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Research Article | Open Access

Edge-enriched MoS2 for kinetics-enhanced potassium storage

Guangshen Jiang1, Xiaosa Xu1, Haojie Han1, Changzhen Qu1, Hlib Repich1, Fei Xu1,2( ), Hongqiang Wang1( )
State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Shaanxi Joint Laboratory of Graphene (NPU), Northwestern Polytechnical University, Xi’an 710072, China
Department of Inorganic Chemistry, Technische Universität Dresden, Bergstrasse 66, 01062 Dresden, Germany
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Graphical Abstract

Abstract

Potassium-ion batteries (PIBs) hold great promise as alternatives to lithium ion batteries in post-lithium age, while face challenges of slow reaction kinetics induced by the inherent characteristics of large-size K+. We herein show that creating sufficient exposed edges in MoS2 via constructing ordered mesoporous architecture greatly favors for improved kinetics as well as increased reactive sites for K storage. The engineered MoS2 with edge-enriched planes (EE-MoS2) is featured by three-dimensional bicontinuous frameworks with ordered mesopores of ~ 5.0 nm surrounded by thin wall of ~ 9.0 nm. Importantly, EE-MoS2 permits exposure of enormous edge planes at pore walls, renders its intrinsic layer spacing more accessible for K+ and accelerates conversion kinetics, thus realizing enhanced capacity and high rate capability. Impressively, EE-MoS2 displays a high reversible charge capacity of 506 mAh·g-1 at 0.05 A·g-1, superior cycling capacities of 321 mAh·g-1 at 1.0 A·g-1 after 200 cycles and a capacity of 250 mAh·g-1 at 2.0 A·g-1, outperforming edge-deficient MoS2 with nonporous bulk structure. This work enlightens the nanoarchitecture design with abundant edges for improving electrochemical properties and provides a paradigm for exploring high-performance PIBs.

