-ion battery electrode processing. Chem Rev 2022, 122: 903–956.
Song J, Wang HC, Zuo YX, et al. Building better full manganese-based cathode materials for next-generation lithium-ion batteries. Electrochem Energy Rev 2023, 6: 20.
Fang YJ, Xiao LF, Chen ZX, et al. Recent advances in sodium-ion battery materials. Electrochem Energy Rev 2018, 1: 294–323.
Nitta N, Wu FX, Lee JT, et al. Li-ion battery materials: Present and future. Mater Today 2015, 18: 252–264.
Manthiram A. A reflection on lithium-ion battery cathode chemistry. Nat Commun 2020, 11: 1550.
Tian ZC, Yu H, Zhang Z, et al. Performance improvements of cobalt oxide cathodes for rechargeable lithium batteries. ChemBioEng Rev 2018, 5: 111–118.
Wang K, Wan JJ, Xiang YX, et al. Recent advances and historical developments of high voltage lithium cobalt oxide materials for rechargeable Li-ion batteries. J Power Sources 2020, 460: 228062.
Konar R, Maiti S, Shpigel N, et al. Reviewing failure mechanisms and modification strategies in stabilizing high-voltage LiCoO2 cathodes beyond 4.55 V. Energy Storage Mater 2023, 63: 103001.
Marincaş AH, Goga F, Dorneanu SA, et al. Review on synthesis methods to obtain LiMn2O4-based cathode materials for Li-ion batteries. J Solid State Electrochem 2020, 24: 473–497.
Thackeray MM, Lee E, Shi BY, et al. Review–From LiMn2O4 to partially-disordered Li2MnNiO4: The evolution of lithiated-spinel cathodes for Li-ion batteries. J Electrochem Soc 2022, 169: 020535.
Kumar J, Neiber RR, Park J, et al. Recent progress in sustainable recycling of LiFePO4-type lithium-ion batteries: Strategies for highly selective lithium recovery. Chem Eng J 2022, 431: 133993.
Chang LJ, Yang W, Cai KD, et al. A review on nickel-rich nickel-cobalt-manganese ternary cathode materials LiNi0.6Co0.2Mn0.2O2 for lithium-ion batteries: Performance enhancement by modification. Mater Horiz 2023, 10: 4776–4826.
Kotal M, Jakhar S, Roy S, et al. Cathode materials for rechargeable lithium batteries: Recent progress and future prospects. J Energy Storage 2022, 47: 103534.
Liu QN, Hu Z, Li WJ, et al. Sodium transition metal oxides: The preferred cathode choice for future sodium-ion batteries. Energy Environ Sci 2021, 14: 158–179.
Wang PF, You Y, Yin YX, et al. Layered oxide cathodes for sodium-ion batteries: Phase transition, air stability, and performance. Adv Energy Mater 2018, 8: 1701912.
Liu QN, Hu Z, Chen MZ, et al. The cathode choice for commercialization of sodium-ion batteries: Layered transition metal oxides versus Prussian blue analogs. Adv Funct Mater 2020, 30: 1909530.
Chen T, Ouyang BX, Fan XW, et al. Oxide cathodes for sodium-ion batteries: Designs, challenges, and perspectives. Carbon Energy 2022, 4: 170–199.
Yang W, Liu Q, Zhao YS, et al. Progress on Fe-based polyanionic oxide cathodes materials toward grid-scale energy storage for sodium-ion batteries. Small Meth 2022, 6: 2200555.
Lv ZQ, Ling MX, Yue M, et al. Vanadium-based polyanionic compounds as cathode materials for sodium-ion batteries: Toward high-energy and high-power applications. J Energy Chem 2021, 55: 361–390.
Peng J, Zhang W, Liu QN, et al. Prussian blue analogues for sodium-ion batteries: Past, present, and future. Adv Mater 2022, 34: 2108384.
Hurlbutt K, Wheeler S, Capone I, et al. Prussian blue analogs as battery materials. Joule 2018, 2: 1950–1960.
Du GY, Pang H. Recent advancements in Prussian blue analogues: Preparation and application in batteries. Energy Storage Mater 2021, 36: 387–408.
Xie BX, Sun BY, Gao TY, et al. Recent progress of Prussian blue analogues as cathode materials for nonaqueous sodium-ion batteries. Coord Chem Rev 2022, 460: 214478.
Han MH, Gonzalo E, Singh G, et al. A comprehensive review of sodium layered oxides: Powerful cathodes for Na-ion batteries. Energy Environ Sci 2015, 8: 81–102.
Liu YF, Han K, Peng DN, et al. Layered oxide cathodes for sodium-ion batteries: From air stability, interface chemistry to phase transition. InfoMat 2023, 5: e12422.
Jin T, Li HX, Zhu KJ, et al. Polyanion-type cathode materials for sodium-ion batteries. Chem Soc Rev 2020, 49: 2342–2377.
Zhao LN, Zhang T, Zhao HL, et al. Polyanion-type electrode materials for advanced sodium-ion batteries. Mater Today Nano 2020, 10: 100072.
Fayaz M, Lai WD, Li J, et al. Prussian blue analogues and their derived materials for electrochemical energy storage: Promises and Challenges. Mater Res Bull 2024, 170: 112593.
Li WJ, Han C, Cheng G, et al. Chemical properties, structural properties, and energy storage applications of Prussian blue analogues. Small 2019, 15: 1900470.
Whittingham MS. Electrical energy storage and intercalation chemistry. Science 1976, 192: 1126–1127.
Westlake DG. Hydrides of intermetallic compounds: A review of stabilities, stoichiometries and preferred hydrogen sites. J Less Common Met 1983, 91: 1–20.
Padhi AK, Nanjundaswamy KS, Goodenough JB. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc 1997, 144: 1188–1194.
Mizushima K, Jones PC, Wiseman PJ, et al. Li x CoO2 (0 < x < −1): A new cathode material for batteries of high energy density. Mater Res Bull 1980, 15: 783–789.
Liu ZL, Yu AS, Lee JY. Synthesis and characterization of LiNi1− x − y Co x Mn y O2 as the cathode materials of secondary lithium batteries. J Power Sources 1999, 81: 416–419.
Ohzuku T, Makimura Y. Layered lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for lithium-ion batteries. Chem Lett 2001, 30: 642–643.
Oh SW, Park SH, Park CW, et al. Structural and electrochemical properties of layered Li[Ni0.5Mn0.5]1− x Co x O2 positive materials synthesized by ultrasonic spray pyrolysis method. Solid State Ionics 2004, 171: 167–172.
