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Review Article

Solid electrolyte interphase on anodes in rechargeable lithium batteries

Lihua Chu1, Yuxin Shi1, Ze Li1, Changxu Sun1, Hao Yan1, Jing Ma1, Xuchen Li1, Chaofeng Liu2, Jianan Gu1, Kai Liu1, Lehao Liu1, Bing Jiang1, Yingfeng Li1, Meicheng Li1( )
School of New Energy, North China Electric Power University, Beijing 102206, China
School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
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Graphical Abstract

The basic science and latest progress of the solid electrolyte interphase (SEI) studies on the anode surface are reviewed. The formation mechanism, materials, and electrolytes are discussed and summarized in detail.

Abstract

Highly safe and efficient rechargeable lithium batteries have become an indispensable component of the intelligent society powering smart electronics and electric vehicles. This review summarizes the formation principle, chemical compositions, and theoretical models of the solid electrolyte interphase (SEI) on the anode in the lithium battery, involving the functions and influences of the electroactive materials. The discrepancies of the SEI on different kinds of anode materials, as well as the choice and design of the electrolytes are detailedly clarified. Furthermore, the design strategies to obtain a stable and efficient SEI are outlined and discussed. Last but not least, the challenges and perspectives of artificial SEI technology are briefly proposed for the development of high-efficiency batteries in practice.

Keywords

solid electrolyte interphase (SEI)lithium batteriesanode materialselectrolytedendrite

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Nano Research
Volume 16 Issue 9,
September 2023
Pages 11589-11603
DOI: 10.1007/s12274-023-5702-2
Cite this article:
Chu L, Shi Y, Li Z, et al. Solid electrolyte interphase on anodes in rechargeable lithium batteries. Nano Research, 2023, 16(9): 11589-11603. https://doi.org/10.1007/s12274-023-5702-2
Topics:
Ion batteriesLithium batteriesSecondary batteries
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Received: 31 January 2023
Revised: 13 March 2023
Accepted: 30 March 2023
Published: 03 May 2023
© Tsinghua University Press 2023
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