AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
{{expandStatus?'Exit ':''}}Advanced Search
The incorporation of small guest molecules or ions by bottom-up hydrothermal synthesis has recently emerged as a promising new way to engineer 1T-phase MoS2 with high hydrogen evolution reaction (HER) activity. However, the mechanism of the associated structural evolution remains elusive and controversial, leading to a lack of effective routes to prepare 1T-phase MoS2 with controlled structure and morphology, along with high purity and stability. Herein, urea is chosen as precursor of small molecules or ions to simultaneously engineer the phase (~16.4%, ~69.4%, and ~90.2% of 1T phase) and size (~98.8, ~151.6, and ~251.8 nm for the 90.2% 1T phase) of MoS2 nanosheets, which represent an ideal model system for investigating the structural evolution in these materials, as well as developing a new type of 1T-phase MoS2 arrays. Using reaction intermediate monitoring and theoretical calculations, we show that the oriented growth of 1T-phase MoS2 is controlled by ammonia-assisted assembly, recrystallization, and stabilization processes. A superior HER performance in acidic media is obtained, with an overpotential of only 76 mV required to achieve a stable current density of 10 mA·cm–2 for 15 h. This excellent performance is attributed to the unique array structure, involving well-dispersed, edge-terminated, and high-purity 1T-phase MoS2 nanosheets.
Wang, Q. H.; Kalantar-Zadeh, K.; Kis, A.; Coleman, J. N.; Strano, M. S. Electronics and optoelectronics of two-dimensional transition metal dichalcogenides. Nat. Nano 2012, 7, 699–712.
Jariwala, D.; Sangwan, V. K.; Lauhon, L. J.; Marks, T. J.; Hersam, M. C. Emerging device applications for semiconducting two-dimensional transition metal dichalcogenides. ACS Nano 2014, 8, 1102–1120.
Lu, Q. P.; Yu, Y. F.; Ma, Q. L.; Chen, B.; Zhang, H. 2D transition-metal-dichalcogenide-nanosheet-based composites for photocatalytic and electrocatalytic hydrogen evolution reactions. Adv. Mater. 2016, 28, 1917–1933.
Liu, D. B.; Xu, W. Y.; Liu, Q.; He, Q.; Haleem, Y. A.; Wang, C. D.; Xiang, T.; Zou, C. W.; Chu, W. S.; Zhong, J. et al. Unsaturated-sulfur-rich MoS2 nanosheets decorated on free-standing SWNT film: Synthesis, characterization and electrocatalytic application. Nano Res. 2016, 9, 2079–2087.
Jaramillo, T. F.; Jørgensen, K. P.; Bonde, J.; Nielsen, J. H.; Horch, S.; Chorkendorff, I. Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts. Science 2007, 317, 100–102.
Ding, Q.; Song, B.; Xu, P.; Jin, S. Efficient electrocatalytic and photoelectrochemical hydrogen generation using MoS2 and related compounds. Chem 2016, 1, 699–726.
Chhowalla, M.; Shin, H. S.; Eda, G.; Li, L. J.; Loh, K. P.; Zhang, H. The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. Nat. Chem. 2013, 5, 263–275.
Kong, D. S.; Wang, H. T.; Cha, J. J.; Pasta, M.; Koski, K. J.; Yao, J.; Cui, Y. Synthesis of MoS2 and MoSe2 films with vertically aligned layers. Nano Lett. 2013, 13, 1341–1347.
Tan, Y. W.; Liu, P.; Chen, L. Y.; Cong, W. T.; Ito, Y.; Han, J. H.; Guo, X. W.; Tang, Z.; Fujita, T.; Hirata, A. et al. Monolayer MoS2 films supported by 3D nanoporous metals for high-efficiency electrocatalytic hydrogen production. Adv. Mater. 2014, 26, 8023–8028.
Kibsgaard, J.; Chen, Z. B.; Reinecke, B. N.; Jaramillo, T. F. Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis. Nat. Mater. 2012, 11, 963–969.