Liao PY, Duh JG, Sheen SR. Microstructure and electrochemical performance of LiNi0.6Co0.4− x Mn x O2 cathode materials. J Power Sources 2005, 143: 212–218.
Kim MH, Shin HS, Shin D, et al. Synthesis and electrochemical properties of Li[Ni0.8Co0.1Mn0.1]O2 and Li[Ni0.8Co0.2]O2 via co-precipitation. J Power Sources 2006, 159: 1328–1333.
Sun C, Zhao B, Mao J, et al. Enhanced cycling stability of 4.6 V LiCoO2 cathodes by inhibiting catalytic activity of its interface via MXene modification. Adv Funct Mater 2023, 33: 2300589.
Yano A, Taguchi N, Kanzaki H, et al. Capability and reversibility of LiCoO2 during charge/discharge with O3/H1–3 layered structure change. J Electrochem Soc 2021, 168: 050517.
Zhang YL, Zhang WJ, Zhou JK, et al. Research development on spinel lithium manganese oxides cathode materials for lithium-ion batteries. J Electrochem Soc 2023, 170: 090532.
Yang ZG, Dai Y, Wang SP, et al. How to make lithium iron phosphate better: A review exploring classical modification approaches in-depth and proposing future optimization methods. J Mater Chem A 2016, 4: 18210–18222.
Ellis BL, Lee KT, Nazar LF. Positive electrode materials for Li-ion and Li-batteries. Chem Mater 2010, 22: 691–714.
Li JX, Liang GM, Zheng W, et al. Addressing cation mixing in layered structured cathodes for lithium-ion batteries: A critical review. Nano Mater Sci 2023, 5: 404–420.
Liu JW, Yue M, Wang SQ, et al. A review of performance attenuation and mitigation strategies of lithium-ion batteries. Adv Funct Mater 2022, 32: 2107769.
Fu CC, Li GS, Luo D, et al. Nickel-rich layered microspheres cathodes: Lithium/nickel disordering and electrochemical performance. ACS Appl Mater Inter 2014, 6: 15822–15831.
Qian GN, Zhang YT, Li LS, et al. Single-crystal nickel-rich layered-oxide battery cathode materials: Synthesis, electrochemistry, and intra-granular fracture. Energy Storage Mater 2020, 27: 140–149.
Shi JL, Sheng H, Meng XH, et al. Size controllable single-crystalline Ni-rich cathodes for high-energy lithium-ion batteries. Natl Sci Rev 2023, 10: nwac226.
Langdon J, Manthiram A. A perspective on single-crystal layered oxide cathodes for lithium-ion batteries. Energy Storage Mater 2021, 37: 143–160.
Yao YFY, Kummer JT. Ion exchange properties of and rates of ionic diffusion in beta-alumina. J Inorg Nucl Chem 1967, 29: 2453–2475.
Coetzer J. A new high energy density battery system. J Power Sources 1986, 18: 377–380.
Mendiboure A, Delmas C, Hagenmuller P. Electrochemical intercalation and deintercalation of Na x MnO2 bronzes. J Solid State Chem 1985, 57: 323–331.
Newman GH, Klemann LP. Ambient temperature cycling of an Na–TiS2 cell. J Electrochem Soc 1980, 127: 2097–2099.
Delmas C, Braconnier JJ, Fouassier C, et al. Electrochemical intercalation of sodium in Na x CoO2 bronzes. Solid State Ionics 1981, 3: 165–169.
Stevens DA, Dahn JR. High capacity anode materials for rechargeable sodium-ion batteries. J Electrochem Soc 2000, 147: 1271.
Ellis BL, Makahnouk WRM, Makimura Y, et al. A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries. Nat Mater 2007, 6: 749–753.
Komaba S, Murata W, Ishikawa T, et al. Electrochemical Na insertion and solid electrolyte interphase for hard-carbon electrodes and application to Na-ion batteries. Adv Funct Mater 2011, 21: 3859–3867.
Lee H, Kim YI, Park JK, et al. Sodium zinc hexacyanoferrate with a well-defined open framework as a positive electrode for sodium ion batteries. Chem Commun 2012, 48: 8416–8418.
Lu YH, Wang L, Cheng JG, et al. Prussian blue: A new framework of electrode materials for sodium batteries. Chem Commun 2012, 48: 6544–6546.
Xu SY, Wu XY, Li YM, et al. Novel copper redox-based cathode materials for room-temperature sodium-ion batteries. Chinese Phys B 2014, 23: 118202.
Lu YX, Rong XH, Hu YS, et al. Research and development of advanced battery materials in China. Energy Storage Mater 2019, 23: 144–153.
Liu TF, Zhang YP, Jiang ZG, et al. Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage. Energy Environ Sci 2019, 12: 1512–1533.
Lee W, Kim J, Yun S, et al. Multiscale factors in designing alkali-ion (Li, Na, and K) transition metal inorganic compounds for next-generation rechargeable batteries. Energy Environ Sci 2020, 13: 4406–4449.
Wang SH, Sun CL, Wang N, et al. Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: Status, challenges and countermeasures. J Mater Chem A 2019, 7: 10138–10158.
Chen MZ, Liu QN, Wang SW, et al. High-abundance and low-cost metal-based cathode materials for sodium-ion batteries: Problems, progress, and key technologies. Adv Energy Mater 2019, 9: 1803609.
Xiang XD, Lu YY, Chen J. Advance and prospect of functional materials for sodium ion batteries. Acta Chim Sinica 2017, 75: 154.
Liu QN, Hu Z, Chen MZ, et al. Recent progress of layered transition metal oxide cathodes for sodium-ion batteries. Small 2019, 15: 1805381.
Usiskin R, Lu YX, Popovic J, et al. Fundamentals, status and promise of sodium-based batteries. Nat Rev Mater 2021, 6: 1020–1035.
Zuo WH, Yang Y. Synthesis, structure, electrochemical mechanisms, and atmospheric stability of Mn-based layered oxide cathodes for sodium ion batteries. Acc Mater Res 2022, 3: 709–720.
Wang H, Liao XZ, Yang Y, et al. Large-scale synthesis of NaNi1/3Fe1/3Mn1/3O2 as high performance cathode materials for sodium ion batteries. J Electrochem Soc 2016, 163: A565–A570.
Zuo WH, Liu XS, Qiu JM, et al. Engineering Na+-layer spacings to stabilize Mn-based layered cathodes for sodium-ion batteries. Nat Commun 2021, 12: 4903.
Zuo WH, Qiu JM, Liu XS, et al. The stability of P2-layered sodium transition metal oxides in ambient atmospheres. Nat Commun 2020, 11: 3544.
