The development of aeroengine with a high thrust-weight ratio poses great challenges for current top-coating thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs) in service. Medium/high-entropy ceramics are highly promising candidate material for advanced TBCs/EBCs owing to their low thermal conductivity, high melting point, high-temperature stability, and calcium–magnesium–alumino–silicate (CMAS) resistance. Most feedstock powder used for medium/high-entropy TBCs/EBCs is prepared via traditional spray drying, which cannot fully exploit the advantages of multicomponent ceramics. The density, sphericity, inner structure, and flowability of feedstock powder affect their melting state during the thermal spraying process, which strongly affects the microstructure and properties of the deposited coatings. Therefore, the deposited coatings exhibit phase segregation, amorphous phases, and microstructure defects owing to unpredictable variations in feedstock powder with random morphologies and structures. Here, the structure and properties of feedstock powder prepared by state-of-the-art granulation technologies and their influences on the deposited coatings were systematically investigated, which can provide guidance for configuration optimization of feedstock powder and the manufacturing accuracy of the deposited coating. This review aims to bridge the gap between cutting-edge ceramics and advanced engineering technologies, thus providing concrete background knowledge and crucial guidelines for designing and developing TBCs/EBCs.
Curtin WA. Theory of mechanical properties of ceramic–matrix composites. J Am Ceram Soc 1991, 74: 2837–2845.
Opila EJ, Hann Jr RE. Paralinear oxidation of CVD SiC in water vapor. J Am Ceram Soc 1997, 80: 197–205.
Dong N, Luan XG, Cheng LF. Corrosion of C/SiC composite in water vapor and Na2SO4 vapor. Sci Eng Compos Mater 2008, 15: 121–129.
Ridley M, Kane K, Lance M, et al. Steam oxidation and microstructural evolution of rare earth silicate environmental barrier coatings. J Am Ceram Soc 2023, 106: 613–620.
Eaton HE, Linsey GD. Accelerated oxidation of SiC CMC’s by water vapor and protection via environmental barrier coating approach. J Eur Ceram Soc 2002, 22: 2741–2747.
Turcer LR, Padture NP. Towards multifunctional thermal environmental barrier coatings (TEBCs) based on rare-earth pyrosilicate solid-solution ceramics. Scripta Mater 2018, 154: 111–117.
Poerschke DL, Hass DD, Eustis S, et al. Stability and CMAS resistance of ytterbium-silicate/hafnate EBCs/TBC for SiC composites. J Am Ceram Soc 2015, 98: 278–286.
Chen HF, Zhang C, Liu YC, et al. Recent progress in thermal/environmental barrier coatings and their corrosion resistance. Rare Metals 2020, 39: 498–512.
Zhang Q, Zhang XQ, Ma Z, et al. Water vapor and CMAS corrosion tests of Y2SiO5/Si thermal and environmental barrier coating. Heliyon 2022, 8: e10262.
Tian ZL, Zheng LY, Wang JM, et al. Theoretical and experimental determination of the major thermo-mechanical properties of RE2SiO5 (RE = Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y) for environmental and thermal barrier coating applications. J Eur Ceram Soc 2016, 36: 189–202.
Clarke DR, Oechsner M, Padture NP. Thermal-barrier coatings for more efficient gas-turbine engines. MRS Bull 2012, 37: 891–898.
Thakare JG, Pandey C, Mahapatra MM, et al. Thermal barrier coatings—A state of the art review. Met Mater Int 2021, 27: 1947–1968.
Guo L, He WT, Chen WB, et al. Progress on high-temperature protective coatings for aero-engines. Surf Sci Technol 2023, 1: 6.
Mondal K, Nuñez III L, Downey CM, et al. Thermal barrier coatings overview: Design, manufacturing, and applications in high-temperature industries. Ind Eng Chem Res 2021, 60: 6061–6077.