Yang, L.; Hong, H.; Fu, Q.; Huang, Y. F.; Zhang, J. Y.; Cui, X. D.; Fan, Z. Y.; Liu, K. H.; Xiang, B. Single-crystal atomic-layered molybdenum disulfide nanobelts with high surface activity. ACS Nano 2015, 9, 6478–6483.
Xie, J. F.; Zhang, H.; Li, S.; Wang, R. X.; Sun, X.; Zhou, M.; Zhou, J. F.; Lou, X. W.; Xie, Y. Defect-rich MoS2 ultrathin nanosheets with additional active edge sites for enhanced electrocatalytic hydrogen evolution. Adv. Mater. 2013, 25, 5807–5813.
Yu, Z. H.; Pan, Y. M.; Shen, Y. T.; Wang, Z. L.; Ong, Z. Y.; Xu, T.; Xin, R.; Pan, L. J.; Wang, B. G.; Sun, L. T. et al. Towards intrinsic charge transport in monolayer molybdenum disulfide by defect and interface engineering. Nat. Commun. 2014, 5, 5290.
Hong, J. H.; Hu, Z. X.; Probert, M.; Li, K.; Lv, D. H.; Yang, X. N.; Gu, L.; Mao, N. N.; Feng, Q. L.; Xie, L. M. et al. Exploring atomic defects in molybdenum disulphide monolayers. Nat. Commun. 2015, 6, 6293.
Li, H.; Tsai, C.; Koh, A. L.; Cai, L. L.; Contryman, A. W.; Fragapane, A. H.; Zhao, J. H.; Han, H. S.; Manoharan, H. C.; Abild-Pedersen, F. et al. Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies. Nat. Mater. 2016, 15, 48–53.
Wang, H. T.; Tsai, C.; Kong, D. S.; Chan, H. R.; Abild-Pedersen, F.; Nørskov, J. K.; Cui, Y. Transition-metal doped edge sites in vertically aligned MoS2 catalysts for enhanced hydrogen evolution. Nano Res. 2015, 8, 566–575.
Voiry, D.; Yamaguchi, H.; Li, J. W.; Silva, R.; Alves, D. C. B.; Fujita, T.; Chen, M. W.; Asefa, T.; Shenoy, V. B.; Eda, G. et al. Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution. Nat. Mater. 2013, 12, 850–855.
Yin, Y.; Han, J. C.; Zhang, Y. M.; Zhang, X. H.; Xu, P.; Yuan, Q.; Samad, L.; Wang, X. J.; Wang, Y.; Zhang, Z. H. et al. Contributions of phase, sulfur vacancies, and edges to the hydrogen evolution reaction catalytic activity of porous molybdenum disulfide nanosheets. J. Am. Chem. Soc. 2016, 138, 7965–7972.
Voiry, D.; Salehi, M.; Silva, R.; Fujita, T.; Chen, M. W.; Asefa, T.; Shenoy, V. B.; Eda, G.; Chhowalla, M. Conducting MoS2 nanosheets as catalysts for hydrogen evolution reaction. Nano Lett. 2013, 13, 6222–6227.
Geng, X. M.; Jiao, Y. C.; Han, Y.; Mukhopadhyay, A.; Yang, L.; Zhu, H. L. Freestanding metallic 1T MoS2 with dual ion diffusion paths as high rate anode for sodium-ion batteries. Adv. Funct. Mater. 2017, 27, 1702998.
Acerce, M.; Voiry, D.; Chhowalla, M. Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials. Nat. Nanotechnol. 2015, 10, 313–318.
Lin, Y. C.; Dumcenco, D. O.; Huang, Y. S.; Suenaga, K. Atomic mechanism of the semiconducting-to-metallic phase transition in single-layered MoS2. Nat. Nanotechnol. 2014, 9, 391–396.