Ni Q, Bai Y, Wu F, et al. Polyanion-type electrode materials for sodium-ion batteries. Adv Sci 2017, 4: 1600275.
Xu CL, Xiao RJ, Zhao JM, et al. Mn-rich phosphate cathodes for Na-ion batteries with superior rate performance. ACS Energy Lett 2022, 7: 97–107.
Zheng Q, Ni X, Lin L, et al. Towards enhanced sodium storage by investigation of the Li ion doping and rearrangement mechanism in Na3V2(PO4)3 for sodium ion batteries. J Mater Chem A 2018, 6: 4209–4218.
Ling MX, Li F, Yi HM, et al. Superior Na-storage performance of molten-state-blending-synthesized monoclinic NaVPO4F nanoplates for Na-ion batteries. J Mater Chem A 2018, 6: 24201–24209.
Hao ZQ, Shi XY, Yang Z, et al. The distance between phosphate-based polyanionic compounds and their practical application for sodium-ion batteries. Adv Mater 2024, 36: 2305135.
Lan YQ, Yao WJ, He XL, et al. Mixed polyanionic compounds as positive electrodes for low-cost electrochemical energy storage. Angew Chem Int Ed 2020, 59: 9255–9262.
Buser HJ, Schwarzenbach D, Petter W, et al. The crystal structure of Prussian blue: Fe4[Fe(CN)6]3· xH2O. Inorg Chem 1977, 16: 2704–2710.
You Y, Wu XL, Yin YX, et al. High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ Sci 2014, 7: 1643–1647.
Song QY, Li ZY, Gan SJ, et al. Progress and challenges of Prussian blue analogs for potassium-ion batteries: A perspective on redox-active transition metals. J Mater Chem A 2023, 11: 1532–1550.
Wan P, Xie H, Zhang N, et al. Stepwise hollow Prussian blue nanoframes/carbon nanotubes composite film as ultrahigh rate sodium ion cathode. Adv Funct Mater 2020, 30: 2002624.
Paolella A, Faure C, Timoshevskii V, et al. A review on hexacyanoferrate-based materials for energy storage and smart windows: Challenges and perspectives. J Mater Chem A 2017, 5: 18919–18932.
Peng J, Ou MY, Yi HC, et al. Defect-free-induced Na+ disordering in electrode materials. Energy Environ Sci 2021, 14: 3130–3140.
Heck CA, von Horstig MW, Huttner F, et al. Review—Knowledge-based process design for high quality production of NCM811 cathodes. J Electrochem Soc 2020, 167: 160521.
Hu MF, Wu HZ, Zhang GJ. High-performance silicon/graphite anode prepared by CVD using SiCl4 as precursor for Li-ion batteries. Chem Phys Lett 2023, 833: 140917.
Ko G, Jeong S, Park S, et al. Doping strategies for enhancing the performance of lithium nickel manganese cobalt oxide cathode materials in lithium-ion batteries. Energy Storage Mater 2023, 60: 102840.
Nisar U, Muralidharan N, Essehli R, et al. Valuation of surface coatings in high-energy density lithium-ion battery cathode materials. Energy Storage Mater 2021, 38: 309–328.
Chen ZX, Zhang WX, Yang ZH. A review on cathode materials for advanced lithium ion batteries: Microstructure designs and performance regulations. Nanotechnology 2020, 31: 012001.
Hu MF, Ma YJ, Wu HZ, et al. Inlaying silicon in SiC-derived graphite with unique cavity structure as a high-capacity anode for Li-ion batteries. J Electrochem Soc 2023, 170: 060549.
Li LJ, Chen ZY, Zhang QB, et al. A hydrolysis–hydrothermal route for the synthesis of ultrathin LiAlO2-inlaid LiNi0.5Co0.2Mn0.3O2 as a high-performance cathode material for lithium ion batteries. J Mater Chem A 2015, 3: 894–904.
Yi HM, Lin L, Ling MX, et al. Scalable and economic synthesis of high-performance Na3V2(PO4)2F3 by a solvothermal-ball-milling method. ACS Energy Lett 2019, 4: 1565–1571.
He SL, Zhao JM, Rong XH, et al. Solvent-free mechanochemical synthesis of Na-rich Prussian white cathodes for high-performance Na-ion batteries. Chem Eng J 2022, 428: 131083.
Shen X, Zhou Q, Han M, et al. Rapid mechanochemical synthesis of polyanionic cathode with improved electrochemical performance for Na-ion batteries. Nat Commun 2021, 12: 2848.
Ahaliabadeh Z, Kong XZ, Fedorovskaya E, et al. Extensive comparison of doping and coating strategies for Ni-rich positive electrode materials. J Power Sources 2022, 540: 231633.
Wang WL, Gang Y, Peng J, et al. Effect of eliminating water in Prussian blue cathode for sodium-ion batteries. Adv Funct Mater 2022, 32: 2111727.
Peng J, Wang JS, Yi HC, et al. A dual-insertion type sodium-ion full cell based on high-quality ternary-metal Prussian blue analogs. Adv Energy Mater 2018, 8: 1702856.
Shang Y, Li XX, Song JJ, et al. Unconventional Mn vacancies in Mn–Fe Prussian blue analogs: Suppressing Jahn–Teller distortion for ultrastable sodium storage. Chem 2020, 6: 1804–1818.
Ren WH, Zhu ZX, Qin MS, et al. Prussian white hierarchical nanotubes with surface-controlled charge storage for sodium-ion batteries. Adv Funct Mater 2019, 29: 1806405.
Wu XY, Wu CH, Wei CX, et al. Highly crystallized Na2CoFe(CN)6 with suppressed lattice defects as superior cathode material for sodium-ion batteries. ACS Appl Mater Inter 2016, 8: 5393–5399.
Huang YX, Xie M, Zhang JT, et al. A novel border-rich Prussian blue synthetized by inhibitor control as cathode for sodium ion batteries. Nano Energy 2017, 39: 273–283.
Wan M, Zeng R, Meng JT, et al. Post-synthetic and in situ vacancy repairing of iron hexacyanoferrate toward highly stable cathodes for sodium-ion batteries. Nano-Micro Lett 2021, 14: 9.
Yue YF, Binder AJ, Guo BK, et al. Mesoporous Prussian blue analogues: Template-free synthesis and sodium-ion battery applications. Angew Chem Int Edit 2014, 53: 3134–3137.
Xie BX, Wang LG, Shu J, et al. Understanding the structural evolution and lattice water movement for rhombohedral nickel hexacyanoferrate upon sodium migration. ACS Appl Mater Inter 2019, 11: 46705–46713.