Liu QM, Huang SZ, He AJ. Composite ceramics thermal barrier coatings of yttria stabilized zirconia for aero-engines. J Mater Sci Technol 2019, 35: 2814–2823.
Zhang XF, Zhou KS, Chang F, et al. Yttria-stabilized-zirconia hollow spheres prepared by atmospheric plasma spray. Particuology 2014, 14: 57–62.
Wang Y, Hsu PF. Microstructure modifications to enhance the scattering coefficient of porous yttria-stabilized zirconia coatings. J Therm Spray Techn 2024, 33: 181–194.
Zhang H, Chen Y, Li L, et al. Unraveling the CMAS corrosion mechanism of APS high-yttria-stabilized zirconia thermal barrier coatings. J Eur Ceram Soc 2024, 44: 5154–5165.
Velasco JHR, Petrosky K, Kilaz G, et al. Thermochemical interaction of biofuel impurities with yttria-stabilized zirconia thermal barrier coatings. Ceram Int 2021, 47: 24675–24682.
Pakseresht A, Sharifianjazi F, Esmaeilkhanian A, et al. Failure mechanisms and structure tailoring of YSZ and new candidates for thermal barrier coatings: A systematic review. Mater Design 2022, 222: 111044.
Qin SY, Cao HT, Gao ZH, et al. A new Al2O3-protected EB-PVD TBC with superior CMAS resistance. Adv Sci 2024, 11: 2305479.
Lin GQ, Wang YL, Yang LX, et al. CMAS corrosion behavior of a novel high entropy (Nd0.2Gd0.2Y0.2Er0.2Yb0.2)2Zr2O7 thermal barrier coating materials. Corros Sci 2023, 224: 111529.
Deng SX, He G, Yang ZC, et al. Calcium–magnesium–alumina–silicate (CMAS) resistant high entropy ceramic (Y0.2Gd0.2Er0.2Yb0.2Lu0.2)2Zr2O7 for thermal barrier coatings. J Mater Sci Technol 2022, 107: 259–265.
Ball JAJ, Martins JF, Brewster G, et al. An investigation into RESZ (RE = Yb, Er, Gd, Sm) materials for CMAS resistance in thermal barrier coatings. J Eur Ceram Soc 2024, 44: 3734–3746.
Yao Y, Yang F, Zhao XF. Multicomponent high-entropy Zr–Y–Yb–Ta–Nb–O oxides for next-generation thermal barrier coating applications. J Am Ceram Soc 2022, 105: 35–43.
Wang KL, Zhu JP, Wang HL, et al. Air plasma-sprayed high-entropy (Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 coating with high thermal protection performance. J Adv Ceram 2022, 11: 1571–1582.
Liu DB, Shi BL, Geng LY, et al. High-entropy rare-earth zirconate ceramics with low thermal conductivity for advanced thermal-barrier coatings. J Adv Ceram 2022, 11: 961–973.
Arai Y, Inoue R. Detection of small delamination in mullite/Si/SiC model EBC system by pulse thermography. J Adv Ceram 2019, 8: 438–447.
Yu YL, Zhang P, Liu XY, et al. Effect of feedstock powder size on the microstructure and thermal conductivity of quasi-eutectic LaYbZr2O7 TBCs. Ceram Int 2024, 50: 13684–13689.
Wang HY, Zhang J, Sun LC, et al. Microstructure and phase composition evolution of dual-phase ytterbium silicate coatings plasma sprayed from stoichiometric Yb2Si2O7 feedstock powder. Surf Coat Tech 2022, 437: 128373.
Richards BT, Zhao HB, Wadley HNG. Structure, composition, and defect control during plasma spray deposition of ytterbium silicate coatings. J Mater Sci 2015, 50: 7939–7957.
Łatka L. Thermal barrier coatings manufactured by suspension plasma spraying—A review. Adv Mater Sci 2018, 18: 95–117.
