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Research Article

2D nanoplate assembled nitrogen doped hollow carbon sphere decorated with Fe3O4 as an efficient electrocatalyst for oxygen reduction reaction and Zn-air batteries

Yanqiang Li1,§( ), Huiyong Huang1,§, Siru Chen3( ), Xin Yu1, Chao Wang1, Tingli Ma2( )
State Key Laboratory of Fine ChemicalsSchool of Petroleum and Chemical EngineeringDalian University of TechnologyPanjin CampusPanjin124221China
Graduate School of Life Science and Systems EngineeringKyushu Institute of Technology, 2-4 Hibikino, Wakamatsu, Kitakyushu, Fukuoka, 808-0196Japan
Center for Advanced Materials ResearchZhongyuan University of TechnologyZhengzhou450007China

§ Yanqiang Li and Huiyong Huang contributed equally to this work.

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Graphical Abstract

Abstract

Designing a highly efficient non-precious based oxygen reduction reaction (ORR) electrocatalyst is critical for the commercialization of various sustainable energy storage and conversion devices such as metal-air batteries and fuel cells. Herein, we report a convenient strategy to synthesis Fe3O4 embedded in N doped hollow carbon sphere (NHCS) for ORR. What's interesting is that the carbon microsphere is composed of two-dimensional (2D) nanoplate that could provide more exposed active sites. The usage of solid ZnO nanowires as zinc source is crucial to obtain this structure. The Fe3O4@NHCS-2 exhibits better catalytic activity and durability than the commercial Pt/C catalyst. Moreover, it further displays high-performance of Zn-air batteries as a cathode electrocatalyst with a high-power density of 133 mW·cm-2 and high specific capacity of 701 mA·h·g-1. The special hollow structure composed 2D nanoplate, high surface area, as well as synergistic effect between the high active Fe3O4 nanoparticles and N-doped matrix endows this outstanding catalytic activity. The work presented here can be easily extended to prepare metal compounds decorated carbon nanomaterials with special structure for a broad range of energy storage and conversion devices.

Keywords

oxygen reduction reactionZn-air batteryFe3O4 N dopinghollow microsphere

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References

1

Debe, M. K. Electrocatalyst approaches and challenges for automotive fuel cells. Nature 2012, 486, 43-51.
Crossref Google Scholar
2

Wang, T. T.; Wu, J. H.; Liu, Y. L.; Cui, X.; Ding, P.; Deng, J.; Zha, C. Y.; Coy, E.; Li, Y. G. Scalable preparation and stabilization of atomic-thick CoNi layered double hydroxide nanosheets for bifunctional oxygen electrocatalysis and rechargeable zinc-air batteries. Energy Storage Mater. 2019, 16, 24-30.
Crossref Google Scholar
3

Fu, S. F.; Zhu, C. Z.; Song, J. H.; Du, D.; Lin, Y. H. Metal-organic framework-derived non-precious metal nanocatalysts for oxygen reduction reaction. Adv. Energy Mater. 2017, 7, 1700363.
Crossref Google Scholar
4

Wang, D. L.; Xin, H. L.; Hovden, R.; Wang, H. S.; Yu, Y. C.; Muller, D. A.; DiSalvo, F. J.; Abruña, H. D. Structurally ordered intermetallic platinum-cobalt core-shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts. Nat. Mater. 2013, 12, 81-87.
Crossref Google Scholar
5

Wang, N.; Li, L. G.; Zhao, D. K.; Kang, X. W.; Tang, Z. H.; Chen, S. W. Graphene composites with cobalt sulfide: Efficient trifunctional electrocatalysts for oxygen reversible catalysis and hydrogen production in the same electrolyte. Small 2017, 13, 1701025.
Crossref Google Scholar
6

Dai, L. M.; Xue, Y. H.; Qu, L. T.; Choi, H. J.; Baek, J. B. Metal-free catalysts for oxygen reduction reaction. Chem. Rev. 2015, 115, 4823-4892.
Crossref Google Scholar
7

Tian, H.; Wang, N.; Xu, F. G.; Zhang, P. F.; Hou, D.; Mai, Y. Y.; Feng, X. L. Nitrogen-doped carbon nanosheets and nanoflowers with holey mesopores for efficient oxygen reduction catalysis. J. Mater. Chem. A 2018, 6, 10354-10360.
Crossref Google Scholar
8