Zhang X, Ju ZY, Zhu Y, et al. Multiscale understanding and architecture design of high energy/power lithium-ion battery electrodes. Adv Energy Mater 2021, 11: 2000808.
Pomerantseva E, Bonaccorso F, Feng XL, et al. Energy storage: The future enabled by nanomaterials. Science 2019, 366: eaan8285.
Kalluri S, Seng KH, Pang WK, et al. Electrospun P2-type Na2/3(Fe1/2Mn1/2)O2 hierarchical nanofibers as cathode material for sodium-ion batteries. ACS Appl Mater Inter 2014, 6: 8953–8958.
Lin LL, Zhang LH, Wang SW, et al. Micro- and nano-structural design strategies towards polycrystalline nickel-rich layered cathode materials. J Mater Chem A 2023, 11: 7867–7897.
Su MF, Shi JW, Kang QL, et al. One-step multiple structure modulations on sodium vanadyl phosphate@carbon towards ultra-stable high rate sodium storage. Chem Eng J 2022, 432: 134289.
Huang YX, Xie M, Wang ZH, et al. A chemical precipitation method preparing hollow-core–shell heterostructures based on the Prussian blue analogs as cathode for sodium-ion batteries. Small 2018, 14: 1801246.
Peng MH, Zhang DT, Zheng LM, et al. Hierarchical Ru-doped sodium vanadium fluorophosphates hollow microspheres as a cathode of enhanced superior rate capability and ultralong stability for sodium-ion batteries. Nano Energy 2017, 31: 64–73.
Chen C, Han Z, Chen SQ, et al. Core–shell layered oxide cathode for high-performance sodium-ion batteries. ACS Appl Mater Inter 2020, 12: 7144–7152.
Li HQ, Zhou HS. Enhancing the performances of Li-ion batteries by carbon-coating: Present and future. Chem Commun 2012, 48: 1201–1217.
Jiang GD, Hu ZH, Xiong J, et al. Enhanced performance of LiFePO4 originating from the synergistic effect of graphene modification and carbon coating. J Alloys Compd 2018, 767: 528–537.
Wang XF, Feng ZJ, Huang JT, et al. Graphene-decorated carbon-coated LiFePO4 nanospheres as a high-performance cathode material for lithium-ion batteries. Carbon 2018, 127: 149–157.
Gu ZY, Guo JZ, Sun ZH, et al. Carbon-coating-increased working voltage and energy density towards an advanced Na3V2(PO4)2F3@C cathode in sodium-ion batteries. Sci Bull 2020, 65: 702–710.
Zhang HM, Huang YX, Ming H, et al. Recent advances in nanostructured carbon for sodium-ion batteries. J Mater Chem A 2020, 8: 1604–1630.
Hall DS, Gauthier R, Eldesoky A, et al. New chemical insights into the beneficial role of Al2O3 cathode coatings in lithium-ion cells. ACS Appl Mater Inter 2019, 11: 14095–14100.
Shobana MK. Metal oxide coated cathode materials for Li ion batteries—A review. J Alloys Compd 2019, 802: 477–487.
Liu YH, Zhang YH, Ma J, et al. Challenges and strategies toward practical application of layered transition metal oxide cathodes for sodium-ion batteries. Chem Mater 2024, 36: 54–73.
Zhao QQ, Wang RR, Gao M, et al. Interfacial engineering of the layered oxide cathode materials for sodium-ion battery. Nano Res 2024, 17: 1441–1464.
Hwang JY, Yu TY, Sun YK. Simultaneous MgO coating and Mg doping of Na[Ni0.5Mn0.5]O2 cathode: Facile and customizable approach to high-voltage sodium-ion batteries. J Mater Chem A 2018, 6: 16854–16862.
Li WJ, Chou SL, Wang JZ, et al. Multifunctional conducing polymer coated Na1+ x MnFe(CN)6 cathode for sodium-ion batteries with superior performance via a facile and one-step chemistry approach. Nano Energy 2015, 13: 200–207.
Chen X, Zhao CC, Yang K, et al. Conducting polymers meet lithium-sulfur batteries: Progress, challenges, and perspectives. Energy & Environ Mater 2023, 6: e12483.
Liu Y, He DD, Cheng YJ, et al. A heterostructure coupling of bioinspired, adhesive polydopamine, and porous Prussian blue nanocubics as cathode for high-performance sodium-ion battery. Small 2020, 16: 1906946.
Zhang ZZ, Nazar LF. Exploiting the paddle-wheel mechanism for the design of fast ion conductors. Nat Rev Mater 2022, 7: 389–405.
Park JH, Cho JH, Kim SB, et al. A novel ion-conductive protection skin based on polyimide gel polymer electrolyte: Application to nanoscale coating layer of high voltage LiNi1/3Co1/3Mn1/3O2 cathode materials for lithium-ion batteries. J Mater Chem 2012, 22: 12574–12581.
Kwon Y, Lee Y, Kim SO, et al. Conducting polymer coating on a high-voltage cathode based on soft chemistry approach toward improving battery performance. ACS Appl Mater Inter 2018, 10: 29457–29466.
Cao YB, Qi XY, Hu KH, et al. Conductive polymers encapsulation to enhance electrochemical performance of Ni-rich cathode materials for Li-ion batteries. ACS Appl Mater Inter 2018, 10: 18270–18280.
Ren QQ, Yuan YF, Wang S. Interfacial strategies for suppression of Mn dissolution in rechargeable battery cathode materials. ACS Appl Mater Inter 2022, 14: 23022–23032.
Shi SJ, Tu JP, Tang YY, et al. Enhanced cycling stability of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 by surface modification of MgO with melting impregnation method. Electrochim Acta 2013, 88: 671–679.
Wang ZY, Huang SS, Chen BJ, et al. Infiltrative coating of LiNi0.5Co0.2Mn0.3O2 microspheres with layer-structured LiTiO2: Towards superior cycling performances for Li-ion batteries. J Mater Chem A 2014, 2: 19983–19987.
Jiang HR, Qian GD, Liu R, et al. Effects of elemental doping on phase transitions of manganese-based layered oxides for sodium-ion batteries. Sci China Mater 2023, 66: 4542–4549.
Yan WW, Yang SY, Huang YY, et al. A review on doping/coating of nickel-rich cathode materials for lithium-ion batteries. J Alloys Compd 2020, 819: 153048.
Dou SM, Tan D, Li P, et al. Research progress and prospect in element doping of lithium-rich layered oxides as cathode materials for lithium-ion batteries. J Solid State Electr 2023, 27: 1–23.
