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Original Article | Open Access

Natural Rosin-based Phosphate Diester Surfactant Assisted One-step Synthesis of 3D Flowerlike β-Ni(OH)2/γ-Ni(OH)2 Composite Nano-microspheres

BoShi Wu1, Juan Li2,3, ChunRui Han2, Feng Xu2( )
China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102, China
Beijing Key Laboratory of Lignocellulosic Chemistry, College of Materials Science and Technology, Beijing Forestry University, Beijing, 100083, China
CNNP Jiangsu Nuclear Power Corporation, Lianyungang, Jiangsu Province, 222042, China
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Abstract

Self-assembled uniform 3D flowerlike β-Ni(OH)2/γ-Ni(OH)2 composite nano-microspheres with hollow interiors were successfully synthesized via a facile aqueous-ethanol mixed solvothermal method, using nickel sulfate as a precursor, urea as a precipitant, and dehydroabietic based phosphate diester sodium (DDPDS) as a surfactant. The prepared 3D flowerlike β-Ni(OH)2/γ-Ni(OH)2 composite nano-microspheres were tested as supercapacitors in a two-electrode cell with 6 mol/L KOH electrolyte. In addition, the influence of DDPDS concentration on the morphology and size of 3D flowerlike β-Ni(OH)2/γ-Ni(OH)2 composite nano-microspheres was studied at 180 ℃. X-ray diffraction (XRD), scanning electron microscopy (SEM), BET (Brunauer, Emmett and Teller) techniques, and equity default swap (EDS) were used to characterize the structure, morphology, and size of the as-prepared samples. Moreover, a possible formation mechanism of the 3D flowerlike β-Ni(OH)2/γ-Ni(OH)2composite nano-microspheres was proposed based on the effects of DDPDS concentration and reaction time. The surfactant micelles were used as soft templates to induce the self-assembly of nanosheets. The crystallinity of the 3D flowerlike β-Ni(OH)2/γ-Ni(OH)2 composite nano-microspheres improved with the increase of DDPDS concentration, and the morphology and size of synthetic nano-microspheres could be controlled.

Keywords

nanomaterialhydrothermal synthesisrosinphosphate diester surfactantnickel hydroxide composites

References

[1]

Wang H, Casalongue H S, Liang Y, et al. Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials[J]. Journal of the American Chemical Society, 2010, 132(21): 2-7.
Crossref Google Scholar
[2]

Ni S, Li T, Lu X, et al. Designed constitution of NiO/Ni nanostructured electrode for high performance lithium ion battery[J]. Electrochimica Acta, 2013, 91(3): 267-274.
Crossref Google Scholar
[3]

Harvey A, He X, Godwin I J, et al. Production of Ni(OH)2 nanosheets by liquid phase exfoliation: from optical properties to electrochemical applications[J]. Journal of Materials Chemistry A, 2016, 4(28): 67-72.
Crossref Google Scholar
[4]

Kurra N, Alhebshi N A, Alshareef H N. Microfabricated Pseudocapacitors Using Ni(OH)2 Electrodes Exhibit Remarkable Volumetric Capacitance and Energy Density[J]. Advanced Energy Materials, 2015, 5(2): 8-11.
Crossref Google Scholar
[5]

Wang Y M, Zhao D D, Zhao Y Q, et al. Effect of electrodeposition temperature on the electrochemical performance of a Ni(OH)2 electrode[J]. Rsc Advances, 2012, 2(3): 1074-1082.
Crossref Google Scholar
[6]

Thakur P, Kool A, Bagchi B, et al. The role of cerium(Ⅲ)/yttrium(Ⅲ) nitrate hexahydrate salts on electroactive β phase nucleation and dielectric properties of poly(vinylidene fluoride) thin films[J]. Rsc Advances, 2015, 5(36): 28487-28496.
Crossref Google Scholar
[7]

Yao M, Chen W, Fan X, et al. Wet chemical synthesis and magnetic properties of core–shell nanocolumns of Ni(OH)2Co(OH)2 and their oxides[J]. Crystengcomm, 2011, 13(7): 2593-2598.
Crossref Google Scholar
[8]

Li G, Wang X, Liu L, et al. Controllable Synthesis of 3D Ni(OH)2 and NiO Nanowalls on Various Substrates for High Performance Nanosensors[J]. Small, 2015, 11(6): 731-739.
Crossref Google Scholar
[9]

Lan W, Sun Y, Chen Y, et al. Ultralight and flexible supercapacitor electrodes made from Ni(OH)2 nanosheets doped with Ag nanoparticle/3D graphene composite[J]. Rsc Advances, 2015, 5(27): 20878-20883.
Crossref Google Scholar
[10]

