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Research Article | Open Access

Bentonite-Based Nano Organic Clay Using Chalcone and Azo Dye as Organophilic Reagents

Department of Chemistry, Faculty of Science, University of Kufa, P.O. Box 21, An-Najaf 54001, Iraq
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Abstract

Organclays (OBNTs) were prepared using two new organic surfactants including 3-(4-aminophenyl)-1-(4-chlorophenyl)prop-2-en-1-on (CH) synthesized from a ClaisenɃSchmidt condensation reaction between p-aminoacetophenone and p-chlorobenzaldehyde; and 4-((4-nitrophenyl)diazenyl)-N-(pyrimidin-2-yl) (AZ) prepared from reaction of sulfadiazine and p-nitoaniline. Organclays OBNTs were characterized by Fourier transform infrared spectroscopy (FTIR) to evaluate the incorporation of surfactants in bentonite. The X-ray diffraction (XRD) technique was utilized to indicate the basal spacing of the treated clay as a measure of susceptibility of new organoclays. The FTIR and XRD results showed that the OBNTs were successfully incorporated in the layers of bentonite clay. Thermogravimetric analysis (TGA) was also used to determine thermal stability. An enhancement in stability was observed in OBNTs compare to pure bentonite. OBNTs prepared in this study can be used to produce disposable packaging a promising polymer nanocomposite.

Keywords

Sodium bentoniteModificationSurfactantsOrganic cations

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Nano Biomedicine and Engineering
Volume 9 Issue 2,
June 2017
Pages 124-128
DOI: 10.5101/nbe.v9i2.p124-128
Cite this article:
Al-Mosawy MGA-A, Al-Mulla EAJ, Mohamad MJ. Bentonite-Based Nano Organic Clay Using Chalcone and Azo Dye as Organophilic Reagents. Nano Biomedicine and Engineering, 2017, 9(2): 124-128. https://doi.org/10.5101/nbe.v9i2.p124-128

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Received: 25 April 2017
Accepted: 26 May 2017
Published: 05 June 2017
© 2017 Manar Ghyath Abd-Almutalib Al-Mosawy, Emad Abbas Jaffar Al-Mulla, and Majed Jari Mohamad.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
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