AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Biomedicine and Engineering Article
PDF (1.2 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Article | Open Access

Experimental and Theoretical Studies of 1,3-diaminopropylene Derivatives as Potential Antioxidative Agents for Copper Nanoparticles in Hydrothermal System

Guo Gao( ), Xueqing Zhang, Kan Wang, Lili Feng, Peng Huang, Yixia Zhang, Chunlei Zhang, Meng He, Xiao Zhi
Department of Bio-Nano-Science and Engineering, National Key Laboratory of Nano/Micro Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of Ministry of Education, Institute of Micro-Nano Science and Technology, Shanghai Jiao Tong University, Shanghai, 200240, China
Show Author Information

Abstract

Novel 1,3-diamino-propylene derivatives as potential corrosion inhibitors for copper nanoparticles has been studied by density functional theory (DFT) calculations, Fourier transform infrared spectra (FTIR), thermogravimetric and Zeta potential analysis. 1,3-Dimorpholin-propylene was considered to be the most promising inhibitor for copper nanoparticles. Thermogravimetric results indicated the oxidation temperature of copper nanoparticles decreased from 286.50 ℃ (blank) to 270.1 ℃ (inhibitor). FTIR spectra indicated the addition of inhibitor could optimize the adsorption behavior of surfactant molecules on the surface of copper nanoparticles. Zeta potential results showed 1,3-dimorpholin-propylene could improve the stability of copper nanoparticles (~0 mV for blank, and -2.5 mV for inhibitor).

Keywords

CorrosionDFTZeta potentialCopper nanoparticles

References

1

Xu Q, Zhao Y, Xu J, Zhu J. Preparation of functionalized copper nanoparticles and fabrication of a glucose sensor. Sens. Actuators, B 2006; 114:379.doi: 10.1016/j.snb.2005.06.005
Crossref Google Scholar
2

Yeshchenko OA, Dmitruk IM, Dmytruk AM, Alexeenko AA. Influence of annealing conditions on size and optical properties of copper nanoparticles embedded in silica matrix. Mater. Sci. Eng., B 2007; 137:247.doi: 10.1016/j.mseb.2006.11.030
Crossref Google Scholar
3

Singh P, Katyal A, Kalra R. Chandra R. Copper nanoparticles in an ionic liquid: an efficient catalyst for the synthesis of bis-(4-hydroxy-2-oxothiazolyl) methanes. Tetrahedron Lett. 2008; 49: 727.doi: 10.1016/j.tetlet.2007.11.106
Crossref Google Scholar
4

Yu B, Woo P, Erb U. Corrosion behaviour of nanocrystalline copper foil in sodium hydroxide solution. Scr. Mater. 2007; 56:353.doi: 10.1016/j.scriptamat.2006.11.007
Crossref Google Scholar
5

Heli H, Jabbari A, Zarghan M, Moosavi-Movahedi A.A. Copper nanoparticles–carbon microparticles nanocomposite for electrooxidation and sensitive detection of sotalol. Sens. Actuators, B 2009; 140:245. doi: 10.1016/j.snb.2009.04.021
Crossref Google Scholar
6

Yoshida K, Gonzalez-Arellano C, Luque R, Gai PL. Efficient hydrogenation of carbonyl compounds using low-loaded supported copper nanoparticles under microwave irradiation. Appl. Catal., A. 2010; 379:38. doi: 10.1016/j.apcata.2010.02.028
Crossref Google Scholar
7

Mott D, Galkowski J, Wang L, Luo J, Zhong C. Synthesis of Size-Controlled and Shaped Copper Nanoparticles Langmuir, 2007; 23: 5740. doi: 10.1021/la0635092
Crossref Google Scholar
8

Chen S, Sommers JM. Alkanethiolate-Protected Copper Nanoparticles: Spectroscopy, Electrochemistry, and Solid-State Morphological Evolution†. J. Phys. Chem. B. 2001; 105:8816. doi: 10.1021/jp011280n
Crossref Google Scholar
9

Chen L, Zhang D, Chen J, Zhou H, Wan H. The use of CTAB to control the size of copper nanoparticles and the concentration of alkylthiols on their surfaces. Mater. Sci. Eng., A 2006; 415:156. doi: 10.1016/j.msea.2005.09.060
Crossref Google Scholar
10

Yıldırım A, Cetin M. Synthesis and evaluation of new long alkyl side chain acetamide, isoxazolidine and isoxazoline derivatives as corrosion inhibitors. Corros. Sci. 2008; 50:155. doi: 10.1016/j.corsci.2007.06.015
Crossref Google Scholar
11

Moretti G, Guidi F. Tryptophan as copper corrosion inhibitor in 0.5 M aerated sulfuric acid. Corros. Sci. 2002; 44: 1995. doi: 10.1016/S0010-938X(02)00020-3
Crossref Google Scholar
12