Kang, Y. M.; Najmaei, S.; Liu, Z.; Bao, Y. J.; Wang, Y. M.; Zhu, X.; Halas, N. J.; Nordlander, P.; Ajayan, P. M.; Lou, J. et al. Plasmonic hot electron induced structural phase transition in a MoS2 monolayer. Adv. Mater. 2014, 26, 6467–6471.
Shi, Y.; Wang, J.; Wang, C.; Zhai, T. T.; Bao, W. J.; Xu, J. J.; Xia, X. H.; Chen, H. Y. Hot electron of Au nanorods activates the electrocatalysis of hydrogen evolution on MoS2 nanosheets. J. Am. Chem. Soc. 2015, 137, 7365–7370.
Sandoval, S. J.; Yang, D.; Frindt, R. F.; Irwin, J. C. Raman study and lattice dynamics of single molecular layers of MoS2. Phys. Rev. B 1991, 44, 3955–3962.
Wang, L. L.; Liu, X.; Luo, J. M.; Duan, X. D.; Crittenden, J.; Liu, C. B.; Zhang, S. Q.; Pei, Y.; Zeng, Y. X.; Duan, X. F. Self-optimization of the active site of molybdenum disulfide by an irreversible phase transition during photocatalytic hydrogen evolution. Angew. Chem., Int. Ed. 2017, 56, 7610–7614.
Geng, X. M.; Sun, W. W.; Wu, W.; Chen, B.; Al-Hilo, A.; Benamara, M.; Zhu, H. L.; Watanabe, F.; Cui, J. B.; Chen, T. P. Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction. Nat. Commun. 2016, 7, 10672.
Liu, Q.; Li, X. L.; Xiao, Z. R.; Zhou, Y.; Chen, H. P.; Khalil, A.; Xiang, T.; Xu, J. Q.; Chu, W. S.; Wu, X. J. et al. Stable metallic 1T-WS2 nanoribbons intercalated with ammonia ions: The correlation between structure and electrical/optical properties. Adv. Mater. 2015, 27, 4837–4844.
Wang, D. Z.; Zhang, X. Y.; Bao, S. Y.; Zhang, Z. T.; Fei, H.; Wu, Z. Z. Phase engineering of a multiphasic 1T/2H MoS2 catalyst for highly efficient hydrogen evolution. J. Mater. Chem. A 2017, 5, 2681–2688.
Liu, Q.; Li, X. L.; He, Q.; Khalil, A.; Liu, D. B.; Xiang, T.; Wu, X. J.; Song, L. Gram-scale aqueous synthesis of stable few-layered 1T-MoS2: Applications for visible-light-driven photocatalytic hydrogen evolution. Small 2015, 11, 5556–5564.
Calandra, M. Chemically exfoliated single-layer MoS2: Stability, lattice dynamics, and catalytic adsorption from first principles. Phys. Rev. B 2013, 88, 245428.
Güller, F.; Llois, A. M.; Goniakowski, J.; Noguera, C. Prediction of structural and metal-to-semiconductor phase transitions in nanoscale MoS2, WS2, and other transition metal dichalcogenide zigzag ribbons. Phys. Rev. B 2015, 91, 075407.
Wang, J.; Zhong, H. X.; Wang, Z. L.; Meng, F. L.; Zhang, X. B. Integrated three-dimensional carbon paper/carbon tubes/cobalt-sulfide sheets as an efficient electrode for overall water splitting. ACS Nano 2016, 10, 2342–2348.
Li, D. Q.; Liao Q. Y.; Ren, B. W.; Jin, Q. Y.; Cui, H.; Wang, C. X. A 3D-composite structure of FeP nanorods supported by vertically aligned graphene for the high-performance hydrogen evolution reaction. J. Mater. Chem. A 2017, 5, 11301–11308.
Tang, C.; Zhang, R.; Lu, W. B.; He, L. B.; Jiang, X. E.; Asiri, A. M.; Sun, X. P. Fe-Doped CoP Nanoarray: A monolithic multifunctional catalyst for highly efficient hydrogen generation. Adv. Mater. 2017, 29, 1602441.
