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Polyoxometalates 2022, 1(2): 9140012 https://doi.org/10.26599/POM.2022.9140012
Review Article | Open Access | Issue | Published: 30 November 2022

Catalytic application of polyoxovanadates in the selective oxidation of organic molecules

Show Author's Information Jie Li,  Di Zhang,  Yingnan Chi( ),  Changwen Hu ( )
Key Laboratory of Cluster Science Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
Keywords:
catalysis, organic transformation, polyoxovanadates, oxidation reaction
Cite this article:
Li J, Zhang D, Chi Y, et al. Catalytic application of polyoxovanadates in the selective oxidation of organic molecules. Polyoxometalates, 2022, 1(2): 9140012. https://doi.org/10.26599/POM.2022.9140012
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Abstract Full text About this article

The structural synthesis and catalytic application of polyoxovanadates (POVs), an important subfamily of polyoxometalates (POMs), have attracted significant attention, owing to their rich coordination chemistry and splendid redox properties. In this review, the advances in the past 10 years in the oxidative transformations catalyzed using all-inorganic POVs, organ functionalized POVs, and POV-based inorganic–organic hybrids have been summarized and are discussed in detail. In particular, we focus on the selective oxidation of organic molecules, including alkanes, alkenes, alcohols, sulfides, sulfur-mustard simulants, and organic dyes. For most oxidative transformations, the active V-peroxo species generated in the presence of hydrogen peroxide or tert-butyl hydroperoxide account for enhanced catalytic activities. In addition, the challenges and prospects in the development of POM-based catalysts are addressed.


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About this article

Catalytic application of polyoxovanadates in the selective oxidation of organic molecules

Show Author's information Jie Li, Di Zhang, Yingnan Chi( ), Changwen Hu ( )
Key Laboratory of Cluster Science Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

Abstract

The structural synthesis and catalytic application of polyoxovanadates (POVs), an important subfamily of polyoxometalates (POMs), have attracted significant attention, owing to their rich coordination chemistry and splendid redox properties. In this review, the advances in the past 10 years in the oxidative transformations catalyzed using all-inorganic POVs, organ functionalized POVs, and POV-based inorganic–organic hybrids have been summarized and are discussed in detail. In particular, we focus on the selective oxidation of organic molecules, including alkanes, alkenes, alcohols, sulfides, sulfur-mustard simulants, and organic dyes. For most oxidative transformations, the active V-peroxo species generated in the presence of hydrogen peroxide or tert-butyl hydroperoxide account for enhanced catalytic activities. In addition, the challenges and prospects in the development of POM-based catalysts are addressed.

Keywords: catalysis, organic transformation, polyoxovanadates, oxidation reaction

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Publication history

Received: 04 August 2022
Revised: 05 October 2022
Accepted: 17 October 2022
Published: 30 November 2022
Issue date: December 2022

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© The Author(s) 2022. Polyoxometalates published by Tsinghua University Press.

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The articles published in this open access journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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