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Highlight | Open Access

Beyond electrode materials structure design: Binders play a vital role for battery application of micro-size electroactive materials

Mingyue Wang, Zhongchao Bai, Nana Wang( )
Institute for Superconducting and Electronic Materials (ISEM), Australian Institute for Innovative Materials (AIIM), Innovation Campus, University of Wollongong, Squires Way, North Wollongong, NSW 2500, Australia
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Abstract

Micrometre-sized electroactive particles with high tapping density show significant potential for commercial application since they effectively alleviate low Coulombic efficiency and excessive solid electrolyte interphase (SEI) issues brought by nanostructures. Furthermore, optimizing the electrode architecture using novel design concepts can improve the energy density. Beyond the electrode material structure design strategy, binder plays a vital role in providing the mechanical stability and regulating the charge transport. This highlight presents the latest development to design high-capacity batteries by optimizing the binder structures in electrodes and emphasizes the significance of binder design for further commercial application.

Keywords

micro-size electroactive materialsbindersmass transporthigh energy density

References

[1]

Choi, S.; Kwon, T. W.; Coskun, A.; Choi, J. W. Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries. Science 2017, 357, 279–283.
Crossref Google Scholar
[2]

Wang, C.; Wu, H.; Chen, Z.; McDowell, M. T.; Cui, Y.; Bao, Z. N. Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries. Nat. Chem. 2013, 5, 1042–1048.
Crossref Google Scholar
[3]

Wang, N. N.; Zhang, X.; Ju, Z. Y.; Yu, X. W.; Wang, Y. X.; Du, Y.; Bai, Z. C.; Dou, S. X.; Yu, G. H. Thickness-independent scalable high-performance Li-S batteries with high areal sulfur loading via electron-enriched carbon framework. Nat. Commun. 2021, 12, 4519.
Crossref Google Scholar
[4]

Ju, Z. Y.; King, S. T.; Xu, X.; Zhang, X.; Raigama, K. U.; Takeuchi, K. J.; Marschilok, A. C.; Wang, L.; Takeuchi, E. S.; Yu, G. H. Vertically assembled nanosheet networks for high-density thick battery electrodes. Proc. Natl. Acad. Sci. USA 2022, 119, e2212777119.
Crossref Google Scholar
[5]

Wang, M. Y.; Bai, Z. C.; Yang, T.; Nie, C. H.; Xu, X.; Wang, Y. X.; Yang, J.; Dou, S. X.; Wang, N. N. Advances in high sulfur loading cathodes for practical lithium-sulfur batteries. Adv. Energy Mater. 2022, 12, 2201585.
Crossref Google Scholar
[6]

Zhu, T. Y.; Sternlicht, H.; Ha, Y.; Fang, C.; Liu, D. Y.; Savitzky, B. H.; Zhao, X.; Lu, Y. Y.; Fu, Y. B.; Ophus, C. et al. Formation of hierarchically ordered structures in conductive polymers to enhance the performances of lithium-ion batteries. Nat. Energy 2023, 8, 129–137.
Crossref Google Scholar
[7]

Park, S. H.; King, P. J.; Tian, R. Y.; Boland, C. S.; Coelho, J.; Zhang, C. F.; McBean, P.; McEvoy, N.; Kremer, M. P.; Daly, D. et al. High areal capacity battery electrodes enabled by segregated nanotube networks. Nat. Energy 2019, 4, 560–567.
Crossref Google Scholar
[8]

Jin, B. Y.; Cui, Z. H.; Manthiram, A. In situ interweaved binder framework mitigating the structural and interphasial degradations of high-nickel cathodes in lithium-ion batteries. Angew. Chem., Int. Ed. 2023, 62, e202301241.
Crossref Google Scholar
[9]

Ling, M.; Qiu, J. X.; Li, S.; Yan, C.; Kiefel, M. J.; Liu, G.; Zhang, S. Q. Multifunctional SA-PProDOT binder for lithium ion batteries. Nano Lett. 2015, 15, 4440–4447.
Crossref Google Scholar
[10]

Yao, Q.; Zhu, Y. S.; Zheng, C.; Wang, N. N.; Wang, D. D.; Tian, F.; Bai, Z. C.; Yang, J.; Qian, Y. T.; Dou, S. X. Intermolecular cross-linking reinforces polymer binders for durable alloy-type anode materials of sodium-ion batteries. Adv. Energy Mater. 2023, 13, 2202939.
Crossref Google Scholar
[11]

Gao, H. C.; Zhou, W. D.; Jang, J. H.; Goodenough, J. B. Cross-linked chitosan as a polymer network binder for an antimony anode in sodium-ion batteries. Adv. Energy Mater. 2016, 6, 1502130.
Crossref Google Scholar
[12]

Wang, C. T.; Su, L.; Wang, N. N.; Lv, D.; Wang, D. D.; Yang, J.; Qian, Y. T. Unravelling binder chemistry in sodium/potassium ion batteries for superior electrochemical performances. J. Mater. Chem. A 2022, 10, 4060–4067.
Crossref Google Scholar
[13]

Xia, J. L.; Lu, A. H.; Yu, X. F.; Li, W. C. Rational design of a trifunctional binder for hard carbon anodes showing high initial Coulombic efficiency and superior rate capability for sodium-ion batteries. Adv. Funct. Mater. 2021, 31, 2104137.
Crossref Google Scholar
Nano Research Energy
Volume 2 Issue 3,
September 2023
Article number: e9120067
DOI: 10.26599/NRE.2023.9120067
Cite this article:
Wang M, Bai Z, Wang N. Beyond electrode materials structure design: Binders play a vital role for battery application of micro-size electroactive materials. Nano Research Energy, 2023, 2: e9120067. https://doi.org/10.26599/NRE.2023.9120067

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Received: 24 February 2023
Revised: 24 March 2023
Accepted: 24 March 2023
Published: 13 April 2023
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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