Chen SP, Lv D, Chen J, et al. Review on defects and modification methods of LiFePO4 cathode material for lithium-ion batteries. Energy Fuels 2022, 36: 1232–1251.
He F, Kang JY, Liu TL, et al. Research progress on electrochemical properties of Na3V2(PO4)3 as cathode material for sodium-ion batteries. Ind Eng Chem Res 2023, 62: 3444–3464.
Xu ZR, Gao LB, Liu YJ, et al. Review—Recent developments in the doped LiFePO4 cathode materials for power lithium ion batteries. J Electrochem Soc 2016, 163: A2600–A2610.
Zhang BF, Ma XN, Hou WQ, et al. Revealing the ultrahigh rate performance of the La and Ce co-doping LiFePO4 composite. ACS Appl Energy Mater 2022, 5: 14712–14719.
Chung SY, Bloking JT, Chiang YM. Electronically conductive phospho-olivines as lithium storage electrodes. Nat Mater 2002, 1: 123–128.
Lee H, Kim S, Parmar NS, et al. Carbon-free Mn-doped LiFePO4 cathode for highly transparent thin-film batteries. J Power Sources 2019, 434: 226713.
Örnek A, Efe O. Doping qualifications of LiFe1− x Mg x PO4–C nano-scale composite cathode materials. Electrochim Acta 2015, 166: 338–349.
Goonetilleke D, Faulkner T, Peterson VK, et al. Structural evidence for Mg-doped LiFePO4 electrode polarisation in commercial Li-ion batteries. J Power Sources 2018, 394: 1–8.
Zhang Y, Shao ZC, Zhang Y. Preparation of Mo-doping LiFePO4/C by carbon reduction method. Mater Manuf Process 2021, 36: 419–425.
Kim S, Mathew V, Kang J, et al. High rate capability of LiFePO4 cathodes doped with a high amount of Ti. Ceram Int 2016, 42: 7230–7236.
Liu XH, Feng GL, Wang EH, et al. Insight into preparation of Fe-doped Na3V2(PO4)3@C from aspects of particle morphology design, crystal structure modulation, and carbon graphitization regulation. ACS Appl Mater Inter 2019, 11: 12421–12430.
Soundharrajan V, Alfaruqi MH, Lee S, et al. Multidimensional Na4VMn0.9Cu0.1(PO4)3/C cotton-candy cathode materials for high energy Na-ion batteries. J Mater Chem A 2020, 8: 12055–12068.
Li XJ, Xin HX, Liu YF, et al. Effect of niobium doping on the microstructure and electrochemical properties of lithium-rich layered Li[Li0.2Ni0.2Mn0.6]O2 as cathode materials for lithium ion batteries. RSC Adv 2015, 5: 45351–45358.
Hu HL, He HC, Xie RK, et al. Achieving reversible Mn2+/Mn4+ double redox couple through anionic substitution in a P2-type layered oxide cathode. Nano Energy 2022, 99: 107390.
Wang K, Zhuo HX, Wang JT, et al. Recent advances in Mn-rich layered materials for sodium-ion batteries. Adv Funct Mater 2023, 33: 2212607.
Yu TY, Kim J, Oh G, et al. High-voltage stability of O3-type sodium layered cathode enabled by preferred occupation of Na in the OP2 phase. Energy Storage Mater 2023, 61: 102908.
Assat G, Tarascon JM. Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries. Nat Energy 2018, 3: 373–386.
Su YF, Chen G, Chen L, et al. High-rate structure-gradient Ni-rich cathode material for lithium-ion batteries. ACS Appl Mater Inter 2019, 11: 36697–36704.
Kim DH, Song JH, Jung CH, et al. Stepwise dopant selection process for high-nickel layered oxide cathodes. Adv Energy Mater 2022, 12: 2200136.
Liu XY, Cao Y, Sun J. Defect engineering in Prussian blue analogs for high-performance sodium-ion batteries. Adv Energy Mater 2022, 12: 2202532.
Zhang ZS, Liu YQ, Liu ZX, et al. Dual-strategy of Cu-doping and O3 biphasic structure enables Fe/Mn-based layered oxide for high-performance sodium-ion batteries cathode. J Power Sources 2023, 567: 232930.
Wu PC, Wu JJ, Huang X, et al. Effect of doping Ni on microstructures and properties of Co x Ni1– x HCF based seawater battery. Vacuum 2024, 220: 112822.
Wang D, Liu YH, Wu ZG, et al. Realizing discrepant oxygen–redox chemistry in honeycomb superlattice cathode via manipulating oxygen-stacking sequences. Chem Eng J 2023, 462: 141994.
House RA, Marie JJ, Pérez-Osorio MA, et al. The role of O2 in O-redox cathodes for Li-ion batteries. Nat Energy 2021, 6: 781–789.
Jin JT, Liu YC, Shen QY, et al. Unveiling the complementary manganese and oxygen redox chemistry for stabilizing the sodium-ion storage behaviors of layered oxide cathodes. Adv Funct Mater 2022, 32: 2203424.
Boivin E, House RA, Marie JJ, et al. Controlling iron versus oxygen redox in the layered cathode Na0.67Fe0.5Mn0.5O2: Mitigating voltage and capacity fade by Mg substitution. Adv Energy Mater 2022, 12: 2200702.
Cheng C, Ding ML, Yan TR, et al. Anionic redox activities boosted by aluminum doping in layered sodium-ion battery electrode. Small Methods 2022, 6: 2101524.
Wang Y, Zhao XD, Jin JT, et al. Boosting the reversibility and kinetics of anionic redox chemistry in sodium-ion oxide cathodes via reductive coupling mechanism. J Am Chem Soc 2023, 145: 22708–22719.
Huang XQ, Li DL, Huang HJ, et al. Fast and highly reversible Na+ intercalation/extraction in Zn/Mg dual-doped P2-Na0.67MnO2 cathode material for high-performance Na-ion batteries. Nano Res 2021, 14: 3531–3537.
Liu ZB, Zhou CJ, Liu J, et al. Phase tuning of P2/O3-type layered oxide cathode for sodium ion batteries via a simple Li/F co-doping route. Chem Eng J 2022, 431: 134273.
Liu TW, Liu YD, Yu YK, et al. Approaching theoretical specific capacity of iron-rich lithium iron silicate using graphene-incorporation and fluorine-doping. J Mater Chem A 2022, 10: 4006–4014.
Wang JJ, Kang JZ, Gu ZY, et al. Localized electron density redistribution in fluorophosphate cathode: Dangling anion regulation and enhanced Na-ion diffusivity for sodium-ion batteries. Adv Funct Mater 2022, 32: 2109694.