Fan, X. B.; Xu, P. T.; Zhou, D. K.; Sun, Y. F.; Li, Y. C.; Nguyen, M. A. T.; Terrones, M.; Mallouk, T. E. Fast and efficient preparation of exfoliated 2H MoS2 nanosheets by sonication-assisted lithium intercalation and infrared laser-induced 1T to 2H phase reversion. Nano. Lett. 2015, 15, 5956–5960.
Cheng, P. F.; Sun. K.; Hu, Y. H. Memristive behavior and ideal memristor of 1T phase MoS2 nanosheets. Nano Lett. 2016, 16, 572–576.
Kappera, R.; Voiry, D.; Yalcin, S. E.; Branch, B.; Gupta, G.; Mohite, A. D.; Chhowalla, M. Phase-engineered low-resistance contacts for ultrathin MoS2 transistors. Nat. Mater. 2014, 13, 1128–1134.
Chou, S. S.; Huang, Y. K.; Kim, J.; Kaehr, B.; Foley, B. M.; Lu, P.; Dykstra, C.; Hopkins, P. E.; Brinker, C. J.; Huang, J. X. et al. Controlling the metal to semiconductor transition of MoS2 and WS2 in solution. J. Am. Chem. Soc. 2015, 137, 1742–1745.
Maitra, U.; Gupta, U.; De, M.; Datta, R.; Govindaraj, A.; Rao, C. N. R. Highly effective visible-light-induced H2 generation by single-layer 1T-MoS2 and a nanocomposite of few-layer 2H-MoS2 with heavily nitrogenated graphene. Angew. Chem., Int. Ed. 2013, 52, 13057–13061.
Ma, L.; Zhou, X. P.; Xu, L. M.; Xu, X. Y.; Zhang, L. L.; Chen, W. X. Chitosan-assisted fabrication of ultrathin MoS2/graphene heterostructures for Li-ion battery with excellent electrochemical performance. Electrochim. Acta 2015, 167, 39–47.
Hu, S.; Wang, X. Single-walled MoO3 nanotubes. J. Am. Chem. Soc. 2008, 130, 8126–8127.
Wang, P. P.; Sun, H. Y.; Ji, Y. J.; Li, W. H.; Wang, X. Three-dimensional assembly of single-layered MoS2. Adv. Mater. 2014, 26, 964–969.
Enyashin, A. N.; Yadgarov, L.; Houben, L.; Popov, I.; Weidenbach, M.; Tenne, R.; Bar-Sadan, M.; Seifert, G. New route for stabilization of 1T-WS2 and MoS2 phases. J. Phys. Chem. C 2011, 115, 24586–24591.
Cai, L.; He, J. F.; Liu, Q. H.; Yao, T.; Chen, L.; Yan, W. S.; Hu, F. C.; Jiang, Y.; Zhao, Y. D.; Hu, T. D. et al. Vacancy-induced ferromagnetism of MoS2 nanosheets. J. Am. Chem. Soc. 2015, 137, 2622–2627.
Hu, S.; Wang. X. Fullerene-like colloidal nanocrystal of nickel hydroxychloride. J. Am. Chem. Soc. 2010, 132, 9573–9575.
Tang, M. L.; Grauer, D. C.; Lassalle-Kaiser, B.; Yachandra, V. K.; Amirav, L.; Long, J. R.; Yano, J.; Alivisatos, A. P. Structural and electronic study of an amorphous MoS3 hydrogen-generation catalyst on a quantum-controlled photosensitizer. Angew. Chem., Int. Ed. 2011, 123, 10385–10389.
Vrubel, H.; Merki, D.; Hu, X. L. Hydrogen evolution catalyzed by MoS3 and MoS2 particles. Energy Environ. Sci. 2012, 5, 6136–6144.
