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Research Article

Active plane modulation of Bi2O3 nanosheets via Zn substitution for efficient electrocatalytic CO2 reduction to formic acid

Yumei Liu1,2,§, Tiantian Wu3,§, Hongfei Cheng4, Jiawen Wu2, Xiaodong Guo1( ), Hong Jin Fan2( )
College of Chemical Engineering, Sichuan University, Chengdu 610065, China
School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, China
Institute of Materials Research and Engineering, A*STAR, 2 Fusionopolis Way, Singapore 138634, Singapore

§ Yumei Liu and Tiantian Wu contributed equally to this work.

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Graphical Abstract

Structural modulation via Zn2+ cooperation promotes the exposure of active plane (002) in the Bi2O3 nanosheet and the formation as well as stabilization of the OCHO* intermediate. Therefore, high Faradaic efficiency of formate (> 90%) in a wide potential range from −0.8 to −1.3 V is obtained in Bi2O3 with Zn doping (Zn-BO).

Abstract

Formic acid is considered one of the most economically viable products for electrocatalytic CO2 reduction reaction (CO2RR). However, developing highly active and selective electrocatalysts for effective CO2 conversion remains a grand challenge. Herein, we report that structural modulation of the bismuth oxide nanosheet via Zn2+ cooperation has a profound positive effect on exposure of the active plane, thereby contributing to high electrocatalytic CO2RR performance. The obtained Zn-Bi2O3 catalyst demonstrates superior selectivity towards formate generation in a wide potential range; a high Faradaic efficiency of 95% and a desirable partial current density of around 20 mA·cm−2 are obtained at −0.9 V (vs. reversible hydrogen electrode (RHE)). As proposed by density functional theory calculations, Zn substitution is the most energetically feasible for forming and stabilizing the key OCHO* intermediate among the used metal ions. Moreover, the more negative adsorption energy of OCHO* and the relatively low energy barrier for the desorption of HCOOH* are responsible for the enhanced activity and selectivity.

Keywords

electrocatalytic CO2 reductionBi2O3 catalystactive plane modulationZn substitutionhigh selectivity

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References

[1]

Ager, J. W.; Lapkin, A. A. Chemical storage of renewable energy. Science 2018, 360, 707–708.
Crossref Google Scholar
[2]

Cheng, H. F.; Liu, Y. M.; Wu, J. W.; Zhang, Z.; Li, X. G.; Wang, X.; Fan, H. J. Concurrent H2 generation and formate production assisted by CO2 absorption in one electrolyzer. Small Methods 2021, 5, 2100871.
Crossref Google Scholar
[3]

Gong, Q. F.; Ding, P.; Xu, M. Q.; Zhu, X. R.; Wang, M. Y.; Deng, J.; Ma, Q.; Han, N.; Zhu, Y.; Lu, J. et al. Structural defects on converted bismuth oxide nanotubes enable highly active electrocatalysis of carbon dioxide reduction. Nat. Commun. 2019, 10, 2807.
Crossref Google Scholar
[4]

Shen, C. Q.; Wang, P. T.; Li, L. G.; Huang, X. Q.; Shao, Q. Phase and structure modulating of bimetallic Cu/In nanoparticles realizes efficient electrosynthesis of syngas with wide CO/H2 ratios. Nano Res. 2022, 15, 528–534.
Crossref Google Scholar
[5]

Liu, M.; Liu, M. X.; Wang, X. M.; Kozlov, S. M.; Cao, Z.; De Luna, P.; Li, H. M.; Qiu, X. Q.; Liu, K.; Hu, J. H. et al. Quantum-dot-derived catalysts for CO2 reduction reaction. Joule 2019, 3, 1703–1718.
Crossref Google Scholar
[6]

Wang, H. X.; Tzeng, Y. K.; Ji, Y. F.; Li, Y. B.; Li, J.; Zheng, X. L.; Yang, A. K.; Liu, Y. Y.; Gong, Y. J.; Cai, L. L. et al. Synergistic enhancement of electrocatalytic CO2 reduction to C2 oxygenates at nitrogen-doped nanodiamonds/Cu interface. Nat. Nanotechnol. 2020, 15, 131–137.
Crossref Google Scholar
[7]

Wei, Z. N.; Yue, S.; Gao, S. Y.; Cao, M. N.; Cao, R. Synergetic effects of gold-doped copper nanowires with low Au content for enhanced electrocatalytic CO2 reduction to multicarbon products. Nano Res. 2023, 16, 7777–7783.
Crossref Google Scholar
[8]

Fan, L.; Xia, C.; Zhu, P.; Lu, Y. Y.; Wang, H. T. Electrochemical CO2 reduction to high-concentration pure formic acid solutions in an all-solid-state reactor. Nat. Commun. 2020, 11, 3633.
Crossref Google Scholar
[9]

Wang, L.; Nitopi, S.; Wong, A. B.; Snider, J. L.; Nielander, A. C.; Morales-Guio, C. G.; Orazov, M.; Higgins, D. C.; Hahn, C.; Jaramillo, T. F. Electrochemically converting carbon monoxide to liquid fuels by directing selectivity with electrode surface area. Nat. Catal. 2019, 2, 702–708.
Crossref Google Scholar
[10]

