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Article | Open Access

Photoactivation of Ion-exchangeable Trititanate Nanotubes Modified by MS (M = Cd, Zn) Nanoparticles

Hong Li1Yingge Zhang1( )Weiping Huang2( )
Institute of Pharmacology and Toxicology and Key Laboratory of Nanopharmacology and Nanotoxicology, Beijing Academy of Medical Sciences, Beijing 100850 P. R. China
Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China
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Abstract

Ion-exchangable trititanate nanotubes synthesized by the alkali treatment of TiO2 (anatase) are modified by MS (M = Cd, Zn) nanoparticles via a simple wet chemical process. The obtained samples are characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and Raman spectroscopy. The photocatalytic activities of the samples are evaluated upon the oxidation of methyl orange under UV light illumination. Results show that the photoactivation may be caused by the strong coupling between the nanotube and the nanoparticles, which is a direct consequence of the ion exchange property of the trititanate wall structure during the formation of TiO2/MS.

References

[1]

Xu JC, M Lu, Guo XY, Li HL. Zinc ions surface-doped titanium dioxide nanotubes and its photocatalysis activity for degradation of methyl orange in water. J Mol Catal A 2005; 226: 123-127. doi:10.1016/j.molcata.2004.09.051

[2]

Idakiev V, Yuan ZY, Tabakova T, Su BL. Titanium oxide nanotubes as supports of nano-sized gold catalysts for low temperature water-gas shift reaction. Appl Catal A 2005; 281: 149-155. doi:10.1016/j.apcata.2004.11.021

[3]

Zhu BL, Guo Q, Huang XL, Wang SR, Zhang SM, Wu SH, Huang WP. Characterization and catalytic performance of TiO2 nanotubes-supported gold and copper particles. J Mol Catal A 2006; 249: 211-217. doi:10.1016/j.molcata.2006.01.013

[4]

Mor GK, Shankar K, Paulose M, Varghese OK. Use of Highly-Ordered TiO2 Nanotube Arrays in Dye-Sensitized Solar Cells. Nano Lett 2006; 6 ; 215-218. doi:10.1021/nl052099j

[5]

Kasuga T, Hiramatsu M, Hoson A. Formation of Titanium Oxide Nanotube. Langmuir 1998; 14: 3160-3163. doi: 10.1021/la9713816

[6]

Hodos M, Horvath E, Haspel H, Kukovecz A, Konya Z, Kiricsi I. Photosensitization of ion-exchangeable titanate nanotubes by CdS nanoparticles. Chem Phys Lett 2004; 399: 512-515. doi:10.1016/j.cplett.2004.10.064

[7]

Kukovecz A, Hodos M, Konya Z, Kiricsi I. Complexassisted one-step synthesis of ion-exchangeable titanate nanotubes decorated with CdS nanoparticles. Chem Phys Lett 2005; 411: 445-449. doi:10.1016/j.cplett.2005.06.073

[8]

Sun XM, Li YD. Synthesis and Characterization of IonExchangeable Titanate Nanotubes. Chem Eur J 2003; 9: 2229-2238. doi:10.1002/chem.200204394

[9]

Bavykin DV, Lapkina AA, Plucinski PK, Friedrich JM, Walsh FC. TiO2 nanotube-supported ruthenium(Ⅲ) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen. J Catal 2005 ; 235 : 10-17. doi:10.1016/j.jcat.2005.07.012

[10]

Yoshida R, Suzuki Y, Yoshikawa S. Effects of synthetic conditions and heat-treatment on the structure of partially ion-exchanged titanate nanotubes. Mater Chem Phys 2005; 91: 409–416. doi:10.1016/j.matchemphys.2004.12.010

[11]

Zheng SR, Yin DQ, Miao W, Anderson GK. Cr(Ⅵ) photoreduction catalysed by ion-exchangeable layered compound. J Photoch Photobio A 1998; 117: 105–109. doi:10.1016/S1010-6030(98)00321-9

[12]

Ferreira OP, Souza Filho AG, Mendes Filhob J, Alve OL. Unveiling the Structure and Composition of Titanium Oxide Nanotubes through Ion Exchang Chemical Reactions and Thermal Decomposition Processes. J Braz Chem Soc 2006; 17: 393-402. doi:10.1590/S0103-50532006000200025

[13]

Ma R, Fukuda K, Sasaki T, Osada M, Bando Y. Structural features of titanate nanotubes/nanoblts revealed by Raman, X-ray absorption spectra and electron diffractions. J Phys Chem B 2005; 109: 6210-6214. doi:10.1021/jp044282r

[14]

Mao YB, Wong SS. Size- and Shape-Dependent Transformation of Nanosized Titanate into Analogous Anatase Titania Nanostructures. J Am Chem Soc 2006; 128: 8217-8226. doi:10.1021/ja0607483

Nano Biomedicine and Engineering
Pages 32-37
Cite this article:
Li H, Zhang Y, Huang W. Photoactivation of Ion-exchangeable Trititanate Nanotubes Modified by MS (M = Cd, Zn) Nanoparticles. Nano Biomedicine and Engineering, 2009, 1(1): 32-37. https://doi.org/10.5101/nbe.v1i1.p32-37

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Received: 10 November 2009
Accepted: 06 December 2009
Published: 09 December 2009
© 2009 H. Li et al.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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