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Research Article | Open Access

In-situ fabrication of carbon compound NiFeMo-P anchored on nickel foam as bi-functional catalyst for boosting overall water splitting

Xiangyang Zhou, Tingting Yang, Ting Li, Youju Zi, Sijing Zhang, Lei Yang, Yingkang Liu, Juan Yang, Jingjing Tang( )
School of Metallurgy and Environment, Central South University, Changsha 410083, China
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Graphical Abstract

The carbon compound NiFeMo-P anchored on nickel foam (NiFeMo-P-C) was successfully constructed via hydrothermal and hydrogen reduction methods. The synergistic effect between alloy and metal phosphide, as well as the carbon composition and partially broken hollow morphology, allowing for much higher oxygen evolution reaction (OER)/hydrogen evolution reaction (HER) activity and superior stability.

Abstract

The efficient non-noble metal-based bifunctional electrocatalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) has attracted great interest, which is highly significant to enhance the efficiency of hydrogen production from water electrolysis. Herein, inspired by the appropriate hydrogen adsorption free energy of transition metal alloy and the strong corrosion resistance of phosphide in alkaline electrolyte, carbon compound NiFeMo-P anchored on nickel foam (NiFeMo-P-C) is obtained by simple one-pot hydrothermal and subsequent hydrogen reduction treatment. Remarkably, the NiFeMo-P-C exhibits excellent bifunctional electrocatalytic performances toward HER and OER with low overpotentials of 87 and 196 mV at 10 mA·cm–2, respectively. Moreover, the electrolyzer using NiFeMo-P-C as both cathode and anode only requires a cell voltage of 1.50 V to reach a current density of 10 mA·cm–2, along with an outstanding long-term stability for 50 h. The synergistic effect among alloys and phosphide, partially broken hollow morphology and porous nickel foam substrate jointly impart NiFeMo-P-C high electrocatalytic activity and superior durability.

Keywords

carbon compoundtransition metal alloyhydrogen evolution reaction (HER)oxygen evolution reaction (OER)overall water splitting

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Nano Research Energy
Volume 2 Issue 4,
December 2023
Pages e9120086-e9120086
DOI: 10.26599/NRE.2023.9120086
Cite this article:
Zhou X, Yang T, Li T, et al. In-situ fabrication of carbon compound NiFeMo-P anchored on nickel foam as bi-functional catalyst for boosting overall water splitting. Nano Research Energy, 2023, 2: e9120086. https://doi.org/10.26599/NRE.2023.9120086

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Received: 20 April 2023
Revised: 02 June 2023
Accepted: 21 June 2023
Published: 07 July 2023
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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