Deng, P. L.; Yang, F.; Wang, Z. T.; Chen, S. H.; Zhou, Y. Z.; Zaman, S.; Xia, B. Y. Metal-organic framework-derived carbon nanorods encapsulating bismuth oxides for rapid and selective CO2 electroreduction to formate. Angew. Chem., Int. Ed. 2020, 59, 10807–10813.
Crossref Google Scholar
[11]

Eppinger, J.; Huang, K. W. Formic acid as a hydrogen energy carrier. ACS Energy Lett. 2017, 2, 188–195.
Crossref Google Scholar
[12]

Wang, F.; Li, Y.; Xia, X. H.; Cai, W.; Chen, Q. G.; Chen, M. H. Metal-CO2 electrochemistry: From CO2 recycling to energy storage. Adv. Energy Mater. 2021, 11, 2100667.
Crossref Google Scholar
[13]

Saha, P.; Amanullah, S.; Dey, A. Selectivity in electrochemical CO2 reduction. Acc. Chem. Res. 2022, 55, 134–144.
Crossref Google Scholar
[14]

Li, H. X.; Yue, X.; Qiu, Y. S.; Xiao, Z.; Yu, X. B.; Xue, C.; Xiang, J. H. Selective electroreduction of CO2 to formate over the co-electrodeposited Cu/Sn bimetallic catalyst. Mater. Today Energy 2021, 21, 100797.
Crossref Google Scholar
[15]

Ma, M.; Djanashvili, K.; Smith, W. A. Controllable hydrocarbon formation from the electrochemical reduction of CO2 over Cu nanowire arrays. Angew. Chem., Int. Ed. 2016, 55, 6680–6684.
Crossref Google Scholar
[16]

Gao, N.; Wang, F. M.; Ding, J. W.; Sendeku, M. G.; Yu, P.; Zhan, X. Y.; Cai, S. F.; Xiao, C. H.; Yang, R.; He, J. et al. Intercalated gold nanoparticle in 2D palladium nanosheet avoiding CO poisoning for formate production under a wide potential window. ACS Appl. Mater. Interfaces 2022, 14, 10344–10352.
Crossref Google Scholar
[17]

Xie, J. F.; Wang, X. Y.; Lv, J. Q.; Huang, Y. Y.; Wu, M. X.; Wang, Y. B.; Yao, J. N. Reversible aqueous zinc-CO2 batteries based on CO2–HCOOH interconversion. Angew. Chem., Int. Ed. 2018, 57, 16996–17001.
Crossref Google Scholar
[18]

Chen, Z.; Fan, T. T.; Zhang, Y. Q.; Xiao, J.; Gao, M. R.; Duan, N. Q.; Zhang, J. W.; Li, J. H.; Liu, Q. X.; Yi, X. D. et al. Wavy SnO2 catalyzed simultaneous reinforcement of carbon dioxide adsorption and activation towards electrochemical conversion of CO2 to HCOOH. Appl. Catal. B: Environ. 2020, 261, 118243.
Crossref Google Scholar
[19]

Liu, S. B.; Xiao, J.; Lu, X. F.; Wang, J.; Wang, X.; Lou, X. W. Efficient electrochemical reduction of CO2 to HCOOH over sub-2 nm SnO2 quantum wires with exposed grain boundaries. Angew. Chem., Int. Ed. 2019, 58, 8499–8503.
Crossref Google Scholar
[20]

Yang, Z. N.; Oropeza, F. E.; Zhang, K. H. L. P-block metal-based (Sn, In, Bi, Pb) electrocatalysts for selective reduction of CO2 to formate. APL Mater. 2020, 8, 060901.
Crossref Google Scholar
[21]

Greeley, J.; Jaramillo, T. F.; Bonde, J.; Chorkendorff, I.; Nørskov, J. K. Computational high-throughput screening of electrocatalytic materials for hydrogen evolution. Nat. Mater. 2006, 5, 909–913.
Crossref Google Scholar
[22]

Li, N. H.; Yan, P.; Tang, Y. H.; Wang, J. H.; Yu, X. Y.; Wu, H. B. In-situ formation of ligand-stabilized bismuth nanosheets for efficient CO2 conversion. Appl. Catal. B: Environ. 2021, 297, 120481.
Crossref Google Scholar
[23]

Yang, H.; Han, N.; Deng, J.; Wu, J. H.; Wang, Y.; Hu, Y. P.; Ding, P.; Li, Y. F.; Li, Y. G.; Lu, J. Selective CO2 reduction on 2D mesoporous Bi nanosheets. Adv. Energy Mater. 2018, 8, 1801536.
Crossref Google Scholar
[24]

Koh, J. H.; Won, D. H.; Eom, T.; Kim, N. K.; Jung, K. D.; Kim, H.; Hwang, Y. J.; Min, B. K. Facile CO2 electro-reduction to formate via oxygen bidentate intermediate stabilized by high-index planes of Bi dendrite catalyst. ACS Catal. 2017, 7, 5071–5077.
Crossref Google Scholar
[25]

