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Research Article | Open Access

Cyclic Voltammetry Study for MnO2 Nanoparticles Modified Carbon Paste Electrode

Emad Salaam Abood1( ), Mothana Salih Mashkoor2, Amer Mousa Jouda2
Department of Medical physics, Hilla University College, Babylon, Iraq
Department of Chemistry, Faculty of Science, University of Kufa, An-Najaf, Iraq
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Abstract

An electrical method was prepared for the measurement of Mn with trace amount in drugs and for the assessment of a sensitive method in comparison with spectrometric and atomic analyzer by a new carbon paste electrode modified with MnO2 nanoparticles. The method was used to study the electro oxidation of manganese ions in solution by cyclic voltammetry (CV) method. The modified electrode displayed strong resolving function for the overlapping voltammetric response of Mn-ion into one well-defined peak. The potential difference between Epa and Epc was > 200 mV; this range referred to the quise-reversible mechanism. The kinetic of electrode was studied at the temperature range from 15 – 35 ℃; the data of voltamograms showed the increase of temperature caused increase of negative shift, which suggested the diffusion electron transferred in the redox process of Mn-ion oxidation. Diffusion coefficient was calculated from the Randles-Sevcik equation and was equal to 1×10-7; the rate constant K was equal to 5.3×10-5; the peak current of Mn-ion increased linearly with its concentration at the range of 0.5 – 4.5 ppm.

Keywords

MnO2 nanoparticlesMnO2 nanoparticlesOxidation-reductionCarbon past electrodes

References

[1]

W.A. Banks, Cell-mediated immune response to human papillomavirus infection. Clin Diagn Lab Immunal, 2001, 8: 209-220.
Crossref Google Scholar
[2]

M. Firoz, M. Graber, Bioavailability of US commercial magnesium preparations. Magnes Res, 2001, 14: 257-262.
Google Scholar
[3]

A. Claire, The definitive guide to magnesium & magnesium supplements. Metabolics, 2013.
Google Scholar
[4]

J.A. DiPalma, Current treatment options for chronic constipation. Rev Gastroenterol Disord, 2004, 4(Suppl 2): S34-S42.
Google Scholar
[5]

Z. Lin, X. Wu, X. Lin, et al., End-column chemiluminescence detection for pressurized capillary electrochromatographic analysis of norepinephrine and epinephrine. Journal of Chromatography, 2007, 12(1-2).
Crossref Google Scholar
[6]

C. Canizares, L. de Castro, Using thermal and spectroscopic data to investigate the thermal behavior of epinephrine. Elsevier Science, 2010, 499: 123-127.
Crossref Google Scholar
[7]

M.H. Sorouraddin, J.L. Manzoori., E. Kargarzadeh, et al., Studies on oxidation of noradrenaline using CuPc as catalyst. Advanced Materials Research, 2012, 496: 419-422.
Crossref Google Scholar
[8]

D.P. Dubal, D.S. Dhawale, T.P. Gujar, et al., Effect of different modes of electrodeposition on superca-pacitive properties of MnO2 thin films. Applied Surface Science, 2011, 257: 3378-3382.
Crossref Google Scholar
[9]

S.C. Pang, M.A. Anderson, and T.W. Chapman, Novel electrode materials for thin-film ultracapacitors: Comparison of electrochemical properties of sol-gel-derived and electrodeposited manganese dioxide. J. Electrochem. Soc., 2000, 147: 444.
Crossref Google Scholar
[10]

H. Beitollahi, M.M. Aedakani, B. Ganjipour, et al., Carbon nanotubes in electrochemical sensors. Biosens. Bioelectron, 2008, 24: 362.
Crossref Google Scholar
[11]

Z. Yang, G. Hu, X. Chen, et al., A review on the synthesis of TiO2 nanoparticles by solution route. Central European Journal of Chemistry, 2012, 54: 279-294.
Crossref Google Scholar
[12]

M. Mazloum-Ardakani, H. Beitollahi, M.A. Sheikh-Mohseni, et al., Electropolymerization of bromothymol blue on carbon paste electrode bulk modified with oxidized multiwall carbon nanotubes and its application in amperometric sensing of epinephrine in pharmaceutical and biological samples. Journal of Electroanalytical Chemistry, 2012, 732: 30-37.
Crossref Google Scholar
[13]

H. Yi, D. Zheng, C. Hu, et al., Functionalized multiwalled carbon nanotubes through in situ electropolymerization of brilliant cresyl blue for determination of epinephrine. Electroanalysis, 2008, 20: 1143.
Crossref Google Scholar
[14]

Y. Ishii, M. Iijima, T. Umemura, et al., Determination of nitrotyrosine and tyrosine by high-performance liquid chromatography with tandem mass spectrometry and immunohistochemical analysis in livers of mice administered acetaminophen. Journal pharma Biomed, 2006, 41: 1325.
Crossref Google Scholar
[15]

J. Hanaee, Carbon film resistor electrode for amperometric determination of acetaminophen in pharmaceutical formulations. Journal of Pharmaceutical and Biomedical, 2007, 43: 1622-1627.
Crossref Google Scholar
[16]

B.O. Regan, M. Gratzel, Synthesis and characterization of metal organic chemical vapour deposited copper titanium oxide (Cu-Ti-O) thin films from single solid source precursors. Journal of Modern Physics, 2013, 4: 12.
Google Scholar
[17]

A. Elkhidir-Suliman, Y. Tang, and L. Xu, Preparation of ZnO nanoparticles and nanosheets and their application to dye-sensitized solar cells. Solar Energy Materials and Solar Cells, 2007, 91: 1658-1660.
Crossref Google Scholar
[18]
P. Kotz, M. Hahna, R. Gallay, J. Power Sources, 2006, 154: 550e555.
Crossref
[19]
C. Masarapu, H.F. Zeng, K.H. Hung, et al., ACS Nano, 2010, 3: 2199e2206.
Crossref
[20]

X. Gao, X. Li, and W. Yu, Low temperature solution synthesis and characterization of ZnO nano-flowers. Materials Research Bulletin, 2007, 42: 1640-1648.
Crossref Google Scholar
[21]

J. Zhang, L.D. Sun, C.S. Liao, et al., Synthesis and characterization of MgF2 and KMgF3 nanorods. Journal of Solid State Chemistry, 2004, 177: 2205-2207.
Crossref Google Scholar
[22]

V. Pandey, S.K. Tripathia, A. Kumar, et al., Linear and nonlinear optical properties of GeSe2-xSnx (0 ≤ x ≤ 0.8) thin films for optoelectronic applications. Journal of Alloys and Compounds, 2017, 709: 640-645.
Crossref Google Scholar
Nano Biomedicine and Engineering
Volume 11 Issue 4,
December 2019
Pages 368-374
DOI: 10.5101/nbe.v11i4.p368-374
Cite this article:
Abood ES, Mashkoor MS, Jouda AM. Cyclic Voltammetry Study for MnO2 Nanoparticles Modified Carbon Paste Electrode. Nano Biomedicine and Engineering, 2019, 11(4): 368-374. https://doi.org/10.5101/nbe.v11i4.p368-374

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Received: 04 September 2019
Accepted: 29 November 2019
Published: 29 November 2019
© Emad Salaam Abood, Mothana Salih Mashkoor, and Amer Mousa Jouda.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
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