Shi MC, Xue ZL, Zhang ZY, et al. Effect of spraying powder characteristics on mechanical and thermal shock properties of plasma-sprayed YSZ thermal barrier coating. Surf Coat Tech 2020, 395: 125913.
Sharma A, Witz G, LeCreux C, et al. High heat flux burner-rig testing of 8YSZ thermal barrier coatings: Influence of the powder feedstock. J Eur Ceram Soc 2022, 42: 7267–7274.
Wang JS, Sun JB, Zhang H, et al. Effect of spraying power on microstructure and property of nanostructured YSZ thermal barrier coatings. J Alloys Compd 2018, 730: 471–482.
Sun QY, Liu T, Wen TP, et al. Ethanol-induced formation of precursor for 8 mol% Yttria-stabilized zirconia: Towards the production of well-dispersed, easily sintering, and high-conductivity nano-powders. J Eur Ceram Soc 2023, 43: 6934–6945.
Esmaeilkhanian AH, Sharifianjazi F, Ahmadi E, et al. Thermal barrier coating with improved durability: An overview of doped, nanostructured, multilayered, and gradient-structured zirconia-based thermal barrier coatings. Mater Today Commun 2023, 37: 107514.
Xue ZL, Zhu Y, Yu HY, et al. Nano-agglomerated powder and thermal shock cycling property of 8YSZ nano-structured thermal barrier coating. Surf Coat Tech 2022, 433: 128173.
Ghoshal A, Murugan M, Walock MJ, et al. Molten particulate impact on tailored thermal barrier coatings for gas turbine engine. J Eng Gas Turb Power 2018, 140: 022601.
Salam Hamdy A. Corrosion protection performance via nano-coatings technologies. Recent Pat Mater Sci 2010, 3: 258–267.
Lu XR, Yuan JY, Li G, et al. Microstructures, thermophysical properties and thermal cyclic behaviors of Nd2O3 and Sc2O3 Co-doped LaMgAl11O19 thermal barrier coating deposited by plasma spraying. Ceram Int 2022, 48: 36539–36555.
Guo FW, Xing C, Wang GW, et al. Hollow ceramic microspheres prepared by combining electro-spraying with non-solvent induced phase separation method: A promising feedstock for thermal barrier coatings. Mater Design 2018, 139: 343–350.
Li BX, Zhang XD, Zhang ZG, et al. Preparation and characterization of a novel nanostructured Yb2Si2O7 feedstock used for plasma-sprayed environmental barrier coatings. Ceram Int 2023, 49: 10897–10905.
Xiao F, Zhang XD, Li BX, et al. Nanostructured Yb2SiO5/mullite–SiC/Si environmental barrier coating with long-term stability at 1250 °C. Ceram Int 2024, 50: 27974–27983.
Zhou FF, Guo DH, Xu BS, et al. Novel controllable solid/hollow T'-YSZ nanostructured powders for additive manufacturing. Ceram Int 2022, 48: 24125–24128.
Guo DH, Liu J, Shi JZ, et al. Synthesis and characterization of single-phase X2-Lu2SiO5 nanostructured feedstocks for advanced plasma-sprayed environmental barrier coatings. Surf Coat Tech 2024, 476: 130230.
Xing C, Yi MY, Zhang X, et al. Compression strength and fracture mechanism of a hierarchical porous yttria-stabilized zirconia microsphere prepared using electro-spraying associated with phase inversion technique. Ceram Int 2021, 47: 18132–18139.
Yu YL, Guo FW, Xing C, et al. Thermal properties of hierarchical YSZ and LZO ceramic microspheres with multi-scaled voids investigated by using theoretical, experimental and simulation methods. Adv Powder Technol 2022, 33: 103879.
Guo HB, Murakami H, Kuroda S. Effect of hollow spherical powder size distribution on porosity and segmentation cracks in thermal barrier coatings. J Am Ceram Soc 2006, 89: 3797–3804.
Buelna G, Lin YS. Sol–gel-derived mesoporous γ-alumina granules. Micropor Mesopor Mat 1999, 30: 359–369.
