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Research Article | Open Access

Influence of Copper and Zinc Doping on Optical Properties of Nano Nickel Oxide Films Deposited by Sol-Gel Method

Ameera J. KadhmIsraa Akram Abbas()
Department of Physics, College of Education for Pure Science, Al-Mustansiriyah University, Baghdad, Iraq
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Abstract

In this study, nano films of pure NiO and films doped with zinc and copper concertation (1%, 3%, 5%) and their mixture for 5% under 100 nm thickness were generated on glass bases using the sol-gel process at a temperature of 298 K. The Cu, Zn-doped NiO and nano NiO optical characteristics were examined throughout a wavelength range of 300 to 800 nm, with high transmittance values of 94% in the Vis-NIR. Transmittance films after doped copper and zinc have dropped to 5% (91% and 92%), respectively. The index of refraction, coefficient of extinction, optical conductivity and the dielctric constants (real and imaginary) were also studied. The results show that the optical conductivity of NiO?Zn and NiO?Cu films increased at the room temperature with increasing the dopant concentrations.

References

[1]

D. Adler, J. Feinleib. Electrical and optical properties of narrow-band materials. Physical Review B, 1970, 2: 3112–3134. doi: 10.1103/physrevb.2.3112

[2]

N. Kikuchi, K. Tonooka. Electrical and structural properties of Ni-doped Cu2O films prepared by pulsed laser deposition. Thin Solid Films, 2005, 486: 33–37. http://dx.doi.org/10.1016/j.tsf.2004.12.044

[3]

A.N. Banerjee, K.K. Chattopadhyay. Recent developments in the emerging field of crystalline p-type transparent conducting oxide thin films. Progress in Crystal Growth and Characterization of Materials, 2005, 50: 52–105. doi: 10.1016/j.pcrysgrow.2005.10.001

[4]

M. Kitao, K. Izawa, K. Urabe, et al. Preparation and electrochromic properties of RF-sputtered NiOx films prepared in Ar/O2/H2 atmosphere. Japanese Journal of Applied Physics, 1994, 33: 6656. doi: 10.1143/jjap.33.6656

[5]

K. Yoshimura, T. Miki, S. Tanemura. Nickel oxide electrochromic thin films prepared by reactive DC magnetron sputtering. Japanese Journal of Applied Physics, 1995, 34: 2440. doi: 10.1143/jjap. 34.2440

[6]

H. Kumagai, M. Matsumoto, K. Toyoda, et al. Preparation and characteristics of nickel oxide thin film by controlled growth with sequential surface chemical reactions. Journal of Materials Science Letters, 1996, 15: 1081–1083. doi: 10.1007/BF00274914

[7]

K.D. Lee, W. Jung. Effect of substrate temperature on the electrochromic properties and cyclic durability of nickel oxide films. Journal of the Korean Physical Society, 2004, 45: 447–454.

[8]

E. Avendaño, L. Berggren, G.A. Niklasson, et al. Electrochromic materials and devices: Brief survey and new data on optical absorption in tungsten oxide and nickel oxide films. Thin Solid Films, 2006, 496: 30–36. doi: 10.1016/j.tsf.2005.08.183

[9]

P.S. Patil, L.D. Kadam. Preparation and characterization of spray pyrolyzed nickel oxide (NiO) thin films. Applied Surface Science, 2002, 199: 211–221. doi: 10.1016/s0169-4332(02)00839-5

[10]

C.M. Lampert. Large-area smart glass and integrated photovoltaics. Solar Energy Materials and Solar Cells, 2003, 76: 489–499. doi: 10.1016/S0927-0248(02)00259-3

[11]

J. Nagai. Advances in research and applications of electrochromic smart windows. Solid State Ionics, 1990, 40-41: 383–387. doi: 10.1016/0167-2738(90)90363-V

[12]

K.D. Lee. Influence of film thickness on the chemical stability of electrochromic tungsten oxide film. Journal of the Korean Physical Society, 2001, 38(1): 33.

[13]

G, Kenanakis. Influence of precursor type, deposition time and doping concentration on the morphological, electrical and optical properties of ZnO and ZnO: Al thin films grown by ultrasonic spray pyrolysis. Thin Solid Films, 2014, 555: 62–67. http://dx.doi.org/10.1016/j.tsf.2013.10.015

[14]

B.W. Shivaraj, H.N.N. Murthy, M. Krishna, et al. Effect of annealing temperature on structural and optical properties of dip and spin coated ZnO thin films. Procedia Materials Science, 2015, 10: 292–300. doi: 10.1016/j.mspro.2015.06.053

[15]

M. Caglar, F. Yakuphanoglu. Structural and optical properties of copper doped ZnO films derived by Sol–gel. Applied Surface Science, 2012, 258: 3039–3044. doi: 10.1016/j.apsusc.2011.11.033

[16]

J.G. Lv, K. Huang, X.M. Chen, et al. Optical constants of Na-doped ZnO thin films by Sol–gel method. Optics Communications, 2011, 284: 2905–2908. doi: 10.1016/j.optcom.2011.01.075

[17]

M.D. Irwin, D.B. Buchholz, A.W. Hains, et al. p-Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells. Proceedings of the National Academy of Sciences, 2008, 105: 2783–2787. doi: 10.1073/pnas.0711990105

[18]

R.S. Kate, S.C. Bulakhe, R.J. Deokate. Co doping effect on structural and optical properties of nickel oxide (NiO) thin films via spray pyrolysis. Optical and Quantum Electronics, 2019, 51: 319. http://dx.doi.org/10.1007/s11082-019-2026-2

[19]
S. Parwani, P. Dubey, R.C. Dixit, et al. AIP Conference Proceedings, 2019, 2100: 020092.
[20]

N.F.A. Shammary. Optical characteristics of NiO thin film on glass formed by chemical spray pyrolysis. Journal of Kufa-Physics, 2010, 2(1): 22–27.

[21]
A.J. Hassan. Journal of Modern Physics, 2014, 5: 2184–2191.
[22]

A.K. Srivastava, S. Thota, J. Kumar. Preparation, microstructure and optical absorption behaviour of NiO thin films. Journal of Nanoscience and Nanotechnology, 2008, 8: 4111–4115. doi: 10.1166/jnn.2008.an36

[23]

A.A. Al-Ghamdi, W.E. Mahmoud, S.J. Yaghmour, et al. Structure and optical properties of nanocrystalline NiO thin film synthesized by Sol–gel spin-coating method. Journal of Alloys and Compounds, 2009, 486: 9–13. doi: 10.1016/j.jallcom.2009.06.139

[24]

L. Zhao, G. Su, W. Liu, et al. Optical and electrochemical properties of Cu-doped NiO films prepared by electrochemical deposition. Applied Surface Science, 2011, 257: 3974–3979. http://dx.doi.org/10.1016/j.apsusc.2010.11.160

Nano Biomedicine and Engineering
Pages 360-366
Cite this article:
Kadhm AJ, Abbas IA. Influence of Copper and Zinc Doping on Optical Properties of Nano Nickel Oxide Films Deposited by Sol-Gel Method. Nano Biomedicine and Engineering, 2022, 14(4): 360-366. https://doi.org/10.5101/nbe.v14i4.p360-366
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