Amiinu, I. S.; Liu, X. B.; Pu, Z. H.; Li, W. Q.; Li, Q. D.; Zhang, J.; Tang, H. L.; Zhang, H. N.; Mu, S. C. From 3D ZIF nanocrystals to Co-Nx/C nanorod array electrocatalysts for ORR, OER, and Zn-air batteries. Adv. Funct. Mater. 2018, 28, 1704638.
Crossref Google Scholar
9

Wang, R.; Dong, X. Y.; Du, J.; Zhao, J. Y.; Zang, S. Q. MOF-derived bifunctional Cu3P nanoparticles coated by a N, P-codoped carbon shell for hydrogen evolution and oxygen reduction. Adv. Mater. 2018, 30, 1703711.
Crossref Google Scholar
10

Tang, F.; Lei, H. T.; Wang, S. J.; Wang, H. X.; Jin, Z. X. A novel Fe-N-C catalyst for efficient oxygen reduction reaction based on polydopamine nanotubes. Nanoscale 2017, 9, 17364-17370.
Crossref Google Scholar
11

Hu, Y.; Jensen, J. O.; Zhang, W.; Cleemann, L. N.; Xing, W.; Bjerrum, N. J.; Li, Q. F. Hollow spheres of iron carbide nanoparticles encased in graphitic layers as oxygen reduction catalysts. Angew. Chem., Int. Ed. 2014, 53, 3675-3679.
Crossref Google Scholar
12

Xia, W.; Mahmood, A.; Liang, Z. B.; Zou, R. Q.; Guo, S. J. Earth-abundant nanomaterials for oxygen reduction. Angew. Chem., Int. Ed. 2016, 55, 2650-2676.
Crossref Google Scholar
13

Qiao, Y. Y.; Yuan, P. F.; Hu, Y. F.; Zhang, J. N.; Mu, S. C.; Zhou, J. H.; Li, H.; Xia, H. C.; He, J.; Xu, Q. Sulfuration of an Fe-N-C catalyst containing FexC/Fe species to enhance the catalysis of oxygen reduction in acidic media and for use in flexible Zn-air batteries. Adv. Mater. 2018, 30, 1804504.
Crossref Google Scholar
14

Guo, Y. Y.; Yuan, P. F.; Zhang, J. N.; Hu, Y. F.; Amiinu, I. S.; Wang, X.; Zhou, J. G.; Xia, H. C.; Song, Z. B.; Xu, Q. et al. Carbon nanosheets containing discrete Co-Nx-By-C active sites for efficient oxygen electrocatalysis and rechargeable Zn-air batteries. ACS Nano 2018, 12, 1894-1901.
Crossref Google Scholar
15

Han, C.; Li, Q.; Wang, D. W.; Lu, Q. Q.; Xing, Z. C.; Yang, X. R. Cobalt sulfide nanowires core encapsulated by a N, S codoped graphitic carbon shell for efficient oxygen reduction reaction. Small 2018, 14, 1703642.
Crossref Google Scholar
16

Luo, H.; Jiang, W. J.; Zhang, Y.; Niu, S.; Tang, T.; Huang, L. B.; Chen, Y. Y.; Wei, Z. D.; Hu, J. S. Self-terminated activation for high-yield production of N, P-codoped nanoporous carbon as an efficient metal-free electrocatalyst for Zn-air battery. Carbon 2018, 128, 97-105.
Crossref Google Scholar
17

Chai, G. L.; Qiu, K.; Qiao, M.; Titirici, M. M.; Shang, C. X.; Guo, Z. X. Active sites engineering leads to exceptional ORR and OER bifunctionality in P, N co-doped graphene frameworks. Energy Environ. Sci. 2017, 10, 1186-1195.
Crossref Google Scholar
18

Chen, P. Z.; Zhou, T. P.; Xing, L. L.; Xu, K.; Tong, Y.; Xie, H.; Zhang, L. D.; Yan, W. S.; Chu, W. S.; Wu, C. Z. et al. Atomically dispersed iron-nitrogen species as electrocatalysts for bifunctional oxygen evolution and reduction reactions. Angew. Chem., Int. Ed. 2017, 56, 610-614.
Crossref Google Scholar
19