Bastakoti B P, Huang H S, Chen L C, et al. Block copolymer assisted synthesis of porous α-Ni(OH)2 microflowers with high surface areas as electrochemical pseudocapacitor materials[J]. Chemical Communications, 2012, 48(73): 9150-9152.
Crossref Google Scholar
[11]

Wolfart F, Dubal D P, Vidotti M, et al. Hybrid core–shell nanostructured electrodes made of polypyrrole nanotubes coated with Ni(OH)2 nanoflakes for high energy-density supercapacitors[J]. Rsc Advances, 2016, 6(18): 15062-15070.
Crossref Google Scholar
[12]

Han D, Xu P, Jing X, et al. Trisodium citrate assisted synthesis of hierarchical NiO nanospheres with improved supercapacitor performance[J]. Journal of Power Sources, 2013, 235(4): 45-53.
Crossref Google Scholar
[13]

Ji J, Zhang L L, Ji H, et al. Nanoporous Ni(OH)2 thin film on 3D Ultrathin-graphite foam for asymmetric supercapacitor[J]. Acs Nano, 2013, 7(7): 6237-43.
Crossref Google Scholar
[14]

Zhang J P, Wang G W, Tian X H, et al. The genus Carpesium: A review of its ethnopharmacology, phytochemistry and pharmacology[J]. Journal of Ethnopharmacology, 2015, 163: 173-191.
Crossref Google Scholar
[15]

Hongliang Li, Suqin Liu, Chenghuan Huang. Characterization and supercapacitor application of coinlike β-nickel hydroxide nanoplates[J]. Electrochimica Acta, 2011, 58(1): 89-94.
Crossref Google Scholar
[16]

Wang Y, Gai S, Li C, et al. Controlled synthesis and enhanced supercapacitor performance of uniform pomponlike β-Ni(OH)2, hollow microspheres[J]. Electrochimica Acta, 2013, 90(5): 673-681. .
Crossref Google Scholar
[17]

Li J, Luo F, Tian X, et al. A facile approach to synthesis coral-like nanoporous β-Ni(OH)2, and its supercapacitor application[J]. Journal of Power Sources, 2013, 243: 721-727.
Crossref Google Scholar
[18]

Salunkhe R R, Lin J, Malgras V, et al. Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2, composites for asymmetric supercapacitor application[J]. Nano Energy, 2015, 11(59): 211-218.
Crossref Google Scholar
[19]

Junfeng Xie, Xu Sun, Ning Zhang. Layer-by-layer β-Ni(OH)2/graphene nanohybrids for ultraflexible all-solid-state thin-film supercapacitors with high electrochemical performance[J]. Nano Energy, 2013, 2(1): 65-74.
Crossref Google Scholar
[20]

Hongtao Cui, Junying Xue, Wanzhong Ren. Ultra-high specific capacitance of β-Ni(OH)2, monolayer nanosheets synthesized by an exfoliation-free solgel route[J]. Journal of Nanoparticle Research, 2014, 16(9): 2601.
Crossref Google Scholar
[21]

Gambardella A, Negaraju C K, O'Shea P J, et al. Glycogen synthase kinase-3α/β inhibition promotes in vivo amplification of endogenous mesenchymal progenitors with osteogenic and adipogenic potential and their differentiation to the osteogenic lineage[J]. Journal of Bone & Mineral Research, 2011, 26(4): 811-821.
Crossref Google Scholar
[22]

Xiaoli Cheng, Dongming Zhang, Xinwei Liu, et al. Influence of CTAB on morphology, structure, and supercapacitance of β-Ni(OH)2[J]. Ionics, 2015, 21(2): 533-540.
Crossref Google Scholar
[23]

Luo Z, Wang K, Li H, et al. One-dimensional β-Ni(OH)2 nanostructures: Ionic liquid etching synthesis, formation mechanism, and application for electrochemical capacitors[J]. Crystengcomm, 2011, 13(23): 7108-7113.
Crossref Google Scholar
[24]

Ishtikhar M, Ali M S, Atta A M, et al. Interaction of biocompatible natural rosin-based surfactants with human serum albumin: A biophysical study[J]. Journal of Luminescence, 2015, 167: 399-407.
Crossref Google Scholar
[25]

Atta A M, El-Mahdy G A, Al-Lohedan H A, et al. Synthesis of Environmentally Friendly Highly Dispersed Magnetite Nanoparticles Based on Rosin Cationic Surfactants as Thin Film Coatings of Steel[J]. International Journal of Molecular Sciences, 2014, 15(4): 6974-6989.
Crossref Google Scholar
[26]

Xu X T, Ma X L, Duan W G, et al. Synthesis and fungicidal activity of dehydroabietyl-1,2,4-triazolothiazolidinones[J]. Holzforschung, 2013, 67(1): 107-112.
Crossref Google Scholar
[27]

