AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Biomedicine and Engineering Article
PDF (4 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Performance Improvement of Working Electrode Using Grafted Polymer Modified with SiO2 Nanoparticles

Muhammed Mizher Radhi1( ), Ahmed Ali Moosa2, Ishraq Abd-Alkareem Khalaf2
Radiological Techniques Department, Health and Medical Technology College-Baghdad, Middle Technology University, Baghdad, (MTU) Iraq
Technical Engineering College-Baghdad, Middle Technology University, Baghdad, (MTU) Iraq
Show Author Information

Abstract

A new modified glassy carbon electrode (GCE) with grafted polymer (GP)/SiO2 nanoparticles (SiO2 NPs) were prepared using mechanical attachment method to produce a new sensor in cyclic voltammetric technique. The new working electrode GP/SiO2 NPs/GCE was characterized by a standard solution of 1 mM K4[Fe(CN)6] with 1 M K2HPO4 as an electrolyte to study the redox current peaks of FeⅡ/FeⅢ ions at different concentrations such as scan rate, pH, determination of diffusion coefficient (Df), reliability and stability of the modified GCE. It was found that the new modified electrode enhanced the redox current peaks of FeⅡ/FeⅢ from 12 μA to 20 μA and -5 μA to -15 μA for oxidation and reduction peaks in GCE, repectevely. So, the current ratio (Ipa/Ipc) for the new modified electrode was 1, and the potential peak separation (ΔEpa-c) was 100 mV, which indicated good electrochemical properties as an irreversible electrode and heterogeneous reaction. Good reliability and stability of modified GCE was obseved with low detection limit. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) analysis of the nano-deposit was also studied.

Keywords

Grafted polymerSilica nanoparticlesCyclic voltammetryFeⅡ/FeⅢGCE

References

[1]

M.M. Radhi, A.A. Moosa, and I.A. Khalaf, Electrochemical characterisation of the redox couple of Fe(Ⅱ)/Fe(Ⅲ) mediated by nano SiO2 modified GCE using cyclic voltammetry. Nano Biomed. Eng., 2018, 10(1): 10-15.
Crossref Google Scholar
[2]

R. Ojani, J.B. Raoof, and S. Zamani, Electrochemical behavior of chloranil chemically modified carbon paste electrode. application to the electrocatalytic determination of ascorbic acid. Electroanal. J., 2005, 17(19): 1740-1745.
Crossref Google Scholar
[3]

M.M. Radhi, W.T. Tan, M.Z.B. Ab Rahman, et al., Electrochemical characterization of the redox couple of [Fe(CN)6]3-Fe(CN)6]4-mediated by a graft polymer modified glassy carbon electrode. J. Chem. Eng. Jpn., 2010, 43: 927-931.
Crossref Google Scholar
[4]

M.M. Radhi, W.T. Tan, and A.J. Haider, Electrochemical characterization of the redox couple of Fe(Ⅱ)/Fe(Ⅲ) mediated by a graft polymer electrode in nonaqueous electrolyte. Int. J. Electrochem. Sci., 2012, 7: 1-10.
Crossref Google Scholar
[5]

M.M. Radhia, F.K.M. Alosfurb, and N.J. Ridhac, Voltammetric characterization of grafted polymer modified with ZnO nanoparticles on glassy carbon electrode. Russian J. Electrochem., 2018, 54(1): 27-32.
Crossref Google Scholar
[6]

M. Hasanzadeh, B. Khalilzadeh, and N. Shadjou, Nanosilica grafted by sulfonic acid: A novel nanocomposite towards amplification of mitoxantrone electrooxidation signals. J. Nanocomposites, 2016, 2(2): 76-83.
Crossref Google Scholar
[7]

M.M. Radhia, E.A.J. Al-Mulla, Voltammetric characterization of grafted polymer electrode self-modification with carbon nanotubes (GPESMCNT). Portugaliae Electrochimica Acta, 2016, 34(2): 97-103.
Crossref Google Scholar
[8]

G. March, T.D. Nguyen, and B. Piro, Modified electrodes used for electrochemical detection of metal ions in environmental analysis. Biosensors (Basel), 2015, 5(2): 241-275.
Crossref Google Scholar
[9]

E. Hübner, J. Allgaier, M. Meyer, et al., Synthesis of Polymer/silica hybrid nanoparticles using anionic polymerization techniques. Macromolecules, 2010, 43(2): 856-867.
Crossref Google Scholar
[10]

M. Hasanzadeh, S. Hassanpour, A.S. Nahr, et al., Electropolymerization of proline supported beta cyclodextrin inside amino functionalized magnetic mesoporous silica nanomaterial: one step preparation, characterization and electrochemical application. Anal. Bioanal. Electrochem., 2018, 10(1): 77-97.
Google Scholar
[11]

