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Review Article | Open Access

Present and future of functionalized Cu current collectors for stabilizing lithium metal anodes

Yuhang Liu1,§, Yifan Li1,§, Jinmeng Sun1, Zhuzhu Du1, Xiaoqi Hu1, Jingxuan Bi1, Chuntai Liu4, Wei Ai1( ), Qingyu Yan2,3( )
Frontiers Science Center for Flexible Electronics (FSCFE) & Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), 127 West Youyi Road, Xi'an 710072, China
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798 Singapore
Institute of Materials Research and Engineering, A*STAR, 138634 Singapore
Key Laboratory of Materials Processing and Mold Ministry of Education, Zhengzhou University, Zhengzhou 450002, China

§ Yuhang Liu and Yifan Li contributed equally to this work.

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Abstract

Li metal has been recognized as the most promising anode materials for next-generation high-energy-density batteries, however, the inherent issues of dendrite growth and huge volume fluctuations upon Li plating/stripping normally result in fast capacity fading and safety concerns. Functionalized Cu current collectors have so far exhibited significant regulatory effects on stabilizing Li metal anodes (LMAs), and hold a great practical potential owing to their easy fabrication, low-cost and good compatibility with the existing battery technology. In this review, a comprehensive overview of Cu-based current collectors, including planar modified Cu foil, 3D architectured Cu foil and nanostructured 3D Cu substrates, for Li metal batteries is provided. Particularly, the design principles and strategies of functionalized Cu current collectors associated with their functionalities in optimizing Li plating/stripping behaviors are discussed. Finally, the critical issues where there is incomplete understanding and the future research directions of Cu current collectors in practical LMAs are also prospected. This review may shed light on the critical understanding of current collector engineering for high-energy-density Li metal batteries.

Keywords

Cu current collectorsfunctionalizationLi metal batterieslithiophilic modificationLi plating/stripping

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Nano Research Energy
Volume 2 Issue 1,
March 2023
Article number: e9120048
DOI: 10.26599/NRE.2023.9120048
Cite this article:
Liu Y, Li Y, Sun J, et al. Present and future of functionalized Cu current collectors for stabilizing lithium metal anodes. Nano Research Energy, 2023, 2: e9120048. https://doi.org/10.26599/NRE.2023.9120048

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Received: 28 October 2022
Revised: 24 November 2022
Accepted: 27 November 2022
Published: 06 January 2023
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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