Liu DM, Fan XJ, Li ZH, et al. A cation/anion co-doped Li1.12Na0.08Ni0.2Mn0.6O1.95F0.05 cathode for lithium ion batteries. Nano Energy 2019, 58: 786–796.
Chen J, Zhao N, Ban KJ, et al. Superior electrochemical properties of Li[Li0.2Ni0.18Mn0.6Mg0.02]O2 cathode material with hierarchical micronanostructure for lithium ion batteries. J Alloys Compd 2019, 805: 673–679.
Korobov DD, Mitrofanov IV, Pushnitsa KA, et al. Features of improved capacity at high discharge rate of K-doped Li-rich cathodes for LIBs. Mater Today Proc 2020, 30: 778–783.
Ding X, Li YX, Deng MM, et al. Cesium doping to improve the electrochemical performance of layered Li1.2Ni0.13Co0.13Mn0.54O2 cathode material. J Alloys Compd 2019, 791: 100–108.
Yuan XL, Xu QJ, Liu XN, et al. Excellent rate performance and high capacity of Mo doped layered cathode material Li[Li0.2Mn0.54Ni0.13Co0.13]O2 derived from an improved coprecipitation approach. Electrochim Acta 2016, 207: 120–129.
Leng MZ, Bi JQ, Wang WL, et al. Superior electrochemical performance of O3-type NaNi0.5− x Mn0.3Ti0.2Zr x O2 cathode material for sodium-ion batteries from Ti and Zr substitution of the transition metals. J Alloys Compd 2020, 816: 152581.
Kubota K, Asari T, Komaba S. Impact of Ti and Zn dual-substitution in P2 type Na2/3Ni1/3Mn2/3O2 on Ni–Mn and Na-vacancy ordering and electrochemical properties. Adv Mater 2023, 35: 2300714.
Chen MM, Zhao EY, Chen DF, et al. Decreasing Li/Ni disorder and improving the electrochemical performances of Ni-rich LiNi0.8Co0.1Mn0.1O2 by Ca doping. Inorg Chem 2017, 56: 8355–8362.
He T, Chen L, Su YF, et al. The effects of alkali metal ions with different ionic radii substituting in Li sites on the electrochemical properties of Ni-rich cathode materials. J Power Sources 2019, 441: 227195.
Chen ZY, Gong XL, Zhu HL, et al. High performance and structural stability of K and Cl co-doped LiNi0.5Co0.2Mn0.3O2 cathode materials in 4.6 voltage. Front Chem 2019, 6: 643.
Li XX, Shang Y, Yan D, et al. Topotactic epitaxy self-assembly of potassium manganese hexacyanoferrate superstructures for highly reversible sodium-ion batteries. ACS Nano 2022, 16: 453–461.
Liu XY, Gong HC, Han CY, et al. Barium ions act as defenders to prevent water from entering Prussian blue lattice for sodium-ion battery. Energy Storage Mater 2023, 57: 118–124.
Shen QY, Liu YC, Zhao XD, et al. Transition-metal vacancy manufacturing and sodium-site doping enable a high-performance layered oxide cathode through cationic and anionic redox chemistry. Adv Funct Mater 2021, 31: 2106923.
Xu XQ, Hu SJ, Pan QC, et al. Enhancing structure stability by Mg/Cr co-doped for high-voltage sodium-ion batteries. Small 2024, 20: 2307377.
Yang W, Bai CJ, Xiang W, et al. Dual-modified compact layer and superficial Ti doping for reinforced structural integrity and thermal stability of Ni-rich cathodes. ACS Appl Mater Inter 2021, 13: 54997–55006.
Kong DF, Hu JT, Chen ZF, et al. Ti-gradient doping to stabilize layered surface structure for high performance high-Ni oxide cathode of Li-ion battery. Adv Energy Mater 2019, 9: 1901756.
Cheng C, Hu HL, Yuan C, et al. Precisely modulating the structural stability and redox potential of sodium layered cathodes through the synergetic effect of co-doping strategy. Energy Storage Mater 2022, 52: 10–18.
Xiang HM, Xing Y, Dai FZ, et al. High-entropy ceramics: Present status, challenges, and a look forward. J Adv Ceram 2021, 10: 385–441.
Ni DW, Cheng Y, Zhang JP, et al. Advances in ultra-high temperature ceramics, composites, and coatings. J Adv Ceram 2022, 11: 1–56.
Ma YJ, Ma Y, Wang QS, et al. High-entropy energy materials: Challenges and new opportunities. Energy Environ Sci 2021, 14: 2883–2905.
Yan JH, Wang D, Zhang XY, et al. A high-entropy perovskite titanate lithium-ion battery anode. J Mater Sci 2020, 55: 6942–6951.
Xu YS, Xu X, Bi L. A high-entropy spinel ceramic oxide as the cathode for proton-conducting solid oxide fuel cells. J Adv Ceram 2022, 11: 794–804.
Xiao B, Wu G, Wang TD, et al. High-entropy oxides as advanced anode materials for long-life lithium-ion batteries. Nano Energy 2022, 95: 106962.
Chen YW, Fu HY, Huang YY, et al. Opportunities for high-entropy materials in rechargeable batteries. ACS Materials Lett 2021, 3: 160–170.
Liu YN, Yang JL, Gu ZY, et al. Entropy-regulated cathode with low strain and constraint phase-change toward ultralong-life aqueous Al-ion batteries. Angew Chem Int Ed 2024, 63: e202316925.
Sturman JW, Baranova EA, Abu-Lebdeh Y. Review: High-entropy materials for lithium-ion battery electrodes. Front Energy Res 2022, 10: 862551.
Cai TX, Cai MZ, Mu JX, et al. High-entropy layered oxide cathode enabling high-rate for solid-state sodium-ion batteries. Nano-micro Lett 2023, 16: 10.
Zou XK, Zhang YR, Huang ZP, et al. High-entropy oxides: An emerging anode material for lithium-ion batteries. Chem Commun 2023, 59: 13535–13550.
Yuan K, Tu TZ, Shen C, et al. Self-ball milling strategy to construct high-entropy oxide coated LiNi0.8Co0.1Mn0.1O2 with enhanced electrochemical performance. J Adv Ceram 2022, 11: 882–892.
Amiri A, Shahbazian-Yassar R. Recent progress of high-entropy materials for energy storage and conversion. J Mater Chem A 2021, 9: 782–823.
Liu ZY, Liu Y, Xu YJ, et al. Novel high-entropy oxides for energy storage and conversion: From fundamentals to practical applications. Green Energy Environ 2023, 8: 1341–1357.
Ma JP, Huang CD. High entropy energy storage materials: Synthesis and application. J Energy Storage 2023, 66: 107419.
