AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
PDF (627.6 KB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Original Article | Open Access

Preparation of Photo-thermal Cellulose Nanocrystal-based Hydrogel

ZiHe GuoTao MaShiYu Fu( )
State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
Show Author Information

Abstract

Cellulose nanocrystal (CNC) prepared by hydrolysis of cotton linters with sulfuric acid was used to react with chloroauric acid to manufacture a gold nanoparticle/CNC composite. The composite was then graft-copolymerized with N-isopropylacrylamide to obtain a photo-thermal ultrafine gold nanoparticles/CNC-based hydrogel. The hydrogel was studied by performing scanning electron microscopy, and it was found that the prepared hydrogel had a network structure. The temperature of the hydrogel increased from 25℃ to 39℃ and its volume decreased by 30% when it was exposed to visible light (400~750 nm) for 1 h. The experiment results indicated that the prepared photo-thermal CNC-based hydrogel has thermal responsiveness and photo-thermal properties.

References

[1]

Abdul Khalil H P S, Bhat A H, Ireana Yusra A F. Green composites from sustainable cellulose nanofibrils: a review[J]. Carbohydrate Polymers, 2012, 87(2): 963-979.

[2]

Hamad W. On the Development and Applications of Cellulosic Nanofibrillar and Nanocrystalline Materials[J]. The Canadian Journal of Chemical Engineering, 2006, 84(5): 513-519.

[3]

Kalia S, Dufresne A, Cherian B M, et al. Cellulose-Based Bio- and Nanocomposites: a Review[J]. International Journal of Polymer Science, 2011, DOI: 10.1155/2011/837875.

[4]

Mittal N, Jansson R, Widhe M, et al. Ultrastrong and Bioactive Nanostructured Bio-based Composites[J]. ACS Nano, 2017, 11(5): 5148-5159.

[5]

Daniel M C, Astruc D. Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-size-related Properties, and Applications toward Biology, Catalysis, and Nanotechnology[J]. Chemical Reviews, 2004, 104(1): 293-346.

[6]

Ghosh S K, Pal T. Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles: From Theory to Applications[J]. Chemical Reviews, 2007, 107(11): 4797-4862.

[7]

Halperin W P. Quantum size effects in metal particles[J]. Reviews of Modern Physics, 1986, 58(3): 533-606.

[8]

Lopez N. On the origin of the catalytic activity of gold nanoparticles for low-temperature CO oxidation[J]. Journal of Catalysis, 2004, 223(1): 232-235.

[9]

Hajian A, Lindstrom S B, Pettersson T, et al. Understanding the Dispersive Action of Nanocellulose for Carbon Nanomaterials[J]. Nano Letters, 2017, 17(3): 1439-1447.

[10]

Xiong R, Kim H S, Zhang L, et al. Wrapping Nanocellulose Nets around Graphene Oxide Sheets[J]. Angewandte Chemie International Edition, 2018, 57(28): 8508-8513.

[11]

Bajpai A K, Shukla S K, Bhanu S, et al. Responsive polymers in controlled drug delivery[J]. Progress in Polymer Science, 2008, 33(11): 1088-1118.

[12]

Hirokawa Y, Tanaka T. Volume phase transition in a nonionic gel[J]. The Journal of Chemical Physics, 1984, 81(12): 6379-6380.

[13]

Varvarenko S, Voronov A, Samaryk V, et al. Covalent grafting of polyacrylamide-based hydrogels to a polypropylene surface activated with functional polyperoxide[J]. Reactive and Functional Polymers, 2010, 70(9): 647-655.

[14]

Medeiros S F, Santos A M, Fessi H, et al. Stimuli-responsive magnetic particles for biomedical applications[J]. International Journal of Pharmaceutics, 2011, 403(1/2): 139-161.

[15]

Becerra N Y, López B L, Restrepo L M. Thermosensitive behavior in cell culture media and cytocompatibility of a novel copolymer: poly(N-isopropylacrylamide-co-butylacrylate)[J]. Journal of Materials Science: Materials in Medicine, 2013, 24(4): 1043-1052.

[16]

Samchenko Y, Ulberg Z, Korotych O. Multipurpose smart hydrogel systems[J]. Advances in Colloid and Interface Science, 2011, 168(1/2): 247-262.

[17]

Tentor F R, de Oliveira J H, Scariot D B, et al. Scaffolds based on chitosan/pectin thermosensitive hydrogels containing gold nanoparticles[J]. International Journal of Biological Macromolecules, 2017, 102: 1186-1194.

[18]

Wang Q, Mynar J L, Yoshida M, et al. High-water-content mouldable hydrogels by mixing clay and a dendritic molecular binder[J]. Nature, 2010, 463(7279): 339-343.

[19]

Hu Z, Fu S, Tang A. Fabrication of Light-triggered AuNP/CNC/SMP Nano-composites[J]. Bioresources, 2017, DOI: 10.15376/biores.12.1.1982-1990.

[20]

Hu Z, Meng Q, Liu R, et al. Physical Study of the Primary and Secondary Photothermal Events in Gold/Cellulose Nanocrystals (AuNP/CNC) Nanocomposites Embedded in PVA Matrices[J]. ACS Sustainable Chemistry & Engineering, 2016, 5(2): 1601-1609.

[21]

Shi C, Zhu N, Cao Y, et al. Biosynthesis of gold nanoparticles assisted by the intracellular protein extract of Pycnoporus sanguineus and its catalysis in degradation of 4-nitroaniline[J]. Nanoscale Research Letters, 2015, 10(1): 147-154.

[22]

Arockiya Aarthi Rajathi F, Arumugam R, Saravanan S, et al. Phytofabrication of gold nanoparticles assisted by leaves of Suaeda monoica and its free radical scavenging property[J]. Journal of Photochemistry and Photobiology B: Biology, 2014, 135: 75-80.

[23]

Leng W, Pati P, Vikesland P. Room temperature seed mediated growth of gold nanoparticles: mechanistic investigations and life cycle assesment[J]. Environmental Science, 2015, 2: 440-453.

[24]

Marques M S, Zepon K M, Heckler J M, et al. One-pot synthesis of gold nanoparticles embedded in polysaccharide-based hydrogel: physical-chemical characterization and feasibility for large-scale production[J]. International Journal of Biological Macromolecules, 2019, 124: 838-845.

Paper and Biomaterials
Pages 32-39
Cite this article:
Guo Z, Ma T, Fu S. Preparation of Photo-thermal Cellulose Nanocrystal-based Hydrogel. Paper and Biomaterials, 2019, 4(2): 32-39. https://doi.org/10.26599/PBM.2019.9260012

444

Views

16

Downloads

0

Crossref

3

Scopus

Altmetrics

Received: 29 January 2019
Accepted: 27 February 2019
Published: 01 April 2019
© 2019 Paper and Biomaterials Editorial Board

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)

Return