Borghei, M.; Laocharoen, N.; Kibena-Põldsepp, E.; Johansson, L. S.; Campbell, J.; Kauppinen, E.; Tammeveski, K.; Rojas, O. J. Porous N, P-doped carbon from coconut shells with high electrocatalytic activity for oxygen reduction: Alternative to Pt-C for alkaline fuel cells. Appl. Catal. B: Environ. 2017, 204, 394-402.
Crossref Google Scholar
20

Zheng, X. J.; Wu, J.; Cao, X. C.; Abbott, J.; Jin, C.; Wang, H. B.; Strasser, P.; Yang, R. Z.; Chen, X.; Wu, G. N-, P-, and S-doped graphene-like carbon catalysts derived from onium salts with enhanced oxygen chemisorption for Zn-air battery cathodes. Appl. Catal. B: Environ. 2019, 241, 442-451.
Crossref Google Scholar
21

Li, Y. Q.; Xu, H. B.; Huang, H. Y.; Gao, L. G.; Zhao, Y. Y.; Ma, T. L. Facile synthesis of N, S co-doped porous carbons from a dual-ligand metal organic framework for high performance oxygen reduction reaction catalysts. Electrochim. Acta 2017, 254, 148-154.
Crossref Google Scholar
22

Niu, W. H.; Li, L. G.; Liu, X. J.; Wang, N.; Liu, J.; Zhou, W. J.; Tang, Z. H.; Chen, S. W. Mesoporous N-doped carbons prepared with thermally removable nanoparticle templates: An efficient electrocatalyst for oxygen reduction reaction. J. Am. Chem. Soc. 2015, 137, 5555-5562.
Crossref Google Scholar
23

Hua, Y. Q.; Jiang, T. T.; Wang, K.; Wu, M. M.; Song, S. Q.; Wang, Y.; Tsiakaras, P. Efficient Pt-free electrocatalyst for oxygen reduction reaction: Highly ordered mesoporous N and S co-doped carbon with saccharin as single-source molecular precursor. Appl. Catal. B: Environ. 2016, 194, 202-208.
Crossref Google Scholar
24

Wang, H. T.; Wang, W.; Xu, Y. Y.; Dong, S.; Xiao, J. W.; Wang, F.; Liu, H. F.; Xia, B. Y. Hollow nitrogen-doped carbon spheres with Fe3O4 nanoparticles encapsulated as a highly active oxygen-reduction catalyst. ACS Appl. Mater. Interfaces 2017, 9, 10610-10617.
Crossref Google Scholar
25

Wang, Y.; Liu, H. Y.; Wang, K.; Song, S. Q.; Tsiakaras, P. 3D interconnected hierarchically porous N-doped carbon with NH3 activation for efficient oxygen reduction reaction. Appl. Catal. B: Environ. 2017, 210, 57-66.
Crossref Google Scholar
26

Park, J.; Kwon, T.; Kim, J.; Jin, H.; Kim, H. Y.; Kim, B.; Joo, S. H.; Lee, K. Hollow nanoparticles as emerging electrocatalysts for renewable energy conversion reactions. Chem. Soc. Rev. 2018, 47, 8173-8202.
Crossref Google Scholar
27

Pei, Y. C.; Qi, Z. Y.; Li, X. L.; Maligal-Ganesh, R. V.; Goh, T. W.; Xiao, C. X.; Wang, T. Y.; Huang, W. Y. Morphology inherence from hollow MOFs to hollow carbon polyhedrons in preparing carbon-based electrocatalysts. J. Mater. Chem. A 2017, 5, 6186-6192.
Crossref Google Scholar
28

Liang, H. W.; Wei, W.; Wu, Z. S.; Feng, X. L.; Müllen, K. Mesoporous metal-nitrogen-doped carbon electrocatalysts for highly efficient oxygen reduction reaction. J. Am. Chem. Soc. 2013, 135, 16002-16005.
Crossref Google Scholar
29

Gao, S. Y.; Fan, B. F.; Feng, R.; Ye, C. L.; Wei, X. J.; Liu, J.; Bu, X. H. N-doped-carbon-coated Fe3O4 from metal-organic framework as efficient electrocatalyst for ORR. Nano Energy 2017, 40, 462-470.
Crossref Google Scholar
30

Singh, D. K.; Jenjeti, R. N.; Sampath, S.; Eswaramoorthy, M. Two in one: N-doped tubular carbon nanostructure as an efficient metal-free dual electrocatalyst for hydrogen evolution and oxygen reduction reactions. J. Mater. Chem. A 2017, 5, 6025-6031.
Crossref Google Scholar
31