F. Bagheralhashemi, A. Omrani, A.A. Rostami, et al., Electrochemical synthesis and characterization of poly o-aminophenol-SiO2 nanocomposite. Materials and Technology, 2014, 48(2): 189-193.
Google Scholar
[12]

A.J.S. Ahammad, J.J. Lee, and M.A. Rahman, Electrochemical sensors based on carbon nanotubes. Sensors, 2009, 9: 2289-2319.
Crossref Google Scholar
[13]

W.T. Tan, M.M. Radhi, M.Z.B. Ab Rahman, et al., Synthesis and characterization of grafted polystyrene with acrylonitrile using gamma-irradiation. J. Applied Sciences, 2010, 10(2): 139-144.
Crossref Google Scholar
[14]

I. Streeter, G.G. Wildgoose, L. Shao, et al., Cyclic voltammetry on electrode surfaces covered with porous layers: An analysis of electron transfer kinetics of single-walled carbon nanotube modified electrodes. Sensors and Actuators B: Chemical, 2008, 133(2): 462-466.
Crossref Google Scholar
[15]

W.T. Tan, G.K. Ng, and A.M. Bond, Electrochemical oxidation of microcrystalline tetrthiafulvalene (TTF) at an electrode-solid-aqueous (KBr) interface. Malysian J. Chem., 2000, 2: 34-42.
Google Scholar
[16]

S.B. Gayathri, P. Kamaraj, M. Arthanareeswari, et al., Electrochemical characterization of guanine and guanosine based biosensors over multi-walled carbon nanotube modified graphite electrode. Chem Sci Trans., 2014, 3(4): 1446-1454.
Google Scholar
[17]

M.T. Rahman, M.E. Hossain, and M.Q. Ehsan, Spectrophotometric and cyclic voltammetric study of interaction of Fe(Ⅲ) with vitamin B3 and vitamin B6. J. Bangladesh Academy of Sciences, 2014, 38(2): 143-153.
Crossref Google Scholar
[18]

G.J. Islam, H.M.N. Akhtar, M.A. Mamun, et al., Investigations on the redox behaviour of manganese in manganese (Ⅱ)-saccharin and manganese (Ⅱ)-saccharin-1,10-phenanthroline complexes. J. Saudi Chem. Soc., 2009, 13: 177-183.
Crossref Google Scholar
[19]

S.J. Watson, R.H. Smallwood, B.H. Brown, et al., Determination of the relationship between the pH and conductivity of gastric juice. Physiol. Meas., 1996, 17(1): 21-27.
Crossref Google Scholar
[20]
P. Zanello, C. Nervi, and F.F. de Biani, Inorganic electrochemistry: Theory, practice and application. The Royal Society of Chemistry, 2003: 212-220.
[21]
D.A. Skoog, F.J. Holler, and S.R. Crouch, Principles of instrumental analysis. Brooks Cole, 2006.
[22]

M.G. Al-Mosawy, M.J. Mohamad, New biopolymer nanocomposites-based epoxidized palm oil/polybutylene succinate modified clay: Preparation and characterization. Rendiconti Lincei, 2017, 28(4): 721-730.
Crossref Google Scholar
[23]

E.A.J. Al-Mulla, Nanoparticles of TiO2-ZnO modified polystyrene-acrylonitrile characterization using glassy carbon electrode. Nano Biomed. Eng., 2018, 10(1), 34-39.
Crossref Google Scholar
[24]

F.H. Jabbar, R.F.C. AL-Hamadanim, Porous media for removal of organic and inorganic contaminants. Nano Biomed. Eng., 2018, 10(2): 104-116.
Crossref Google Scholar
[25]

F.H. Jabbar, Z.J. Kadhim, and A.A. Abdullah, Epoxidized palm oil plasticized polycaprolactone nanocomposites preparation. Nano Biomed. Eng., 2017, 9(3), 214-220.
Crossref Google Scholar
[26]

S.M.M. Al Mutoki, B.A.H.K. Al-Ghzawi, and S.M.A. Amohsin, Raman shift of silicon rubber-nano titania PMNC. Építôanyag Journal of Silicate Based and Composite Materials, 2017, 69(1): 20-23.
Crossref Google Scholar
Nano Biomedicine and Engineering
Volume 10 Issue 2,
June 2018
Pages 156-164
DOI: 10.5101/nbe.v10i2.p156-164
Cite this article:
Radhi MM, Moosa AA, Khalaf IA-A. Performance Improvement of Working Electrode Using Grafted Polymer Modified with SiO2 Nanoparticles. Nano Biomedicine and Engineering, 2018, 10(2): 156-164. https://doi.org/10.5101/nbe.v10i2.p156-164

585

Views

19

Downloads

3

Crossref

5

Scopus

Altmetrics
Received: 30 March 2018
Accepted: 17 May 2018
Published: 28 May 2018
© Muhammed Mizher Radhi, Ahmed Ali Moosa, and Ishraq Abd-Alkareem Khalaf.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
Return