Song J, Kim B, Park D, et al. Fabrications of spherical alumina particles by controlling process parameters in a transferred arc plasma system. Ceram Int 2020, 46: 21225–21232.
Lou XW, Archer LA, Yang ZC. Hollow micro-/nanostructures: Synthesis and applications. Adv Mater 2008, 20: 3987–4019.
Hu J, Chen M, Fang XS, et al. Fabrication and application of inorganic hollow spheres. Chem Soc Rev 2011, 40: 5472–5491.
Yu M, Zhou KC, Zhang Y, et al. Porous Al2O3 microspheres prepared by a novel ice-templated spray drying technique. Ceram Int 2014, 40: 1215–1219.
Nouri A, Sola A. Powder morphology in thermal spraying. J Adv Manuf & Process 2019, 1: 10020.
Stunda-Zujeva A, Irbe Z, Berzina-Cimdina L. Controlling the morphology of ceramic and composite powders obtained via spray drying—A review. Ceram Int 2017, 43: 11543–11551.
Kim DJ, Jung JY. Granule performance of zirconia/alumina composite powders spray-dried using polyvinyl pyrrolidone binder. J Eur Ceram Soc 2007, 27: 3177–3182.
Zhu RB, Zou JP, Mao J, et al. A comparison between novel Gd2Zr2O7 and Gd2Zr2O7/YSZ thermal barrier coatings fabricated by plasma spray-physical vapor deposition. Rare Metals 2021, 40: 2244–2253.
Liang SS, Li J, Li XM, et al. Microfluidic fabrication of ceramic microspheres with controlled morphologies. J Am Ceram Soc 2018, 101: 3787–3796.
Chu LY, Utada AS, Shah RK, et al. Controllable monodisperse multiple emulsions. Angew Chem-Ger Edit 2007, 46: 8970–8974.
Zou ZH, Xing C, He LM, et al. A highly strain and damage-tolerant thermal barrier coating fabricated by electro-sprayed zirconia hollow spheres. J Am Ceram Soc 2018, 101: 4375–4386.
Zhang RJ, Guo FW, Zhang X, et al. ZrB2–SiC spiral fibers prepared by combining liquid rope effect with non-solvent-induced phase separation method: A promising toughening material for ultra-high temperature ceramics. J Adv Ceram 2023, 12: 132–144.
Yu YL, Zhang X, Guo FW, et al. Enhanced near infrared reflectivity in hierarchical porous La2Zr2O7 microspheres produced by electro-spraying assisted phase inversion method. Opt Mater 2021, 118: 111270.
Yu YL, Zhang P, Zhang XF, et al. Formation mechanism of an ultra-low thermal conductivity thermal barrier coating deposited using biomimetic hierarchical porous microspheres. J Eur Ceram Soc 2025, 45: 116862.
Kulkarni A, Wang Z, Nakamura T, et al. Comprehensive microstructural characterization and predictive property modeling of plasma-sprayed zirconia coatings. Acta Mater 2003, 51: 2457–2475.
Allen AJ, Ilavsky J, Long GG, et al. Microstructural characterization of yttria-stabilized zirconia plasma-sprayed deposits using multiple small-angle neutron scattering. Acta Mater 2001, 49: 1661–1675.
Chi WG, Sampath S, Wang H. Microstructure–thermal conductivity relationships for plasma-sprayed yttria-stabilized zirconia coatings. J Am Ceram Soc 2008, 91: 2636–2645.
Bertrand G, Bertrand P, Roy P, et al. Low conductivity plasma sprayed thermal barrier coating using hollow psz spheres: Correlation between thermophysical properties and microstructure. Surf Coat Tech 2008, 202: 1994–2001.
Dwivedi G, Viswanathan V, Sampath S, et al. Fracture toughness of plasma-sprayed thermal barrier ceramics: Influence of processing, microstructure, and thermal aging. J Am Ceram Soc 2014, 97: 2736–2744.
