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Research Article | Open Access

Bentonite-Based Nano Organic Clay Using Chalcone and Azo Dye as Organophilic Reagents

Department of Chemistry, Faculty of Science, University of Kufa, P.O. Box 21, An-Najaf 54001, Iraq
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Abstract

Organclays (OBNTs) were prepared using two new organic surfactants including 3-(4-aminophenyl)-1-(4-chlorophenyl)prop-2-en-1-on (CH) synthesized from a ClaisenɃSchmidt condensation reaction between p-aminoacetophenone and p-chlorobenzaldehyde; and 4-((4-nitrophenyl)diazenyl)-N-(pyrimidin-2-yl) (AZ) prepared from reaction of sulfadiazine and p-nitoaniline. Organclays OBNTs were characterized by Fourier transform infrared spectroscopy (FTIR) to evaluate the incorporation of surfactants in bentonite. The X-ray diffraction (XRD) technique was utilized to indicate the basal spacing of the treated clay as a measure of susceptibility of new organoclays. The FTIR and XRD results showed that the OBNTs were successfully incorporated in the layers of bentonite clay. Thermogravimetric analysis (TGA) was also used to determine thermal stability. An enhancement in stability was observed in OBNTs compare to pure bentonite. OBNTs prepared in this study can be used to produce disposable packaging a promising polymer nanocomposite.

Keywords

Sodium bentoniteModificationSurfactantsOrganic cations

References

[1]

S. Yun-Hwei, Preparations of organobentonite using nonionic surfactants. Chemosphere, 2001, 44: 989-995.

Crossref Google Scholar
[2]

A.M. Motawie, M.M. Madany, A.Z. El-Dakrory, et al., Physico-chemical characteristics of nano-organobentonite prepared using different organo-modifiers. Egy. J. Petroleum., 2014, 23: 331-338.

Crossref Google Scholar
[3]

W.F. Jaynes, S.A. Boyd, Clay mineral type and organic compound sorption by hexadecyltrimethyl ammonium exchanged clays. Soil. Sci. Soc. Am. J., 1991, 55: 43-48.

Crossref Google Scholar
[4]

J. Zhang, C.A. Wilkie, Preparation and flammability properties of polyethylene-clay nanocomposites. Polym. Degrad. Stability, 2003, 80: 163-169.

Crossref Google Scholar
[5]

M. Maiti, A.K. Bhowmick, Structure and properties of some novel fluorolastomer/clay nanocomposites with special reference to their interaction. J. Appl. Polym. Sci., 2005, 44: 162-176.

Crossref Google Scholar
[6]

E.A.J. Al-Mulla, Preparation of polylactic acid/epoxidized palm oil/fatty nitrogen compounds modified clay nanocomposites by melt blending. Polym. Sci - Series A., 2011, 53: 149-157.

Crossref Google Scholar
[7]

M.A. Motawie, N.M. Ahmed, S.M. ElMesallamy, et al., Unsaturated polyesters/layered silicate nanocomposites: Synthesis and characterization. IOSR J. of Appl. Chem., 2014, 7(10): 34-43.

Crossref Google Scholar
[8]
S.M.M. Al-Mutoki, B.A.K. Al-Ghzawi, and A.A. Abdullah, et al., AIR AlAmmar Synthesis and characterization of new epoxy/titanium dioxide nanocomposite. Nano Biomed. Eng., 7 (4): 135-138.
Crossref
[9]

S.A. Sadiq, E.M. Atiyah, and A.T. Numan, Synthesis and characterization of new bidentatechalcone ligand type (NO) and its MnІІ, CoІІ, NiІІ and CuІІ complexes with study of their antibacterial activity. Diyala J. Pure Sci., 2015, 11(3): 2222-2235.

Google Scholar
[10]

F.W. Salman, S.W. Radhi, and A.M. Jodh, Preparation and study antibacterial activity of a new polymer. J. of Babylon Pure Appl. Sci., 2015, 2: 23-31.

Google Scholar
[11]

E.A.J. Al-Mulla, A.H. Suhail, and A.A. Saadon, New biopolymer nanocomposites based on epoxidized soybean oil plasticizedpoly(lactic acid)/fatty nitrogen compounds modified clay: Preparation and characterization. Ind. Crops Prod.., 2011, 33: 23-29.

Crossref Google Scholar
[12]

E.A.J. Al-Mulla, W.M.Z. Yunus, N.A. Ibrahim, et al., Enzymatic synthesis of fatty amides from palm olein. J. Oleo. Sci., 2010, 59(2): 157-160.

Crossref Google Scholar
[13]

E.A.J. Al-Mulla, W.M.Z. Yunus, and N.A. Ibrahim, Epoxidizedpalmoil plasticized polylactic acid/fatty nitrogen compound modifiedclaynanocomposites: Preparation and characterization. J. Polym. Comp., 2010, 18(8): 451-460.

Crossref Google Scholar
[14]

W.M.Z. Yunus, N.A.B. Ibrahim, and M.Z.A. Rahman, Difatty acyl urea from corn oil: Synthesis and characterization. J. Oleo Sci., 2010, 59: 157-160.

Crossref Google Scholar
[15]

Y.J. Phua, W.S. Chow, and Z.A. MohdIshak, Organomodification of montmorillonite and its effects on the properties of poly(butylene succinate) nanocomposites. Polym. Eng. Sci., 2013, 53: 1947-1957.

Crossref Google Scholar
[16]

B.A. Mansor, H.H. Wisam, N.I. Azowa, Modification of montmorillonite by new surfactants. J. of. Eng. Appl. Sci., 2009, 4(3): 184-188.

Google Scholar
[17]
F.H.J. Al-Shemmari, E.A.J. Al-Mulla, and A.A. Rabah, A comparative study of different surfactants for natural rubber clay nanocomposite preparation. Rendiconti Lincei. 25(3): 409-413.
Crossref
[18]

L. Guo, S. Wu, and F. Zeng, Synthesis and Fluorescence property of terbium complex with novel Schiff-base macromolecular legend. Eur. Polymer J., 2006, 42: 1670-1675.

Crossref Google Scholar
[19]

E. Ramachandranl, K. Baskaran, and S. Natarajan, XRD, thermal, FTIR and SEM studies on gel grown gamma-glycine crystals. Crys. Res. Tec., 2007, 42: 73-77.

Crossref Google Scholar
[20]

S.M.M. Al-Mutoki, A.G. Wadday, and A.A. Abdullah, Effect of nano TiO2 dopant on electrical properties of SR8100/nano TiO2 PMNC. Results Phys., 2016, 6: 551-553.

Crossref Google Scholar
Nano Biomedicine and Engineering
Volume 9 Issue 2,
June 2017
Pages 124-128
DOI: 10.5101/nbe.v9i2.p124-128
Cite this article:
Al-Mosawy MGA-A, Al-Mulla EAJ, Mohamad MJ. Bentonite-Based Nano Organic Clay Using Chalcone and Azo Dye as Organophilic Reagents. Nano Biomedicine and Engineering, 2017, 9(2): 124-128. https://doi.org/10.5101/nbe.v9i2.p124-128
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