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Review Article

Boride-based electrocatalysts: Emerging candidates for water splitting

Zhijie Chen1, Xiaoguang Duan2, Wei Wei1, Shaobin Wang2, Zejie Zhang3, Bing-Jie Ni1( )
Centre for Technology in Water and Wastewater, School of Civil and Environmental Engineering, University of Technology Sydney, NSW 2007, Australia
School of Chemical Engineering and Advanced Materials, The University of Adelaide, South Australia 5005, Australia
State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China
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Abstract

Electrocatalytic water splitting (EWS) is a promising route to produce hydrogen in a sustainable and environment-benign manner. To realize the large-scale hydrogen production, it is paramount to develop desirable electrocatalysts with engineered structure, high catalytic activity, facile accessibility, low cost, and good durability. Of late, boride-based materials, especially transition-metal borides (TMBs), are emerging as promising candidates for the EWS process. However, so far, little attempt has been made to provide a comprehensive summary on these findings. Herein, this review provides the up-to-date status on upgrading the catalytic performance of TMB-based nanomaterials by regulating the internal and external characteristics. The conventional synthetic techniques are first presented for the preparation of TMB-based catalysts. Afterwards, the advanced strategies are summarized to enhance the catalytic performance of TMBs, including morphology control, component regulation, phase engineering, surface oxidation and hybridization. Then, the design principles of TMB-based electrocatalysts for high-performance EWS are outlined. Lastly, the current challenges and future directions in the development of TMB-based materials are proposed. This review article is expected to envisage insights into the TMBs-based water splitting and to provide strategies for design of the next-generation TMB-based electrocatalysts.

Keywords

transition-metal borideselectrocatalystswater splittingoxygen evolution reactionhydrogen evolution reaction

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Nano Research
Volume 13 Issue 2,
February 2020
Pages 293-314
DOI: 10.1007/s12274-020-2618-y
Cite this article:
Chen Z, Duan X, Wei W, et al. Boride-based electrocatalysts: Emerging candidates for water splitting. Nano Research, 2020, 13(2): 293-314. https://doi.org/10.1007/s12274-020-2618-y
Topics:
BoridesCatalyst activityCatalytic oxidation ElectrocatalystsElectrolysis MorphologyTransition metals

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Received: 08 October 2019
Revised: 15 December 2019
Accepted: 19 December 2019
Published: 02 January 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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