Li, X. C.; Zhang, L.; He, G. H. Fe3O4 doped double-shelled hollow carbon spheres with hierarchical pore network for durable high-performance supercapacitor. Carbon 2016, 99, 514-522.
Crossref Google Scholar
32

Huang, J.; Cheng, S. P.; Chen, Y. X.; Chen, Z. L.; Luo, H.; Xia, X. H.; Liu, H. B. High-rate capability and long-term cycling of self-assembled hierarchical Fe3O4/carbon hollow spheres through interfacial control. J. Mater. Chem. A 2019, 7, 16720-16727.
Crossref Google Scholar
33

Li, Y. Q.; Huang, H. Y.; Chen, S. R.; Wang, C.; Ma, T. L. Nanowire-templated synthesis of FeNx-decorated carbon nanotubes as highly efficient, universal-pH, oxygen reduction reaction catalysts. Chem. —Eur. J. 2019, 25, 2637-2644.
Crossref Google Scholar
34

Pan, J.; Song, S. Y.; Li, J. Q.; Wang, F.; Ge, X.; Yao, S.; Wang, X.; Zhang, H. J. Solid ion transition route to 3D S-N-codoped hollow carbon nanosphere/graphene aerogel as a metal-free handheld nanocatalyst for organic reactions. Nano Res. 2017, 10, 3486-3495.
Crossref Google Scholar
35

Li, Y. Q.; Huang, H. Y.; Chen, S. R.; Wang, C.; Liu, A. M.; Ma, T. L. Killing two birds with one stone: A highly active tubular carbon catalyst with effective N doping for oxygen reduction and hydrogen evolution reactions. Catal. Lett. 2019, 149, 486-495.
Crossref Google Scholar
36

Wang, T. H.; Tan, S. X.; Liang, C. H. Preparation and characterization of activated carbon from wood via microwave-induced ZnCl2 activation. Carbon 2009, 47, 1880-1883.
Crossref Google Scholar
37

He, X. J.; Ling, P. H.; Yu, M. X.; Wang, X. T.; Zhang, X. Y.; Zheng, M. D. Rice husk-derived porous carbons with high capacitance by ZnCl2 activation for supercapacitors. Electrochim. Acta 2013, 105, 635-641.
Crossref Google Scholar
38

Gadipelli, S.; Zhao, T. T.; Shevlin, S. A.; Guo, Z. X. Switching effective oxygen reduction and evolution performance by controlled graphitization of a cobalt-nitrogen-carbon framework system. Energy Environ. Sci. 2016, 9, 1661-1667.
Crossref Google Scholar
39

You, B.; Jiang, N.; Sheng, M. L.; Drisdell, W. S.; Yano, J.; Sun, Y. J. Bimetal-organic framework self-adjusted synthesis of support-free nonprecious electrocatalysts for efficient oxygen reduction. ACS Catal. 2015, 5, 7068-7076.
Crossref Google Scholar
40

Chen, Y. Z.; Wang, C. M.; Wu, Z. Y.; Xiong, Y. J.; Xu, Q.; Yu, S. H.; Jiang, H. L. From bimetallic metal-organic framework to porous carbon: High surface area and multicomponent active dopants for excellent electrocatalysis. Adv. Mater. 2015, 27, 5010-5016.
Crossref Google Scholar
41

Jiang, H. L.; Liu, B.; Lan, Y. Q.; Kuratani, K.; Akita, T.; Shioyama, H.; Zong, F. Q.; Xu, Q. From metal-organic framework to nanoporous carbon: Toward a very high surface area and hydrogen uptake. J. Am. Chem. Soc. 2011, 133, 11854-11857.
Crossref Google Scholar
42

Zhao, S. L.; Yin, H. J.; Du, L.; He, L. C.; Zhao, K.; Chang, L.; Yin, G. P.; Zhao, H. J.; Liu, S. Q.; Tang, Z. Y. Carbonized nanoscale metal-organic frameworks as high performance electrocatalyst for oxygen reduction reaction. ACS Nano 2014, 8, 12660-12668.
Crossref Google Scholar
43