Gao XD, Zhang XY, Liu XY, et al. Recent advances for high-entropy based layered cathodes for sodium ion batteries. Small Meth 2023, 7: 2300152.
Bérardan D, Franger S, Meena AK, et al. Room temperature lithium superionic conductivity in high entropy oxides. J Mater Chem A 2016, 4: 9536–9541.
Sarkar A, Velasco L, Wang D, et al. High entropy oxides for reversible energy storage. Nat Commun 2018, 9: 3400.
Li S, Peng ZJ, Fu XL. Zn0.5Co0.5Mn0.5Fe0.5Al0.5Mg0.5O4 high-entropy oxide with high capacity and ultra-long life for Li-ion battery anodes. J Adv Ceram 2023, 12: 59–71.
Bai YH, Li JR, Lu H, et al. Ultrafast high-temperature sintering of high-entropy oxides with refined microstructure and superior lithium-ion storage performance. J Adv Ceram 2023, 12: 1857–1871.
Yeh JW, Chen SK, Lin SJ, et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv Eng Mater 2004, 6: 299–303.
George EP, Raabe D, Ritchie RO. High-entropy alloys. Nat Rev Mater 2019, 4: 515–534.
Chang XJ, Zeng MQ, Liu KL, et al. Phase engineering of high-entropy alloys. Adv Mater 2020, 32: 1907226.
Rost CM, Sachet E, Borman T, et al. Entropy-stabilized oxides. Nat Commun 2015, 6: 8485.
Sarkar A, Wang QS, Schiele A, et al. High-entropy oxides: Fundamental aspects and electrochemical properties. Adv Mater 2019, 31: 1806236.
Tu TZ, Liu JX, Wu Y, et al. Synergistic effects of high-entropy engineering and particulate toughening on the properties of rare-earth aluminate-based ceramic composites. J Adv Ceram 2023, 12: 861–872.
Zhou L, Liu JX, Tu TZ, et al. Fast grain growth phenomenon in high-entropy ceramics: A case study in rare-earth hexaaluminates. J Adv Ceram 2023, 12: 111–121.
Zhang XY, Ren K, Liu YN, et al. Progress on entropy production engineering for electrochemical catalysis. Acta Phys Chim Sin 2023, 40: 2307057.
Du AB, Wang YF, Wei ZH, et al. Photothermal microscopy of graphene flakes with different thicknesses. Acta Phys Chim Sin 2023, 40: 2304027.
Owen LR, Jones NG. Lattice distortions in high-entropy alloys. J Mater Res 2018, 33: 2954–2969.
Dąbrowa J, Danielewski M. State-of-the-art diffusion studies in the high entropy alloys. Metals 2020, 10: 347.
Song J, Ning FH, Zuo YX, et al. Entropy stabilization strategy for enhancing the local structural adaptability of Li-rich cathode materials. Adv Mater 2023, 35: 2208726.
Yu BK, Wang YQ, Li JQ, et al. Recent advances on low-Co and Co-free high entropy layered oxide cathodes for lithium-ion batteries. Nanotechnology 2023, 34: 452501.
Zhou DS, Sun YX, Gao T, et al. Enhanced Li+ diffusion and lattice oxygen stability by the high entropy effect in disordered-rocksalt cathodes. Angew Chem Int Edit 2023, 62: e202311930.
Wang QS, Sarkar A, Wang D, et al. Multi-anionic and -cationic compounds: New high entropy materials for advanced Li-ion batteries. Energy Environ Sci 2019, 12: 2433–2442.
Sturman J, Yim CH, Baranova EA, et al. Communication—Design of LiNi0.2Mn0.2Co0.2Fe0.2Ti0.2O2 as a high-entropy cathode for lithium-ion batteries guided by machine learning. J Electrochem Soc 2021, 168: 050541.
Zhang R, Wang CY, Zou PC, et al. Compositionally complex doping for zero-strain zero-cobalt layered cathodes. Nature 2022, 610: 67–73.
Zheng QF, Ren ZH, Zhang YX, et al. Surface-stabilized high-entropy layered oxyfluoride cathode for lithium-ion batteries. J Phys Chem Lett 2023, 14: 5553–5559.
Zheng QF, Ren ZH, Zhang YX, et al. Surface phase conversion in a high-entropy layered oxide cathode material. ACS Appl Mater Inter 2023, 15: 4643–4651.
Wang JB, Cui YY, Wang QS, et al. Lithium containing layered high entropy oxide structures. Sci Rep 2020, 10: 18430.
Lun ZY, Ouyang B, Kwon DH, et al. Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries. Nat Mater 2021, 20: 214–221.
Zuo WH, Luo MZ, Liu XS, et al. Li-rich cathodes for rechargeable Li-based batteries: Reaction mechanisms and advanced characterization techniques. Energy Environ Sci 2020, 13: 4450–4497.
Walczak K, Plewa A, Ghica C, et al. NaMn0.2Fe0.2Co0.2Ni0.2Ti0.2O2 high-entropy layered oxide-experimental and theoretical evidence of high electrochemical performance in sodium batteries. Energy Storage Mater 2022, 47: 500–514.
Joshi A, Chakrabarty S, Akella SH, et al. High-entropy Co-free O3-type layered oxyfluoride: A promising air-stable cathode for sodium-ion batteries. Adv Mater 2023, 35: 2304440.
Wu B, Hou GR, Kovalska E, et al. High-entropy NASICON phosphates (Na3M2(PO4)3 and NaMPO4O x , M = Ti, V, Mn, Cr, and Zr) for sodium electrochemistry. Inorg Chem 2022, 61: 4092–4101.
Wang JY, He TJ, Yang XC, et al. Design principles for NASICON super-ionic conductors. Nat Commun 2023, 14: 5210.
Xu CL, Zhao JM, Wang EH, et al. A novel NASICON-typed Na4VMn0.5Fe0.5(PO4)3 cathode for high-performance Na-ion batteries. Adv Energy Mater 2021, 11: 2100729.
Du M, Geng PB, Pei CX, et al. High-entropy Prussian blue analogues and their oxide family as sulfur hosts for lithium–sulfur batteries. Angew Chem Int Ed 2022, 61: e202209350.
Zhao X, Xing ZH, Huang CD. Investigation of high-entropy Prussian blue analog as cathode material for aqueous sodium-ion batteries. J Mater Chem A 2023, 11: 22835–22844.
Jiang W, Wang T, Chen H, et al. Room temperature synthesis of high-entropy Prussian blue analogues. Nano Energy 2021, 79: 105464.
