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Research Article | Open Access
Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property
Yan-Ping He 
(
), Jian Zhang ()
(), Jian Zhang ()Abstract
Herein, we present a novel cage-cluster-based framework composed of Ti4L6 (L = embonate) tetrahedra and [Pb4(µ3-OH)4]4+ cubane-like clusters that also exhibits high stability in water, air, and other common solvents. According to the topology study, it exhibits a chiral srs-type network. Integrating titanium cages and lead-oxo clusters into a rigid cage-cluster-based framework significantly enhances its third-order nonlinear optical (NLO) property.
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Article number: 9140002
Cite this article:
Chen R-Y, He Y-P, Zhang J. Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property. Polyoxometalates, 2022, 1(1): 9140002. https://doi.org/10.26599/POM.2022.9140002
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