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The practical application of all-inorganic semiconductor lead halide perovskite nanocrystals (LHP NCs) has been limited by their poor stability. Recently, a lot of research on core–shell structure has been done to improve the stability of perovskite NCs, but the effect was far from the application requirements. Herein, we, for the first time, report a convenient approach to synthesize organic–inorganic double shell CsPbBr3@SiO2@polystyrene (PS) NCs with an inter-core of CsPbBr3, the intermediate layer of SiO2 shell, and outmost PS shell. Particularly, the CsPbBr3@SiO2@PS NCs maintained more than 90% of their initial photoluminescence (PL) intensity under one month's ultraviolet lamp irradiation or in 85 °C and 85% relative humidity (RH) condition. The white-light-emitting-diodes (WLEDs) were fabricated by encapsulating commercial InGaN chip with CsPbBr3@SiO2@PS NCs and K2SiF6:Mn4+ (KSF:Mn4+) phosphor with a luminous efficacy of ~ 100 lm/W at 20 mA current and a color gamut of 128% of the National Television Standards Committee (NTSC) standard. In addition, these WLEDs still maintain 91% of the initial luminous efficacy after 1200 h of continuous lighting. These results demonstrated that double shell-protected CsPbBr3 perovskite NCs have great potential in the field of WLEDs.
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