Tan Y, Longtin JP, Sampath S, et al. Effect of the starting microstructure on the thermal properties of as-sprayed and thermally exposed plasma-sprayed YSZ coatings. J Am Ceram Soc 2009, 92: 710–716.
Ercan B, Bowman KJ, Trice RW, et al. Effect of initial powder morphology on thermal and mechanical properties of stand-alone plasma-sprayed 7 wt% Y2O3–ZrO2 coatings. Mat Sci Eng A-Struct 2006, 435: 212–220.
Ilavsky J, Stalick JK. Phase composition and its changes during annealing of plasma-sprayed YSZ. Surf Coat Tech 2000, 127: 120–129.
Liu MJ, Zhang M, Zhang XF, et al. Transport and deposition behaviors of vapor coating materials in plasma spray-physical vapor deposition. Appl Surf Sci 2019, 486: 80–92.
Avcı A, Karabaş M, Eker AA, et al. Improvement of CMAS resistance of laser glazed and nano-modified YSZ thermal barrier coatings. Ceram Int 2024, 50: 9985–9999.
Busso EP, Wright L, Evans HE, et al. A physics-based life prediction methodology for thermal barrier coating systems. Acta Mater 2007, 55: 1491–1503.
Mercer C, Faulhaber S, Evans AG, et al. A delamination mechanism for thermal barrier coatings subject to calcium–magnesium–alumino–silicate (CMAS) infiltration. Acta Mater 2005, 53: 1029–1039.
Yan Z, Guo L, Li ZH, et al. Effects of laser glazing on CMAS corrosion behavior of Y2O3 stabilized ZrO2 thermal barrier coatings. Corros Sci 2019, 157: 450–461.
Ma X, Ruggiero P, Wildridge G. Evaluation of CMAS resistance and failure behavior for phase composite thermal barrier coatings. J Therm Spray Techn 2023, 32: 693–705.
Wang JS, Lu XJ, Shu CX, et al. CMAS corrosion resistance of YSZ thermal barrier coatings enhanced by Pt–Al films. Ceram Int 2024, 50: 5111–5120.
Peng H, Wang L, Guo L, et al. Degradation of EB-PVD thermal barrier coatings caused by CMAS deposits. Prog Nat Sci-Mater 2012, 22: 461–467.
Wu J, Guo HB, Abbas M, et al. Evaluation of plasma sprayed YSZ thermal barrier coatings with the CMAS deposits infiltration using impedance spectroscopy. Prog Nat Sci-Mater 2012, 22: 40–47.
Li X, Wang X, Niu SP, et al. Reactive deposition of CYSZ coatings using PS-PVD technology. J Eur Ceram Soc 2024, 44: 6071–6081.
Wei ZY, Meng GH, Chen L, et al. Progress in ceramic materials and structure design toward advanced thermal barrier coatings. J Adv Ceram 2022, 11: 985–1068.
Mauer G, Hospach A, Vaßen R. Process development and coating characteristics of plasma spray-PVD. Surf Coat Tech 2013, 220: 219–224.
Liu SH, Trelles JP, Murphy AB, et al. Low-pressure plasma-induced physical vapor deposition of advanced thermal barrier coatings: Microstructures, modelling and mechanisms. Mater Today Phys 2021, 21: 100481.
Zhang RJ, Zhang X, Xing C, et al. Preparation of long-lifetime thermal barrier coatings and toughening mechanism by using hierarchy structured zirconia-based microspheres. J Eur Ceram Soc 2021, 41: 4625–4636.
Lima RS, Kucuk A, Berndt CC. Bimodal distribution of mechanical properties on plasma sprayed nanostructured partially stabilized zirconia. Mat Sci Eng A-Struct 2002, 327: 224–232.
Lima RS, Marple BR. Thermal spray coatings engineered from nanostructured ceramic agglomerated powders for structural, thermal barrier and biomedical applications: A review. J Therm Spray Techn 2007, 16: 40–63.
