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Research Article

Encapsulating segment-like antimony nanorod in hollow carbon tube as long-lifespan, high-rate anodes for rechargeable K-ion batteries

Wen Luo1,§, Feng Li2,§, Weiran Zhang3, Kang Han4, Jean-Jacques Gaumet5, Hans-Eckhardt Schaefer4,6, Liqiang Mai4( )
Department of Physics,School of Science, Wuhan University of Technology,Wuhan,430070,China;
Hefei National Laboratory for Physical Sciences at the Microscale,University of Science and Technology of China,Hefei,230000,China;
Division of Materials Science and Engineering,Boston University,MA,02215,USA;
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,International School of Materials Science and Technology, Wuhan University of Technology,Wuhan,430070,China;
Laboratoire de Chimie et Physique: Approche Multi-échelles des Milieux Complexes,Institut Jean Barriol, Université de Lorraine,Metz,57070,France;
Institute for Functional Matter and Quantum Technologies,Stuttgart University, Pfaffenwaldring 57,Stuttgart,70569,Germany;

§ Wen Luo and Feng Li contributed equally to this work.

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Graphical Abstract

Abstract

K-ion battery (KIB) is a new-type energy storage device that possesses potential advantages of low-cost and abundant resource of potassium. To develop advanced electrode materials for accommodating the large size and high activity of potassium ion is of great interests. Herein, a segment-like antimony (Sb) nanorod encapsulated in hollow carbon tube electrode material (Sb@HCT) was prepared. Beneficial from the virtue of abundant nitrogen doping in carbon tube, one-dimensional and hollow structure advantages, Sb@HCT exhibits excellent potassium storage properties: in the case of potassium bis(fluorosulfonyl)imide (KFSI) electrolyte, Sb@HCT displays a reversible capacity of up to 453.4 mAh·g-1 at a current density of 0.5 A·g-1 and good rate performance (a capacity of 211.5 mAh·g-1 could be achieved at an ultrahigh rate of 5 A·g-1). Additionally, Sb@HCT demonstrates excellent long-cycle stability at a current density of 2 A·g-1 over 120 cycles. Meanwhile, electrolyte optimization is an effective strategy for greatly improving electrochemical performance. Through ex-situ characterizations, we disclosed the potassiation of Sb anode is quite reversible and undergoes multistep processes, combining solid solution reaction and two-phase reaction.

Keywords

K-ion batteryantimony anodehollow carbon tube encapsulationelectrolyte optimizationpotassium storage mechanism

Electronic Supplementary Material

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Nano Research
Volume 12 Issue 5,
May 2019
Pages 1025-1031
DOI: 10.1007/s12274-019-2335-6
Cite this article:
Luo W, Li F, Zhang W, et al. Encapsulating segment-like antimony nanorod in hollow carbon tube as long-lifespan, high-rate anodes for rechargeable K-ion batteries. Nano Research, 2019, 12(5): 1025-1031. https://doi.org/10.1007/s12274-019-2335-6
Topics:
AntimonyAntimony compoundsCarbonElectrolytesIonsNanorodsPotassiumSecondary batteriesStorage (materials)

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Received: 12 December 2018
Revised: 24 January 2019
Accepted: 10 February 2019
Published: 23 March 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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