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Research Article

Cobalt doping boosted electrocatalytic activity of CaMn3O6 for hydrogen evolution reaction

Qun Li1,§, Kaisi Liu1,§, Siwei Gui3, Jiabin Wu1, Xiaogang Li3, Zaifang Li2( ), Hongrun Jin1, Hui Yang3( ), Zhimi Hu1, Wenxi Liang1( ), Liang Huang1( )
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China
China-Australia Institute for Advanced Materials and Manufacturing, Jiaxing University, Jiaxing 314001, China
State Key Laboratory of Material Processing and Die & Mold Technology, Department of Mechanics, School of Aerospace Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

§ Qun Li and Kaisi Liu contributed equally to this work.

Show Author Information

Graphical Abstract

The cobalt (Co) doped CaMn3O6 nanowires (NWs) exhibit excellent performance for hydrogen evolution reaction (HER) with a small onset overpotential of 70 mV, and an overpotential of 140 mV at the current density of 10 mA·cm−2.

Abstract

The development of earth-abundant-metal-based electrocatalysts with high efficiency and long-term stability for hydrogen evolution reaction (HER) is crucial for the clean and renewable energy application. Herein, we report a molten-salt method to synthesize Co-doped CaMn3O6 (CMO) nanowires (NWs) as effective electrocatalyst for HER. The as-obtained CaMn3−xCoxO6 (CMCO) exhibits a small onset overpotential of 70 mV, a required overpotential of 140 mV at a current density of 10 mA·cm−2, a Tafel slope of 39 mV·dec−1 in 0.1 M HClO4, and a satisfying long-term stability. Experimental characterizations combined with density functional theory (DFT) calculations demonstrate that the obtained HER performance can be attributed to the Co-doping which altered CMO’s surface electronic structures and properties. Considering the simplicity of synthesis route and the abundance of the pertinent elements, the synthesized CMCO shows a promising prospect as a candidate for the development of earth-abundant, metal-based, and cost-effective electrocatalyst with superior HER activity. Our results also establish a strategy of rational design and construction of novel electrocatalyst toward HER by tailoring band structures of transition metal oxides (TMOs).

Keywords

CMCO nanowireshydrogen evolution reactionelectronic structuredopant

Electronic Supplementary Material

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Nano Research
Volume 15 Issue 4,
April 2022
Pages 2870-2876
DOI: 10.1007/s12274-021-3879-9
Cite this article:
Li Q, Liu K, Gui S, et al. Cobalt doping boosted electrocatalytic activity of CaMn3O6 for hydrogen evolution reaction. Nano Research, 2022, 15(4): 2870-2876. https://doi.org/10.1007/s12274-021-3879-9
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Received: 01 July 2021
Revised: 06 September 2021
Accepted: 09 September 2021
Published: 20 October 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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