Keywords

molybdenum disulfideenriched edgespotassium-ion batterieskinetics

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References

[1]
Wu, X.; Chen, Y. L.; Xing, Z.; Lam, C. W. K.; Pang, S. S.; Zhang, W.; Ju, Z. C. Advanced carbon-based anodes for potassium-ion batteries. Adv. Energy Mater. 2019, 9, 1900343.
Google Scholar
[2]
Wu, Y.; Huang, H. B.; Feng, Y. Z.; Wu, Z. S.; Yu, Y. The promise and challenge of phosphorus-based composites as anode materials for potassium-ion batteries. Adv. Mater. 2019, 31, 1901414.
Google Scholar
[3]
Lei, K. X.; Wang, C. C.; Liu, L. J.; Luo, Y. W.; Mu, C. N.; Li, F. J.; Chen, J. A porous network of bismuth used as the anode material for high-energy-density potassium-ion batteries. Angew. Chem., Int. Ed. 2018, 57, 4687-4691.
Google Scholar
[4]
Yang, W. X.; Zhou, J. H.; Wang, S.; Zhang, W. Y.; Wang, Z. C.; Lv, F.; Wang, K.; Sun, Q.; Guo, S. J. Freestanding film made by necklace-like N-doped hollow carbon with hierarchical pores for high-performance potassium-ion storage. Energy Environ. Sci. 2019, 12, 1605-1612.
Google Scholar
[5]
Qin, L.; Lei, Y.; Wang, H. W.; Dong, J. H.; Wu, Y. Y.; Zhai, D. Y; Kang, F. Y.; Tao, Y.; Yang, Q. H. Capillary encapsulation of metallic potassium in aligned carbon nanotubes for use as stable potassium metal anodes. Adv. Energy Mater. 2019, 9, 1901427.
Google Scholar
[6]
Hu, X.; Liu, Y. J.; Chen, J. X.; Yi, L. C.; Zhan, H. B.; Wen, Z. H. Fast redox kinetics in Bi-heteroatom doped 3D porous carbon nanosheets for high-performance hybrid potassium-ion battery capacitors. Adv. Energy Mater. 2019, 9, 1901533.
Google Scholar
[7]
Zhang, W. C.; Mao, J. F.; Li, S. A.; Chen, Z. X.; Guo, Z. P. Phosphorus- based alloy materials for advanced potassium-ion battery anode. J. Am. Chem. Soc. 2017, 139, 3316-3319.
Google Scholar
[8]
Zhao, S. Q.; Yan, K.; Munroe, P.; Sun, B.; Wang, G. X. Construction of hierarchical K1.39Mn3O6 spheres via AlF3 coating for high- performance potassium-ion batteries. Adv. Energy Mater. 2019, 9, 1803757.
Google Scholar
[9]
Zeng, C.; Xie, F. X.; Yang, X. F.; Jaroniec, M.; Zhang, L.; Qiao, S. Z. Ultrathin titanate nanosheets/graphene films derived from confined transformation for excellent Na/K ion storage. Angew. Chem., Int. Ed. 2018, 57, 8540-8544.
Google Scholar
[10]
Xu, F.; Zhai, Y. X.; Zhang, E.; Liu, Q. H.; Jiang, G. S.; Xu, X. S.; Qiu, Y. Q.; Liu, X. M.; Wang H. Q.; Kaskel, S. Ultrastable surface- dominated pseudocapacitive potassium storage enabled by edge- enriched N-doped porous carbon nanosheets. Angew. Chem., Int. Ed., in press, .
Crossref Google Scholar
[11]
Wang, N. N.; Chu, C. X.; Xu, X.; Du, Y.; Yang, J.; Bai, Z. C.; Dou, S. X. Comprehensive new insights and perspectives into Ti-based anodes for next-generation alkaline metal (Na+, K+) ion batteries. Adv. Energy Mater. 2018, 8, 1801888.
Google Scholar
[12]
Zhao, Y.; Zhu, J. J.; Ong, S. J. H.; Yao, Q. Q.; Shi, X. L.; Hou, K.; Xu, Z. J.; Guan, L. H. High-rate and ultralong cycle-life potassium ion batteries enabled by in situ engineering of yolk-shell FeS2@C structure on graphene matrix. Adv. Energy Mater. 2018, 8, 1802565.
Google Scholar
[13]
Zhou, J. W.; Liu, Y.; Zhang, S. L.; Zhou, T. F.; Guo, Z. P. Metal chalcogenides for potassium storage. InfoMat 2020, 2, 437-465.
Google Scholar
[14]
Chen, B.; Chao, D. L.; Liu, E. Z.; Jaroniec, M.; Zhao, N. Q.; Qiao, S. Z. Transition metal dichalcogenides for alkali metal ion batteries: Engineering strategies at the atomic level. Energy Environ. Sci. 2020, 13, 1096-1131.
Google Scholar
[15]
Yang, F. H.; Gao, H.; Hao, J. N.; Zhang, S. L.; Li, P.; Liu, Y. Q.; Chen, J.; Guo, Z. P. Yolk-shell structured FeP@C nanoboxes as advanced anode materials for rechargeable lithium-/potassium-ion batteries. Adv. Funct. Mater. 2019, 29, 1808291.
Google Scholar
[16]
Liu, Q. N.; Hu, Z.; Liang, Y. R.; Li, L.; Zou, C.; Jin, H. L.; Wang, S.; Lu, H. M.; Gu, Q. F.; Chou, S. L. et al. Facile synthesis of hierarchical hollow CoP@C composites with superior performance for sodium and potassium storage. Angew. Chem., Int. Ed. 2020, 59, 5159-5164.