Lima RS, Marple BR. Nanostructured YSZ thermal barrier coatings engineered to counteract sintering effects. Mat Sci Eng A-Struct 2008, 485: 182–193.
Kusano E, Kitagawa M, Satoh A, et al. Hardness of compositionally nano-modulated TiN films. Nanostruct Mater 1999, 12: 807–810.
Hernandez-Lopez JL, Bauer RE, Chang WS, et al. Functional polymers as nanoscopic building blocks. Mater Sci Eng C 2003, 23: 267–274.
Zhou CG, Wang N, Wang ZB, et al. Thermal cycling life and thermal diffusivity of a plasma-sprayed nanostructured thermal barrier coating. Scripta Mater 2004, 51: 945–948.
Ghasemi R, Vakilifard H. Plasma-sprayed nanostructured YSZ thermal barrier coatings: Thermal insulation capability and adhesion strength. Ceram Int 2017, 43: 8556–8563.
Liang B, Ding CX. Thermal shock resistances of nanostructured and conventional zirconia coatings deposited by atmospheric plasma spraying. Surf Coat Tech 2005, 197: 185–192.
Lima RS, Kucuk A, Berndt CC. Integrity of nanostructured partially stabilized zirconia after plasma spray processing. Mat Sci Eng A-Struct 2001, 313: 75–82.
Xing C, Yi MY, Shan X, et al. Sintering behavior of a nanostructured thermal barrier coating deposited using electro-sprayed particles. J Am Ceram Soc 2020, 103: 7267–7282.
Yang P, An YL, Zhao D, et al. Structure evolution, thermal properties and sintering resistance of promising thermal barrier coating material La2(Zr0.75Ce0.25)2O7. Ceram Int 2020, 46: 20652–20663.
Zhao YL, Wen JH, Peyraut F, et al. Porous architecture and thermal properties of thermal barrier coatings deposited by suspension plasma spray. Surf Coat Tech 2020, 386: 125462.
Arai M, Ochiai H, Suidzu T. A novel low-thermal-conductivity plasma-sprayed thermal barrier coating controlled by large pores. Surf Coat Tech 2016, 285: 120–127.
Zheng T, Xu BS, Wang S, et al. Microstructure and nanomechanical properties of plasma-sprayed nanostructured Yb2SiO5 environmental barrier coatings. J Am Ceram Soc 2023, 106: 2666–2678.
Guo DH, Xu BS, Shi JZ, et al. Nanomechanical characterization of nanostructured Lu2SiO5 environmental barrier coatings by nano-indentation. Surf Coat Tech 2024, 477: 130317.
Guo DH, Peng XC, Shi BL, et al. Bimodal nanomechanical performance of nanostructured Lu2Si2O7 environmental barrier coating. Ceram Int 2024, 50: 27635–27638.
Xiao F, Yan MF, Wang Y, et al. Water vapor corrosion behaviours of nanostructured Yb2O3–Yb2SiO5/mullite/Si environmental barrier coatings. Ceram Int 2025, 51: 279–289.
Guo DH, Shi JZ, Shi BL, et al. Comparison of thermal properties of conventional and nanostructured Lu2Si2O7 environmental barrier coatings. Surf Interfaces 2024, 51: 104799.
Gild J, Wright A, Quiambao-Tomko K, et al. Thermal conductivity and hardness of three single-phase high-entropy metal diborides fabricated by borocarbothermal reduction and spark plasma sintering. Ceram Int 2020, 46: 6906–6913.
Song D, Song T, Paik U, et al. Glass-like thermal conductivity in mass-disordered high-entropy (Y,Yb)2(Ti,Zr,Hf)2O7 for thermal barrier material. Mater Design 2021, 210: 110059.