Xia, B. Y.; Yan, Y.; Li, N.; Wu, H. B.; Lou, X. W.; Wang, X. A metal-organic framework-derived bifunctional oxygen electrocatalyst. Nat. Energy 2016, 1, 15006.
Crossref Google Scholar
44

Proietti, E.; Jaouen, F.; Lefèvre, M.; Larouche, N.; Tian, J.; Herranz, J.; Dodelet, J. P. Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells. Nat. Commun. 2011, 2, 416.
Crossref Google Scholar
45

Fu, X. G.; Zamani, P.; Choi, J. Y.; Hassan, F. M.; Jiang, G. P.; Higgins, D. C.; Zhang, Y. N.; Hoque, M. A.; Chen, Z. W. In situ polymer graphenization ingrained with nanoporosity in a nitrogenous electrocatalyst boosting the performance of polymer-electrolyte-membrane fuel cells. Adv. Mater. 2017, 29, 1604456.
Crossref Google Scholar
46

Sharifi, T.; Hu, G. Z.; Jia, X. E.; Wågberg, T. Formation of active sites for oxygen reduction reactions by transformation of nitrogen functionalities in nitrogen-doped carbon nanotubes. ACS Nano 2012, 6, 8904-8912.
Crossref Google Scholar
47

Su, Y. H.; Jiang, H. L.; Zhu, Y. H.; Yang, X. L.; Shen, J. H.; Zou, W. J.; Chen, J. D.; Li, C. Z. Enriched graphitic N-doped carbon-supported Fe3O4 nanoparticles as efficient electrocatalysts for oxygen reduction reaction. J. Mater. Chem. A 2014, 2, 7281-7287.
Crossref Google Scholar
48

Wu, Z. S.; Yang, S. B.; Sun, Y.; Parvez, K.; Feng, X. L.; Müllen, K. 3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction. J. Am. Chem. Soc. 2012, 134, 9082-9085.
Crossref Google Scholar
49

Zhang, J.; Wang, K. X.; Xu, Q.; Zhou, Y. C.; Cheng, F. Y.; Guo, S. J. Beyond yolk-shell nanoparticles: Fe3O4@Fe3C core@shell nanoparticles as yolks and carbon nanospindles as shells for efficient lithium ion storage. ACS Nano 2015, 9, 3369-3376.
Crossref Google Scholar
50

Wei, Q. L.; Yang, X. H.; Zhang, G. X.; Wang, D. N.; Zuin, L.; Banham, D.; Yang, L. J.; Ye, S. Y.; Wang, Y. L.; Mohamedi, M. et al. An active and robust Si-Fe/N/C catalyst derived from waste reed for oxygen reduction. Appl. Catal. B: Environ. 2018, 237, 85-93.
Crossref Google Scholar
51

Xu, P.; Zhang, J.; Jiang, G. P.; Hassan, F.; Choi, J. Y.; Fu, X. G.; Zamani, P.; Yang, L. J.; Banham, D.; Ye, S. Y. et al. Embellished hollow spherical catalyst boosting activity and durability for oxygen reduction reaction. Nano Energy 2018, 51, 745-753.
Crossref Google Scholar
52

Wu, Z. X.; Liu, R.; Wang, J.; Zhu, J.; Xiao, W. P.; Xuan, C. J.; Lei, W.; Wang, D. L. Nitrogen and sulfur Co-doping of 3D hollow-structured carbon spheres as an efficient and stable metal free catalyst for the oxygen reduction reaction. Nanoscale 2016, 8, 19086-19092.
Crossref Google Scholar
Nano Research
Volume 12 Issue 11,
November 2019
Pages 2774-2780
DOI: 10.1007/s12274-019-2512-7
Cite this article:
Li Y, Huang H, Chen S, et al. 2D nanoplate assembled nitrogen doped hollow carbon sphere decorated with Fe3O4 as an efficient electrocatalyst for oxygen reduction reaction and Zn-air batteries. Nano Research, 2019, 12(11): 2774-2780. https://doi.org/10.1007/s12274-019-2512-7
Topics:
CarbonCatalyst activityDoping (additives)ElectrocatalystsElectrolytic reduction Energy storageFuel cellsIIIron oxidesMagnettiteMicrospheresNanostructuresNitrogenOxygenTin oxidesVI semiconductors

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Received: 19 June 2019
Revised: 15 August 2019
Accepted: 02 September 2019
Published: 07 September 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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