Google Scholar
[17]
Yi, Y. Y.; Sun, Z. T.; Li, C.; Tian, Z. N.; Lu, C.; Shao, Y. L.; Li, J.; Sun, J. Y.; Liu, Z. F. Designing 3D biomorphic nitrogen-doped MoSe2/ graphene composites toward high-performance potassium-ion capacitors. Adv. Funct. Mater. 2020, 30, 1903878.
Google Scholar
[18]
Jia, B. R.; Yu, Q. Y.; Zhao, Y. Z.; Qin, M. L.; Wang, W.; Liu, Z. W.; Lao, C. Y.; Liu, Y.; Wu, H. W.; Zhang, Z. L. et al. Bamboo-like hollow tubes with MoS2/N-doped-C interfaces boost potassium-ion storage. Adv. Funct. Mater. 2018, 28, 1803409.
Google Scholar
[19]
Yang, T. Y.; Liang, J.; Sultana, I.; Rahman, M. M.; Monteiro, M. J.; Chen, Y.; Shao, Z. P.; Silva, S. R. P.; Liu, J. Formation of hollow MoS2/ carbon microspheres for high capacity and high rate reversible alkali-ion storage. J. Mater. Chem. A 2018, 6, 8280-8288.
Google Scholar
[20]
Cui, Y. P.; Liu, W.; Feng, W. T.; Zhang, Y.; Du, Y. X.; Liu, S.; Wang, H. L.; Chen, M.; Zhou, J. Controlled design of well-dispersed ultrathin MoS2 nanosheets inside hollow carbon skeleton: Toward fast potassium storage by constructing spacious “houses” for K ions. Adv. Funct. Mater. 2020, 30, 1908755.
Google Scholar
[21]
Zheng, N.; Jiang, G. Y.; Chen, X.; Mao, J. Y.; Zhou, Y. J.; Li, Y. S. Rational design of a tubular, interlayer expanded MoS2-N/O doped carbon composite for excellent potassium-ion storage. J. Mater. Chem. A 2019, 7, 9305-9315.
Google Scholar
[22]
Song, Q.; Yan, H. B.; Liu, K. D.; Xie, K. Y.; Li, W.; Gai, W. H.; Chen, G. H.; Li, H. J.; Shen, C.; Fu, Q. G. et al. Vertically grown edge-rich graphene nanosheets for spatial control of Li nucleation. Adv. Energy Mater. 2018, 8, 1800564.
Google Scholar
[23]
Zhang, Q. F.; Wang, L. L.; Wang, J.; Xing, C. Y.; Ge, J. M.; Fan, L.; Liu, Z. M.; Lu, X. L.; Wu, M. G.; Yu, X. Z. et al. Low-temperature synthesis of edge-rich graphene paper for high-performance aluminum batteries. Energy Storage Mater. 2018, 15, 361-367.
Google Scholar
[24]
Zhang, Z. Y.; Wu, S. L.; Cheng, J. Y.; Zhang, W. J. MoS2 nanobelts with (002) plane edges-enriched flat surfaces for high-rate sodium and lithium storage. Energy Storage Mater. 2018, 15, 65-74.
Google Scholar
[25]
Zheng, N.; Jiang, G. Y.; Chen, X.; Mao, J. Y.; Jiang, N.; Li, Y. S. Battery separators functionalized with edge-rich MoS2/C hollow microspheres for the uniform deposition of Li2S in high-performance lithium-sulfur batteries. Nano-Micro Lett. 2019, 11, 43-57.
Google Scholar
[26]
Shaju, K. M.; Jiao, F.; Débart, A.; Bruce, P. G. Mesoporous and nanowire Co3O4 as negative electrodes for rechargeable lithium batteries. Phys. Chem. Chem. Phys. 2007, 9, 1837-1842.
Google Scholar
[27]
Dong, Y. L.; Xu, Y.; Li, W.; Fu, Q.; Wu, M. H.; Manske, E.; Kröger, J.; Lei, Y. Insights into the crystallinity of layer-structured transition metal dichalcogenides on potassium ion battery performance: A case study of molybdenum disulfide. Small 2019, 15, 1900497.
Google Scholar
[28]
Teng, Y. Q.; Zhao, H. L.; Zhang, Z. J.; Li, Z. L.; Xia, Q.; Zhang, Y.; Zhao, L. N.; Du, X. F.; Du, Z. H.; Lv, P. P. et al. MoS2 nanosheets vertically grown on graphene sheets for lithium-ion battery anodes. ACS Nano 2016, 10, 8526-8535.
Google Scholar
[29]
Zhang, Z. J.; Zhao, H. L.; Teng, Y. Q.; Chang, X. W.; Xia, Q.; Li, Z. L.; Fang, J. J.; Du, Z. H.; Świerczek, K. Carbon-sheathed MoS2 nanothorns epitaxially grown on CNTs: Electrochemical application for highly stable and ultrafast lithium storage. Adv. Energy Mater. 2018, 8, 1700174.
Google Scholar
[30]
Jiang, G. S.; Xu, F.; Yang, S. H.; Wu, J. P.; Wei, B. Q.; Wang, H. Q. Mesoporous, conductive molybdenum nitride as efficient sulfur hosts for high-performance lithium-sulfur batteries. J. Power Sources 2018, 395, 77-84.
Google Scholar
[31]
Chong, S. K.; Sun, L.; Shu, C. Y.; Guo, S. W.; Liu, Y. N.; Wang, W.; Liu, H. K. Chemical bonding boosts nano-rose-like MoS2 anchored on reduced graphene oxide for superior potassium-ion storage. Nano Energy 2019, 63, 103868.
Google Scholar
[32]
