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Review Article | Open Access

Research progress of transition metal compounds as bifunctional catalysts for zinc-air batteries

Yan Ran1, Changfan Xu1, Deyang Ji2, Huaping Zhao1, Liqiang Li2, Yong Lei1( )
Fachgebiet Angewandte Nanophysik, Institut für Physik & IMN MacroNano, Technische Universität Ilmenau, Ilmenau 98693, Germany
Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China
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Graphical Abstract

It is of great significance to develop efficient, stable, and environmentally friendly bifunctional catalysts in zinc-air batteries (ZABs). This review aims to report the latest research progress on the transition metal compounds as bifunctional catalysts as cathode materials for zinc-air batteries promptly, hoping to provide a reference value for future research in this field.

Abstract

Zinc-air batteries (ZABs) are widely studied because of their high theoretical energy density, high battery voltage, environmental protection, and low price. However, the slow kinetics of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on the air electrode limits the further application of ZABs, so that how to develop a cheap, efficient, and stable catalyst with bifunctional catalytic activity is the key to solving the development of ZABs. Transition metal compounds are widely used as cathode materials for ZABs due to their low cost, high electrocatalytic activity, and stable structure. This review summarizes the research progress of transition metal compounds as bifunctional catalysts for ZABs. The development history, operation principle, and mechanism of ORR and OER reactions are introduced first. The application and development of transition metal compounds as bifunctional catalysts for ZABs in recent years are systematically introduced, including transition metal oxides (TMOs), transition metal nitrides (TMNs), transition metal sulfides (TMSs), transition metal carbides (TMCs), transition metal phosphates (TMPs), and others. In addition, the shortcomings of transition metal compounds as bifunctional catalysts for ZABs were summarized and reasonable design strategies and improvement measures were put forward, aiming at providing a reference for the design and construction of high-performance ZABs cathode materials. Finally, the challenges and future in this field are discussed and prospected.

Keywords

transition metal compoundszinc-air batteriesbifunctional catalystselectrochemicalair electrode

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Nano Research Energy
Volume 3 Issue 1,
March 2024
Article number: e9120092
DOI: 10.26599/NRE.2023.9120092
Cite this article:
Ran Y, Xu C, Ji D, et al. Research progress of transition metal compounds as bifunctional catalysts for zinc-air batteries. Nano Research Energy, 2024, 3: e9120092. https://doi.org/10.26599/NRE.2023.9120092

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Received: 28 June 2023
Revised: 02 August 2023
Accepted: 03 August 2023
Published: 19 September 2023
© The Author(s) 2023. Published by Tsinghua University Press.

The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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