Li, D. J.; Maiti, U. N.; Lim, J.; Choi, D. S.; Lee, W. J.; Oh, Y.; Lee, G. Y.; Kim, S. O. Molybdenum sulfide/N-doped CNT forest hybrid catalysts for high performance hydrogen evolution reaction. Nano Lett. 2014, 14, 1228–1233.
Wang, H.; Lu, Z.; Xu, S.; Kong, D.; Cha, J. J.; Zheng, G.; Hsu, P.; Yan, K.; Bradshaw, D.; Prinz, F. B. et al. Electrochemical tuning of vertically aligned MoS2 nanofilms and its application in improving hydrogen evolution reaction. Proc. Natl. Acad. Sci. USA 2013, 110, 19701–19706.
Tan, S. J. R.; Abdelwahab, I.; Ding, Z. J.; Zhao, X. X.; Yang, T. S.; Loke, G. Z. J.; Lin, H.; Verzhbitskiy, I.; Sock Mui Poh, S. M.; Xu, H. et al. Chemical stabilization of 1T' phase transition metal dichalcogenides with giant optical Kerr nonlinearity. J. Am. Chem. Soc. 2017, 139, 2504–2511.
Cook J. B.; Kim H. S.; Yan Y.; Ko J. S.; Robbennolt S.; Dunn B.; Tolbert S. H. Mesoporous MoS2 as a transition metal dichalcogenide exhibiting pseudocapacitive Li and Na-ion charge storage. Adv. Energy Mater. 2016, 6, 1501937.
Liu, K. K.; Zhang, W. J.; Lee, Y. H.; Lin, Y. C.; Chang, M. T.; Su, C. Y.; Chang, C. S.; Li, H.; Shi, Y. M.; Zhang, H. et al. Growth of large-area and highly crystalline MoS2 thin layers on insulating substrates. Nano Lett. 2012, 12, 1538–1544.
Koroteev, V. O.; Bulusheva, L. G.; Okotrub, A. V.; Yudanov, N. F.; Vyalikh, D. V. Formation of MoS2 nanoparticles on the surface of reduced graphite oxide. Phys. Stat. Solid. B 2011, 248, 2740–2743.
Liao, L.; Zhu, J.; Bian, X. J.; Zhu, L. N.; Scanlon, M. D.; Girault, H. H.; Liu, B. H. MoS2 formed on mesoporous graphene as a highly active catalyst for hydrogen evolution. Adv. Funct. Mater. 2013, 23, 5326–5333.
Lukowski, M. A.; Daniel, A. S.; Meng, F.; Forticaux, A.; Li, L. S.; Jin, S. Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS2 nanosheets. J. Am. Chem. Soc. 2013, 135, 10274–10277.
Skúlason, E.; Karlberg, G. S.; Rossmeisl, J.; Bligaard, T.; Greeley, J.; Jónsson, H.; Nørskov, J. K. Density functional theory calculations for the hydrogen evolution reaction in an electrochemical double layer on the Pt(111) electrode. Phys. Chem. Chem. Phys. 2007, 9, 3241–3250.
Hinnemann, B.; Moses, P. G.; Bonde, J.; Jørgensen, K. P.; Nielsen, J. H.; Horch, S.; Chorkendorff, I.; Nørskov, J. K. Biomimetic hydrogen evolution: MoS2 nanoparticles as catalyst for hydrogen evolution. J. Am. Chem. Soc. 2005, 127, 5308–5309.
Greeley, J.; Nørskov, J. K. Large-scale, density functional theory-based screening of alloys for hydrogen evolution. Surf. Sci. 2007, 601, 1590–1598.
Fan, X. L.; Yang, Y.; Xiao, P.; Lau, W. M. Site-specific catalytic activity in exfoliated MoS2 single-layer polytypes for hydrogen evolution: Basal plane and edges. J. Mater. Chem. A 2014, 2, 20545–20551.
京公网安备11010802044758号