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Review Article | Open Access

Interfacial Challenges and Strategies toward Practical Sulfide-Based Solid-State Lithium Batteries

Ruiqi Guo1,2, Kun Zhang1, Wenbin Zhao1, Zhifan Hu1, Shuqiang Li1, Yuxi Zhong1, Rong Yang3,4, Xinran Wang1,2( ), Jiantao Wang3,4( ), Chuan Wu1,2, Ying Bai1( )
Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China
Yangtze Delta Region Academy of Beijing Institute of Technology, Jiaxing 314019, P. R. China
China Automotive Battery Research Institute Co. Ltd., Beijing 100088, P. R. China
General Research Institute for Nonferrous Metals, Beijing 100088, P. R. China
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Abstract

All-solid-state lithium batteries are considered as the priority candidates for next-generation energy storage devices due to their better safety and higher energy density. As the key part of solid-state batteries, solid-state electrolytes have made certain research progress in recent years. Among the various types of solid-state electrolytes, sulfide electrolytes have received extensive attention because of their high room-temperature ionic conductivity and good moldability. However, sulfide-based solid-state batteries are still in the research stage. This situation is mainly due to the fact that the application of sulfide electrolytes still faces challenges in particular of interfacial issues, mainly including chemical and electrochemical instability, unstable interfacial reaction, and solid–solid physical contact between electrolyte and electrode. Here, this review provides a comprehensive summary of the existing interfacial issues in the fabrication of sulfide-based solid-state batteries. The in-depth mechanism of the interfacial issues and the current research progress of the main coping strategies are discussed in detail. Finally, we also present an outlook on the future development of sulfide-based solid-state batteries to guide the rational design of next-generation high-energy solid-state batteries.

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Energy Material Advances
Volume 4,
2023
Article number: 0022
DOI: 10.34133/energymatadv.0022
Cite this article:
Guo R, Zhang K, Zhao W, et al. Interfacial Challenges and Strategies toward Practical Sulfide-Based Solid-State Lithium Batteries. Energy Material Advances, 2023, 4: 0022. https://doi.org/10.34133/energymatadv.0022

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Received: 07 January 2023
Accepted: 22 February 2023
Published: 23 May 2023
© 2023 Ruiqi Guo et al. Exclusive Licensee Beijing Institute of Technology Press. No claim to original U.S. Government Works.

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