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Research Article

Wafer-scale quasi-layered tungstate-doped polypyrrole film with high volumetric capacitance

Huabo Liu1, Jiaxing Liang1, John Watt2, Richard D. Tilley3, Rose Amal1, Da-Wei Wang1( )
School of Chemical Engineering, University of New South Wales, Sydney, NSW 2052, Australia
Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, NW 87545, USA
School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia
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Graphical Abstract

Wafer-scale quasi-layered tungstate-doped polypyrrole prepared from electrochemical deposition shows high volumetric capacitance and excellent charge—discharge cycling stability.

Abstract

Layered materials are particularly attractive for supercapacitors because of their unique physical, electrical and chemical properties. Here, we demonstrate a facile and scalable electrochemical deposition method for wafer-scale synthesis of quasi-layered tungstate-doped polypyrrole films (named TALPy) with controllable thickness and size. The as-prepared TALPy film exhibits a high gravimetric density and excellent volumetric capacitance, exceeding many high-performing carbon- and polymer-based film electrodes. Based on combined results of ex-situ X-ray diffraction (XRD), Raman and X-ray photoelectron spectroscopy (XPS), it is determined that TALPy stores charge through an ion intercalation process accompanied by change in oxidation states of polypyrrole backbone, which is referred as intercalation pseudocapacitance. All these results suggest the great promise of electrochemical deposition as a scalable and controllable bottom-up approach for synthesizing quasi-layered conductive organic-inorganic hybrid films for electrochemical energy storage applications with high volumetric performance.

Keywords

electrochemical depositionconductive polymerpolypyrroleorganic-inorganic hybridsupercapacitorintercalation pseudocapacitance

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Nano Research
Volume 16 Issue 4,
April 2023
Pages 4895-4900
DOI: 10.1007/s12274-021-3783-3
Cite this article:
Liu H, Liang J, Watt J, et al. Wafer-scale quasi-layered tungstate-doped polypyrrole film with high volumetric capacitance. Nano Research, 2023, 16(4): 4895-4900. https://doi.org/10.1007/s12274-021-3783-3
Part of a topical collection:
Special Issue of Xiamen University Centennial CelebrationAccelerating clean energy innovations via nanotechnology toward achieving circular economy

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Received: 03 May 2021
Revised: 28 July 2021
Accepted: 31 July 2021
Published: 12 August 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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