AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
PDF (515.4 KB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Article | Open Access

Au-Ag Gradient Alloy Nanoparticles with Extended Surface Plasmon Resonance Wavelength: Synthesis via Microreaction

Li Sun1Weiling Luan1( )Shan-tung Tu1Yue Jin Shan2
The Key Laboratory of Safety Science of Pressurized System (MOE), School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237, China
Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Japan
Show Author Information

Abstract

Au-Ag gradient alloy nanoparticles were directly synthesized in a microreaction system with their surface plasmon resonance been facilely adjusted. The surface plasmon resonance wavelength was red-shifted through increasing the raw ratio of Au3+:Ag+, decreasing the synthesis temperature or the residence time. A linear relationship was found between the surface plasmon resonance wavelength and the synthesis temperature, or the residence time. The range of surface plasmon resonance wavelength of monodispersed Au-Ag gradient alloy could be extended to 548 nm generated on the enrichment of Au as outer layer. It provided a suitable way to prepare Au-Ag gradient alloy NPs with longer surface plasmon resonance wavelength than 520 nm (Au) at low temperature.

References

[1]

Burda C, Chen XB, Narayanan R, EI-Sayed MA. Chemistry and Properties of Nanocrystals of Different Shapes. Chem. Rev. 2005; 105: 1025-1102. doi: 10.1021/cr030063a.

[2]
(a) Bardhan R, Grady NK, Cole JR, Joshi A, Halas NJ. Fluorescence Enhancement by Au Nanostructures: Nanoshells and Nanorods. ACS Nano 2009; 3: 744-752. doi: 10.1021/nn900001q. (b) Quarta A, Di Corato R, Manna L, Argentiere S, Cingolani R, Barbarella G, Pellegrino T. Multifunctional Nanostructures Based on Inorganic Nanoparticles and Oligothiophenes and Their Exploitation for Cellular Studies. J. Am. Chem. Soc. 2008; 130: 10545-10555. doi: 10.1021/ja800102v.
[3]
(a) Huang XH, EI-Sayed IH, Qian W, EI-Sayed MA. Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods. J. Am. Chem. Soc. 2006; 128: 2115-2120. doi: 10.1021/ja057254a. (b) Nann T. Nanoparticles in photodynamic therapy. Nano Biomed. Eng. 2011; 3: 137-143. doi: 10.5101/nbe.v3i2.p137-143.
[4]
(a) Liong M, Lu J, Kovochich M, Xia T, Ruehm SG, Nel AE, Tamanoi F, Zink JI. Multifunctional Inorganic Nanoparticles for Imaging, Targeting, and Drug Delivery. ACS Nano 2006; 2: 889-896. doi: 10.1021/nn800072t. (b) Cui DX, Zhang H, Wang K, Gao F, Zhang, XQ, Asahi T, He R, Osaka, T. Gold nanoparticles enhance efficiency of in vitro gene transcription-translation system. Nano Biomed. Eng. 2011; 3: 120-125. doi: 10.5101/nbe.v3i2.p120-125.
[5]

Devarajan S, Bera P, Sampath S. Bimetallic nanoparticles: A single step synthesis, stabilization, and characterization of Au-Ag, Au-Pd, and Au-Pt in sol-gel derived silicates. J. Colloid Interf. Sci. 2005; 290: 117-129. doi: 10.1016/j.jcis.2005.04.034.

[6]
(a) Yang J, Lee JY, Too H-P. Core-Shell Ag-Au Nanoparticles from Replacement Reaction in Organic Medium. J. Phys. Chem. B 2005; 109: 19208-19212. doi: 10.1021/jp052242x. (b) Chen DP, Zhu G, Zhu XG, Qiao XL, Chen JG. Effects of silver nanowires on the electrochemical performance of LiFePO4. Nano Biomed. Eng. 2011; 3: 19-24. doi: 10.5101/nbe.v3i1.p19-24.
[7]

Wang C, Peng S, Chan R, Sun SH. Synthesis of AuAg Alloy Nanoparticles from Core/Shell-Structured Ag/Au. Small 2009; 5: 567-570. doi: 10.1002/smll.200801169.

[8]
(a) Uppal MA, Ewing MB, Parkin IP. One-Pot Synthesis of Core-Shell Silver-Gold Nanoparticle Solutions and Their Interaction with Methylene Blue Dye. Eur. J. Inorg. Chem. 2011; 4534-4544. doi: 10.1002/ejic.201100536. (b) Chen SH, Ji YX, Lian Q, Wen YL, Shen HB, Jia, NQ. Gold nanorods coated with multilayer polyelectrolyte as intracellular delivery vector of antisense oligonucleotides. Nano Biomed. Eng. 2010; 2: 15-23. doi: 10.5101/nbe.v2i1.p15-23.
[9]

Wang A-Q, Liu J-H, Lin T-S, Mou C-Y. A novel efficient Au-Ag alloy catalyst system: preparation, activity, and characterization. J. Cata. 2005; 233: 186-197. doi: 10.1016/j.jcat.2005.04.028.

[10]
(a) Mallin MP, Murphy C. Solution-phase synthesis of sub-10 nm Au-Ag alloy nanoparticles. Nano Lett. 2002; 2: 1235-1237. doi: 10.1021/nl025774n. (b) Zhang YG. Relations between size and function of natural substance particles. Nano Biomed. Eng. 2011; 3: 1-16. doi: 10.5101/nbe.v3i1.p1-16.
[11]

Wang C, Yin HF, Chan R, Peng S, Dai S, Sun SH. One-pot synthesis of oleylamine coated AuAg alloy NPs and their catalysis for CO oxidation. Chem Mater 2009, 21: 433-435. doi: 10.1021/cm802753j.

[12]
(a) Nightingale MA, Mello JC. Microscale synthesis of quantum dots. J. Mater. Chem. 2010; 20: 8454-8463. doi: 10.1039/c0jm01221a. (b) Luan WL, Yang HW, Tu S-T. Synthesis of efficiently green luminescent CdSe/ZnS nanocrystals via microfluidic reaction. Nanoscale Res. Lett. 2008; 3: 134-139. doi: 10.1007/s11671-008-9125-5. (c) Tu S-T, Yu XH, Luan WL, Loewe H. Development of micro chemical, biological and thermal systems in China: A review. Chem. Eng. J. 2010; 163: 165-179. doi: 10.1016/j.cej.2010.07.021.
[13]

Poovathinthodiyi R, Jie F, Scoot LW. A simple and green method for the synthesis of Au, Ag, and Au-Ag alloy nanoparticles. Green Chem. 2006; 8: 34-38. doi: 10.1039/b512540e.

Nano Biomedicine and Engineering
Pages 232-235
Cite this article:
Sun L, Luan W, Tu S-t, et al. Au-Ag Gradient Alloy Nanoparticles with Extended Surface Plasmon Resonance Wavelength: Synthesis via Microreaction. Nano Biomedicine and Engineering, 2011, 3(4): 232-235. https://doi.org/10.5101/nbe.v3i4.p232-235

314

Views

10

Downloads

5

Crossref

0

Scopus

Altmetrics

Published: 31 December 2011
© 2011 L. Sun, et al.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

Return