Zhao CL, Ding FX, Lu YX, et al. High-entropy layered oxide cathodes for sodium-ion batteries. Angew Chem Int Ed 2020, 59: 264–269.
Guo H, Avdeev M, Sun K, et al. Pentanary transition-metals Na-ion layered oxide cathode with highly reversible O3–P3 phase transition. Chem Eng J 2021, 412: 128704.
Yang LF, Chen C, Xiong S, et al. Multiprincipal component P2–Na0.6(Ti0.2Mn0.2Co0.2Ni0.2Ru0.2)O2 as a high-rate cathode for sodium-ion batteries. JACS Au 2020, 1: 98–107.
Tian KH, He H, Li X, et al. Boosting electrochemical reaction and suppressing phase transition with a high-entropy O3-type layered oxide for sodium-ion batteries. J Mater Chem A 2022, 10: 14943–14953.
Ding FX, Zhao CL, Xiao DD, et al. Using high-entropy configuration strategy to design Na-ion layered oxide cathodes with superior electrochemical performance and thermal stability. J Am Chem Soc 2022, 144: 8286–8295.
Mu JX, Cai TX, Dong WJ, et al. Biphasic high-entropy layered oxide as a stable and high-rate cathode for sodium-ion batteries. Chem Eng J 2023, 471: 144403.
Li MJ, Sun CL, Ni Q, et al. High entropy enabling the reversible redox reaction of V4+/V5+ couple in NASICON-type sodium ion cathode. Adv Energy Mater 2023, 13: 202203971.
Gu ZY, Guo JZ, Cao JM, et al. An advanced high-entropy fluorophosphate cathode for sodium-ion batteries with increased working voltage and energy density. Adv Mater 2022, 34: 2110108.
Gu ZY, Zhao XX, Li K, et al. Homeostatic solid solution reaction in phosphate cathode: Breaking high-voltage barrier to achieve high energy density and long life of sodium-ion batteries. Adv Mater 2024, 36: 2400690.
Ma YJ, Hu Y, Pramudya Y, et al. Resolving the role of configurational entropy in improving cycling performance of multicomponent hexacyanoferrate cathodes for sodium-ion batteries. Adv Funct Mater 2022, 32: 2202372.
Peng J, Zhang B, Hua WB, et al. A disordered rubik’s cube-inspired framework for sodium-ion batteries with ultralong cycle lifespan. Angew Chem Int Ed 2023, 62: e202215865.
Wang KD, Nishio K, Horiba K, et al. Synthesis of high-entropy layered oxide epitaxial thin films: LiCr1/6Mn1/6Fe1/6Co1/6Ni1/6Cu1/6O2. Cryst Growth Des 2022, 22: 1116–1122.
Wang B, Ma J, Wang KJ, et al. High-entropy phase stabilization engineering enables high-performance layered cathode for sodium-ion batteries. Adv Energy Mater 2024, 14: 2401090.
Yao LB, Zou PC, Wang CY, et al. High-entropy and superstructure-stabilized layered oxide cathodes for sodium-ion batteries. Adv Energy Mater 2022, 12: 2201989.
Dang YZ, Xu Z, Yang HD, et al. Designing water/air-stable Co-free high-entropy oxide cathodes with suppressed irreversible phase transition for sodium-ion batteries. Appl Surf Sci 2023, 636: 157856.
Deng HH, Liu LY, Shi ZC. Effect of copper substitution on the electrochemical properties of high entropy layered oxides cathode materials for sodium-ion batteries. Mater Lett 2023, 340: 134113.
Du XY, Meng Y, Yuan HY, et al. High-entropy substitution: A strategy for advanced sodium-ion cathodes with high structural stability and superior mechanical properties. Energy Storage Mater 2023, 56: 132–140.
Zhou PF, Che ZN, Liu J, et al. High-entropy P2/O3 biphasic cathode materials for wide-temperature rechargeable sodium-ion batteries. Energy Storage Mater 2023, 57: 618–627.
Wang K, Hua WB, Huang XH, et al. Synergy of cations in high entropy oxide lithium ion battery anode. Nat Commun 2023, 14: 1487.
Guo RN, Yang Y, Zhao CC, et al. The role of high-entropy materials in lithium-based rechargeable batteries. Adv Funct Mater 2024, 34: 2313168.
Zheng W, Liang GM, Liu Q, et al. The promise of high-entropy materials for high-performance rechargeable Li-ion and Na-ion batteries. Joule 2023, 7: 2732–2748.
Hong WC, Chen F, Shen Q, et al. Microstructural evolution and mechanical properties of (Mg,Co,Ni,Cu,Zn)O high-entropy ceramics. J Am Ceram Soc 2019, 102: 2228–2237.
Yan SX, Luo SH, Yang L, et al. Novel P2-type layered medium-entropy ceramics oxide as cathode material for sodium-ion batteries. J Adv Ceram 2022, 11: 158–171.
Biesuz M, Spiridigliozzi L, Dell’Agli G, et al. Synthesis and sintering of (Mg,Co,Ni,Cu,Zn)O entropy-stabilized oxides obtained by wet chemical methods. J Mater Sci 2018, 53: 8074–8085.
Nguyen TX, Patra J, Chang JK, et al. High entropy spinel oxide nanoparticles for superior lithiation–delithiation performance. J Mater Chem A 2020, 8: 18963–18973.
Wang G, Qin J, Feng YY, et al. Sol–gel synthesis of spherical mesoporous high-entropy oxides. ACS Appl Mater Inter 2020, 12: 45155–45164.
Park T, Javadinejad HR, Kim YK, et al. Effect of processing route on the crystal structure and physical properties of bixbyite high-entropy oxides. J Alloys Compd 2022, 893: 162108.
Dąbrowa J, Olszewska A, Falkenstein A, et al. An innovative approach to design SOFC air electrode materials: High entropy La1− x Sr x (Co,Cr,Fe,Mn,Ni)O3− δ ( x = 0, 0.1, 0.2, 0.3) perovskites synthesized by the sol–gel method. J Mater Chem A 2020, 8: 24455–24468.
Djenadic R, Sarkar A, Clemens O, et al. Multicomponent equiatomic rare earth oxides. Mater Res Lett 2017, 5: 102–109.
Sarkar A, Loho C, Velasco L, et al. Multicomponent equiatomic rare earth oxides with a narrow band gap and associated praseodymium multivalency. Dalton Trans 2017, 46: 12167–12176.
1801
Views
600
Downloads
2
Crossref
1
Web of Science
1
Scopus
0
CSCD
Altmetrics
This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, http://creativecommons.org/licenses/by/4.0/).
京公网安备11010802044758号