Ali SA, Al-Muallem HA, Rahman SU, Saeed MT. Bisisoxazolidines: A new class of corrosion inhibitors of mild steel in acidic media. Corros. Sci. 2008; 50:3070. doi: 10.1016/j.corsci.2008.08.011
Crossref Google Scholar
13

Bentiss F, Traisnel M, Lagrenee M. The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media. Corros. Sci. 2000; 42:127. doi: 10.1016/S0010-938X(99)00049-9
Crossref Google Scholar
14

Obot IB, Obi-Egbedi NO. 2,3-Diphenylbenzoquinoxaline: A new corrosion inhibitor for mild steel in sulphuric acid. Corros. Sci. 2010; 52: 282. doi: 10.1016/j.corsci.2009.09.013
Crossref Google Scholar
15

Jamil H.E, Shriri A, Boulif R, Bastos C, Montemor M.F, Ferreira MGS. Electrochemical behaviour of amino alcohol-based inhibitors used to control corrosion of reinforcing steel. Electrochim. Acta 2004; 49:2753. doi: 10.1016/j.electacta.2004.01.041
Crossref Google Scholar
16

Quraishi M.A, Sharma H.K. 4-Amino-3-butyl-5-mercapto-1,2,4-triazole: a new corrosion inhibitor for mild steel in sulphuric acid. Mater. Chem. Phys. 2002; 78:18.doi: 10.1016/S02540584(02)00313-9
Crossref Google Scholar
17

Nmai CK. Multi-functional organic corrosion inhibitor. Cem. Concr. Compos. 2004; 26:199. doi: 10.1016/S0958-9465(03)00039-8
Crossref Google Scholar
18

Neville A, Wang C. Multi-functional organic corrosion inhibitor. Wear, 2009; 267:195. doi: 10.1016/j.wear.2009.01.038
Crossref Google Scholar
19

Reznik VS, Akamsin VD, Khodyrev YuP, Galiakberov RM, Efremov Yu Ya, Tiwari L. Mercaptopyrimidines as inhibitors of carbon dioxide corrosion of iron. Corros. Sci. 2008; 50:392. doi: 10.1016/j.corsci.2007.06.021
Crossref Google Scholar
20

Kandemirli F, Sagdinc S. Theoretical study of corrosion inhibition of amides and thiosemicarbazones. Corros. Sci. 2007; 49:2118. doi: 10.1016/j.corsci.2006.10.026
Crossref Google Scholar
21

Gece G. The use of quantum chemical methods in corrosion inhibitor studies. Corros. Sci. 2008; 50:2981. doi: 10.1016/j.corsci.2008.08.043
Crossref Google Scholar
22

Jamalizadeh E, Hosseini SMA, Jafari AH. Quantum chemical studies on corrosion inhibition of some lactones on mild steel in acid media. Corros. Sci. 2009; 51:1428. doi: 10.1016/j.corsci.2009.03.029
Crossref Google Scholar
23

Rodríguez-Valdez LM, Martínez-Villafañe A, Glossman-Mitnik D. Computational simulation of the molecular structure and properties of heterocyclic organic compounds with possible corrosion inhibition properties. J. Mol. Struct.: THEOCHEM. 2005; 713:65. doi: 10.1016/j.theochem.2004.10.036
Crossref Google Scholar
24

Gao G, Wu HX, He R, Cui DX. Corrosion inhibition during synthesis of Cu2O nanoparticles by 1,3-diaminopropylene in solution. Corros. Sci. 2010; 52:2804. doi: 10.1016/j.corsci.2010.04.028
Crossref Google Scholar
25

Mott D, Galkowski J, Wang L, Luo J, Zhong CJ. Synthesis of Size-Controlled and Shaped Copper Nanoparticles. Langmuir. 2007; 23:5740. doi: 10.1021/la0635092
Crossref Google Scholar
26

Cruz J, Pandiyan T, García-Ochoa E. A new inhibitor for mild carbon steel: Electrochemical and DFT studies. J. Electroanal. Chem. 2005; 583:8.doi: 10.1016/j.jelechem.2005.02.026
Crossref Google Scholar
Nano Biomedicine and Engineering
Volume 3 Issue 2,
June 2011
Pages 130-136
DOI: 10.5101/nbe.v3i2.p130-136
Cite this article:
Gao G, Zhang X, Wang K, et al. Experimental and Theoretical Studies of 1,3-diaminopropylene Derivatives as Potential Antioxidative Agents for Copper Nanoparticles in Hydrothermal System. Nano Biomedicine and Engineering, 2011, 3(2): 130-136. https://doi.org/10.5101/nbe.v3i2.p130-136

344

Views

7

Downloads

0

Crossref

1

Scopus

Altmetrics
Published: 30 June 2011
© 2011 G.Gao et al.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
Return