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Research Article | Open Access

Intermetallic ferric nickel silicide alloy derived from magadiite by magnesiothermic reaction as bifunctional electrocatalyst for overall water splitting

Xuyang Jing1Yang Mu1Zhanming Gao1Xueying Dong1Changgong Meng1,2Chi Huang3Yifu Zhang1( )
School of Chemistry, Dalian University of Technology, Dalian 116024, China
College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
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Graphical Abstract

The intermetallic silicide (iron-nickel silicide) is first synthesized via a facile magnesiothermic reduction and employed as bifunctional electrocatalysts for electrochemical water splitting.

Abstract

As the cleanest energy source, hydrogen energy is regarded as the most promising fuel. Water electrolysis, as the primary means of hydrogen production, has constantly been the focus of attention in the energy conversion field. Developing eco-friendly, cheap, safe and efficient catalysts for electrochemical water splitting (EWS) is the key challenge. Herein, the intermetallic silicide alloy is first synthesized via a facile magnesiothermic reduction and employed as bifunctional electrocatalysts for EWS. Ferric-nickel silicide (denoted as FeNiSi) alloy is designed and shows a good electrocatalytic performance for EWS. The lattice distortions of FeNiSi enhance the electrocatalytic activity. Besides, the porous structure affords more active sites and improves the reaction kinetics. As a consequence, FeNiSi delivers an excellent performance with overpotential of 308 mV for oxygen evolution reaction (OER) and 386 mV for hydrogen evolution reaction (HER) at 10 mA·cm−2 in 1 M KOH. The stability structure of intermetallic silicide achieves an outstanding durability with an unchanged potential of 1.66 V for overall water splitting at 10 mA·cm−2 for 15 h. This work not only provides a facile method for the synthesis of intermetallic silicide with considerable porous structures, but also develops the potential of intermetallic silicide alloy as bifunctional electrocatalysts for EWS, which opens up a new avenue for the design and application of intermetallic silicide alloy.

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Nano Research Energy
Cite this article:
Jing X, Mu Y, Gao Z, et al. Intermetallic ferric nickel silicide alloy derived from magadiite by magnesiothermic reaction as bifunctional electrocatalyst for overall water splitting. Nano Research Energy, 2024, 3: e9120104. https://doi.org/10.26599/NRE.2023.9120104

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Received: 15 July 2023
Revised: 07 October 2023
Accepted: 09 October 2023
Published: 03 November 2023
© The Author(s) 2024. Published by Tsinghua University Press.

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