Zhang, J. Y.; Cui, P. X.; Gu, Y.; Wu, D. J.; Tao, S.; Qian, B.; Chu, W. S.; Song, L. Encapsulating carbon-coated MoS2 nanosheets within a nitrogen-doped graphene network for high-performance potassium- ion storage. Adv. Mater. Interfaces 2019, 6, 1901066.
Google Scholar
[33]
Ge, J. M.; Fan, L.; Wang, J.; Zhang, Q. F.; Liu, Z. M.; Zhang, E. J.; Liu, Q.; Yu, X. Z.; Lu, B. A. MoSe2/N-doped carbon as anodes for potassium-ion batteries. Adv. Energy Mater. 2018, 8, 1801477.
Google Scholar
[34]
Wang, W.; Jiang, B.; Qian, C.; Lv, F.; Feng, J. R.; Zhou, J. H.; Wang, K.; Yang, C.; Yang, Y.; Guo, S. J. Pistachio-shuck-like MoSe2/C core/shell nanostructures for high-performance potassium-ion storage. Adv. Mater. 2018, 30, 1801812.
Google Scholar
[35]
Yang, C.; Feng, J. R.; Lv, F.; Zhou, J. H.; Lin, C. F.; Wang, K.; Zhang, Y. L.; Yang, Y.; Wang, W.; Li, J. B. et al. Metallic graphene-like VSe2 ultrathin nanosheets: Superior potassium-ion storage and their working mechanism. Adv. Mater. 2018, 30, 1800036.
Google Scholar
[36]
Yang, L.; Hong, W. W.; Zhang, Y.; Tian, Y.; Gao, X.; Zhu, Y. R.; Zou, G. Q.; Hou, H. S.; Ji, X. B. Hierarchical NiS2 modified with bifunctional carbon for enhanced potassium-ion storage. Adv. Funct. Mater. 2019, 29, 1903454.
Google Scholar
[37]
Xu, F.; Qiu, Y. Q.; Han, H. J.; Jiang, G. S.; Zhao, R. X.; Zhang, E.; Li, H. J.; Wang, H. Q.; Kaskel, S. Manipulation of carbon framework from the microporous to nonporous via a mechanical-assisted treatment for structure-oriented energy storage. Carbon 2020, 159, 140-148.
Google Scholar
[38]
Jiang, G. S.; Han, H. J.; Zhuang, W. Q.; Xu, X. S.; Kaskel, S.; Xu, F.; Wang, H. Q. Three-dimensional ordered mesoporous cobalt nitride for fast-kinetics and stable-cycling lithium storage. J. Mater. Chem. A 2019, 7, 17561-17569.
Google Scholar
[39]
Jiang, G. S.; Qiu, Y. Q.; Lu, Q. Q.; Zhuang, W. Q.; Xu, X. S.; Kaskel, S.; Xu, F.; Wang, H. Q. Mesoporous thin-wall molybdenum nitride for fast and stable Na/Li storage. ACS Appl. Mater. Interfaces 2019, 11, 41188-41195.
Google Scholar
[40]
Xu, F.; Ding, B. C.; Qiu, Y. Q.; Dong, R. H.; Zhuang, W. Q.; Xu, X. S.; Han, H. J.; Yang, J. Y.; Wei, B. Q.; Wang, H. Q. et al. Generalized domino-driven synthesis of hollow hybrid carbon spheres with ultrafine metal nitrides/oxides. Matter, in press, .
Crossref Google Scholar
[41]
Xu, X. S.; Xu, Y. X.; Xu, F.; Jiang, G. S.; Jian, J.; Yu, H. W.; Zhang, E. M.; Shchukin, D.; Kaskel, S.; Wang, H. Q. Black BiVO4: Size tailored synthesis, rich oxygen vacancies, and sodium storage performance. J. Mater. Chem. A 2020, 8, 1636-1645.
Google Scholar
[42]
Xu, F.; Han, H. J.; Qiu Y. Q.; Zhang E.; Repich, H.; Qu C. Z.; Yu, H. W.; Wang, H. Q.; Kaskel, S. Facile regulation of carbon framework from the microporous to low-porous via molecular crosslinker design and enhanced Na storage, Carbon, in press, .
Crossref Google Scholar
[43]
Wu, J. X.; Lu, Z. H.; Li, K. K.; Cui, J.; Yao, S. S.; Haq, M. I. U.; Li, B. H.; Yang, Q. H.; Kang, F. Y.; Ciucci, F. et al. Hierarchical MoS2/ carbon microspheres as long-life and high-rate anodes for sodium-ion batteries. J. Mater. Chem. A 2018, 6, 5668-5677.
Google Scholar
[44]
Teng, Y. Q.; Zhao, H. L.; Zhang, Z. J.; Zhao, L. N.; Zhang, Y.; Li, Z. L.; Xia, Q.; Du, Z. H.; Świerczek, K. MoS2 nanosheets vertically grown on reduced graphene oxide via oxygen bonds with carbon coating as ultrafast sodium ion batteries anodes. Carbon 2017, 119, 91-100.
Google Scholar
Nano Research
Volume 13 Issue 10,
October 2020
Pages 2763-2769
DOI: 10.1007/s12274-020-2925-3
Cite this article:
Jiang G, Xu X, Han H, et al. Edge-enriched MoS2 for kinetics-enhanced potassium storage. Nano Research, 2020, 13(10): 2763-2769. https://doi.org/10.1007/s12274-020-2925-3
Topics:
Ion batteriesKinetics Layered semiconductorsLithiumMolybdenum compoundsPotassium

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Received: 03 May 2020
Revised: 07 June 2020
Accepted: 08 June 2020
Published: 05 October 2020
© The Author(s) 2020

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