Luo XW, Huang S, Huang RQ, et al. Phase evolution, thermophysical and mechanical properties of high-entropy (Ce0.2Nd0.2Sm0.2Eu0.2Yb0.2)2Zr2O7 ceramic for advanced thermal barrier coatings. J Eur Ceram Soc 2024, 44: 2452–2459.
Zhang WC, Guo FW, Zhang RJ, et al. A simple route to synthesize high-entropy carbide (Hf0.2Zr0.2Ti0.2Ce0.2La0.2)C1− δ nanoparticles with large covalent radius difference. Ceram Int 2023, 49: 38566–38574.
Tu TZ, Liu JX, Zhou L, et al. Graceful behavior during CMAS corrosion of a high-entropy rare-earth zirconate for thermal barrier coating material. J Eur Ceram Soc 2022, 42: 649–657.
Sun LC, Luo YX, Tian ZL, et al. High temperature corrosion of (Er0.25Tm0.25Yb0.25Lu0.25)2Si2O7 environmental barrier coating material subjected to water vapor and molten calcium–magnesium–aluminosilicate (CMAS). Corros Sci 2020, 175: 108881.
Lan YW, Cui JG, Dai BX, et al. One pot synthesis of high entropy rare earth zirconate ceramics with low thermal conductivity for high performance thermal-barrier coatings. Mater Sci Eng B-Adv 2024, 301: 117186.
Chen ZY, Lin CC, Zheng W, et al. A high-entropy (Yb0.2Y0.2Lu0.2Ho0.2Er0.2)2Si2O7 environmental barrier coating prepared by atmospheric plasma-spray. Ceram Int 2023, 49: 11323–11333.
Zhang XD, Liang YF, Song Y, et al. Research progress of high entropy rare earth oxide thermal barrier coating materials. Mater Prot 2024, 57: 15–27.
Chen Z, Cui XF, Wang X, et al. Novel high-entropy (La0.35Gd0.35Y0.35Sm0.35Yb0.6)Zr2O7 thermal barrier coatings: Thermal cycling performance and failure behavior. Ceram Int 2024, 50: 54716–54727.
Zhou L, Li F, Liu JX, et al. High-entropy thermal barrier coating of rare-earth zirconate: A case study on (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 prepared by atmospheric plasma spraying. J Eur Ceram Soc 2020, 40: 5731–5739.
Zhou L, Huang ZY, Qi JQ, et al. Thermal-driven fluorite–pyrochlore–fluorite phase transitions of Gd2Zr2O7 ceramics probed in large range of sintering temperature. Metall Mater Trans A 2016, 47: 623–630.
Zhang DB, Yu Y, Feng XL, et al. Thermal barrier coatings with high-entropy oxide as a top coat. Ceram Int 2022, 48: 1349–1359.
Chen GH, Zhang YL, Guo XT, et al. Microstructure and water corrosion behavior of (Lu0.2Yb0.2Er0.2Tm0.2Sc0.2)2Si2O7 high-entropy rare-earth disilicate coating for SiC coated C/C composites. J Eur Ceram Soc 2023, 43: 3647–3657.
Fan D, Zhong X, Zhang ZZ, et al. Interaction of high-entropy rare-earth monosilicate environmental barrier coatings subjected to corrosion by calcium–magnesium–alumino–silicate melts. Corros Sci 2022, 207: 110564.
Hu WP, Lei YM, Zhang J, et al. Mechanical and thermal properties of RE4Hf3O12 (RE = Ho, Er, Tm) ceramics with defect fluorite structure. J Mater Sci Technol 2019, 35: 2064–2069.
Hu WP, Zhang GH, Lei YM, et al. Mechanical and thermal properties of δ-RE4Hf3O12 (RE = Yb, Lu). Int J Appl Ceram Tec 2023, 20: 833–841.
Zheng T, Wang S, Xu BS, et al. A study of fracture toughness and thermal property of nanostructured Yb2SiO5 environmental barrier coatings. J Mater Res Technol 2023, 26: 4436–4443.