Rao X P, Wu Y, Song Z Q, et al. Synthesis and antitumor activities of unsymmetrically disubstituted acylthioureas fused with hydrophenanthrene structure[J]. Medicinal Chemistry Research, 2011, 20(3): 333-338.
Crossref Google Scholar
[28]

Ishtikhar M, Chandel T I, Ahmad A, et al. Rosin Surfactant QRMAE Can Be Utilized as an Amorphous Aggregate Inducer: A Case Study of Mammalian Serum Albumin[J]. Plos One, 2015, 10(9): 13-27.
Crossref Google Scholar
[29]

Tan W X, Lin Z T, Bu H T, et al. Nano-micelles based on a rosin derivative as potent sorbents and sinking agents with high absorption capabilities for the removal of metal ions[J]. Rsc Advances, 2012, 2(18): 7279-7289.
Crossref Google Scholar
[30]

Zhao K, Deng Z, Wang X C, et al. New diluted ferromagnetic semiconductor with Curie temperature up to 180 K and isostructural to the '122' iron-based superconductors[J]. Nature Communications, 2013, 4(1): 1442-1448.
Crossref Google Scholar
[31]

Han C, Zhu L W, Liu L J, et al. Microwave rosinsurfactants solvothermal synthesis of nickel hydroxide material control agent[J]. Chemistry and Industry of Forest Products, 2009, 29 (10): 149-153.
Google Scholar
[32]

Liu Y, Yu C, Zhang X, et al. Impaired long distance functional connectivity and weighted network architecture in Alzheimer's disease[J]. Cerebral Cortex, 2014, 24(6): 1422.
Crossref Google Scholar
[33]

Li J, Lin H, Chen X, et al. Self-assembled structures and excellent surface properties of a novel anionic phosphate diester surfactant derived from natural rosin acids[J]. Journal of Colloid and Interface Science, 2017, 486: 67-74.
Crossref Google Scholar
[34]

Dai H, Zhang W, Li X, et al. Tolerance and efficacy of autologous or donor-derived T cells expressing CD19 chimeric antigen receptors in adult B-ALL with extramedullary leukemia[J]. Oncoimmunology, 2015, 4(11): 31-37.
Crossref Google Scholar
[35]

Salunkhe R R, Lin J, Malgras V, et al. Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2, composites for asymmetric supercapacitor application[J]. Nano Energy, 2015, 11(59): 211-218.
Crossref Google Scholar
[36]

Zhu L P, Liao G H, Huang W Y, et al. Preparation, characterization and photocatalytic properties of ZnO-coated multi-walled carbon nanotubes[J]. Materials Science & Engineering B, 2009, 163(3): 194-198.
Crossref Google Scholar
[37]

Ashassi-Sorkhabi H, Asghari E, Badakhshan P L. Potentiostatic and cyclic voltammetric deposition of nanostructured manganese oxide for supercapacitor applications[J]. Current Applied Physics, 2014, 14(2): 187-191.
Crossref Google Scholar
[38]

Guo M M, Yin X L, Zhou C H, et al. Ultrasensitive nonenzymatic sensing of glucose on Ni(OH)2-coated nanoporous gold film with two pairs of electron mediators[J]. Electrochimica Acta, 2014, 142: 351-358.
Crossref Google Scholar
[39]

Yan H, Wang J, Li S, et al. l -Lysine assisted synthesis of β-Ni(OH)2, hierarchical hollow microspheres and their enhanced electrochemical capacitance performance[J]. Electrochimica Acta, 2013, 87: 880-888.
Crossref Google Scholar
[40]

Chen S R, Zhai Y P, Xu G L, et al. Ordered mesoporous carbon/sulfur nanocomposite of high performances as cathode for lithium–sulfur battery[J]. Electrochimica Acta, 2011, 56(26): 9549-9555.
Crossref Google Scholar
[41]

Zhang Q R, Li X H, Feng L J, et al. A New Age Constraint on the Onset of the Neoproterozoic Glaciations in the Yangtze Platform, South China[J]. Journal of Geology, 2008, 116(4): 423-429.
Crossref Google Scholar
Paper and Biomaterials
Volume 3 Issue 1,
January 2018
Pages 35-46
DOI: 10.26599/PBM.2018.9260005
Cite this article:
Wu B, Li J, Han C, et al. Natural Rosin-based Phosphate Diester Surfactant Assisted One-step Synthesis of 3D Flowerlike β-Ni(OH)2/γ-Ni(OH)2 Composite Nano-microspheres. Paper and Biomaterials, 2018, 3(1): 35-46. https://doi.org/10.26599/PBM.2018.9260005

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Received: 11 October 2017
Accepted: 30 October 2017
Published: 01 January 2018
© 2018 Paper and Biomaterials Editorial Board

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
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