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Review Article | Open Access

Recent advances of SiOx-based anodes for sustainable lithium-ion batteries

Mengyu Zhang1, Naiwen Liang1, Derek Hao2, Zuxin Chen3,4( ), Fan Zhang1( ), Jiang Yin1, Yahui Yang1, Li-shan Yang1,4( )
Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education of China), National and Local Joint Engineering Laboratory for New Petrochemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha 410081, China
School of Science, STEM College, RMIT University, Melbourne 3000, Australia
School of Semiconductor Science and Technology, South China Normal University, Foshan 528225, China
International Iberian Nanotechnology Laboratory (INL), 4715–330 Braga, Portugal
Show Author Information

Graphical Abstract

Recent developments in SiOx anodes are reviewed, including material design, performance optimization, and mechanistic research. Two promising designs have been highlighted and proposed: SiOx/C composites and porous structures.

Abstract

The world is facing an ever-growing global energy crisis with unprecedented depth and complexity. The sustainable development of high energy density lithium-ion batteries for electric vehicles and portable electric devices has become a feasible way to deal with this problem. Silicon suboxides (SiOx) have been deemed as one of the most promising anode materials because of their ultrahigh theoretical lithium storage capacity, proper working potential, natural abundance, and environmental friendliness. However, the mass utilization of SiOx-based anodes is severely obstructed by their low electrical conductivity and inevitable volume expansion. While lithium silicate and lithium oxide formed in the first lithiation process act as buffer layers to some extent, it is urgent to address the accompanying low initial Coulombic efficiency and unsatisfactory cycling stability. In this review, we summarized recent advances in the synthesis methods of SiOx-based materials. Besides, the benefits and shortcomings of the various methods are briefly concluded. Then, we discussed the effective combination of SiOx with carbon materials and designs of porous structure, which could considerably enhance the electrochemical performance in detail. Furthermore, progresses on the modified strategies, advanced characteristics and industrial applications for SiOx-based anodes are also mentioned. Finally, the remaining challenges encountered and future perspectives on SiOx-based anodes are highlighted.

Keywords

SiOx anodeslithium-ion batteriessynthesis methodsSiOx/C compositesporous

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Nano Research Energy
Volume 2 Issue 3,
September 2023
Article number: e9120077
DOI: 10.26599/NRE.2023.9120077
Cite this article:
Zhang M, Liang N, Hao D, et al. Recent advances of SiOx-based anodes for sustainable lithium-ion batteries. Nano Research Energy, 2023, 2: e9120077. https://doi.org/10.26599/NRE.2023.9120077

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Received: 22 March 2023
Revised: 24 April 2023
Accepted: 03 May 2023
Published: 23 May 2023
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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