Deng, P. L.; Wang, H. M.; Qi, R. J.; Zhu, J. X.; Chen, S. H.; Yang, F.; Zhou, L.; Qi, K.; Liu, H. F.; Xia, B. Y. Bismuth oxides with enhanced bismuth-oxygen structure for efficient electrochemical reduction of carbon dioxide to formate. ACS Catal. 2020, 10, 743–750.
Crossref Google Scholar
[26]

Wu, Z. X.; Wu, H. B.; Cai, W. Q.; Wen, Z. H.; Jia, B. H.; Wang, L.; Jin, W.; Ma, T. Y. Engineering bismuth–tin interface in bimetallic aerogel with a 3D porous structure for highly selective electrocatalytic CO2 reduction to HCOOH. Angew. Chem., Int. Ed. 2021, 60, 12554–12559.
Crossref Google Scholar
[27]

Zhang, Z.; Wen, G. B.; Luo, D.; Ren, B. H.; Zhu, Y. F.; Gao, R.; Dou, H. Z.; Sun, G. R.; Feng, M.; Bai, Z. Y. et al. “Two ships in a bottle” design for Zn-Ag-O catalyst enabling selective and long-lasting CO2 electroreduction. J. Am. Chem. Soc. 2021, 143, 6855–6864.
Crossref Google Scholar
[28]

Han, N.; Wang, Y.; Yang, H.; Deng, J.; Wu, J. H.; Li, Y. F.; Li, Y. G. Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate. Nat. Commun. 2018, 9, 1320.
Crossref Google Scholar
[29]

Ren, J. J.; Zheng, L. C.; Su, Y. M.; Meng, P. P.; Zhou, Q. Y.; Zeng, H.; Zhang, T.; Yu, H. J. Competitive adsorption of Cd(II), Pb(II) and Cu(II) ions from acid mine drainage with zero-valent iron/phosphoric titanium dioxide: XPS qualitative analyses and DFT quantitative calculations. Chem. Eng. J. 2022, 445, 136778.
Crossref Google Scholar
[30]

Liu, S.; Cao, Y.; Liu, H.; Wang, H. L.; Zhang, B. S.; Zhang, Y. M.; Zhang, L. H.; Zhang, S.; Sun, J. Efficient electrochemical reduction of CO2 promoted by the electrospun Cu1.96S/Cu tandem catalyst. Nanoscale 2021, 13, 16986–16994.
Crossref Google Scholar
[31]

Li, M. L.; Li, W. B.; Song, W. T.; Wang, C.; Yao, Y. F.; Wu, C. P.; Luo, W. J.; Zou, Z. G. Do Cu substrates participate in Bi electrocatalytic CO2 reduction? ChemNanoMat 2021, 7, 128–133.
Crossref Google Scholar
[32]

Yan, S.; Peng, C.; Yang, C.; Chen, Y. S.; Zhang, J. B.; Guan, A. X.; Lv, X. M.; Wang, H. Z.; Wang, Z. Q.; Sham, T. K. et al. Electron localization and lattice strain induced by surface lithium doping enable ampere-level electrosynthesis of formate from CO2. Angew. Chem., Int. Ed. 2021, 60, 25741–25745.
Crossref Google Scholar
[33]

Zheng, X. B.; Yang, J. R.; Xu, Z. F.; Wang, Q. S.; Wu, J. B.; Zhang, E. H.; Dou, S. X.; Sun, W. P.; Wang, D. S.; Li, Y. D. Ru–Co pair sites catalyst boosts the energetics for the oxygen evolution reaction. Angew. Chem., Int. Ed. 2022, 61, e202205946.
Crossref Google Scholar
[34]

Li, L.; Cai, F. F.; Qi, F. X. Y.; Ma, D. K. Cu nanowire bridged Bi nanosheet arrays for efficient electrochemical CO2 reduction toward formate. J. Alloys Compd. 2020, 841, 155789.
Crossref Google Scholar
[35]

Liu, G. B.; Li, Z. H.; Shi, J. J.; Sun, K.; Ji, Y. J.; Wang, Z. G.; Qiu, Y. F.; Liu, Y. Y.; Wang, Z. J.; Hu, P. A. Black reduced porous SnO2 nanosheets for CO2 electroreduction with high formate selectivity and low overpotential. Appl. Catal. B: Environ. 2020, 260, 118134.
Crossref Google Scholar
[36]

Yang, G.; Liang, Y. J.; Wang, K.; Yang, J.; Zeng, Z. K.; Xu, R.; Xie, X. J. Simultaneous introduction of 0D Bi nanodots and oxygen vacancies onto 1D Bi6Mo2O15 sub-microwires for synergistically enhanced photocatalysis. Chem. Eng. J. 2021, 409, 128098.
Crossref Google Scholar
[37]

Chen, Z. P.; Mou, K. W.; Wang, X. H.; Liu, L. C. Nitrogen-doped graphene quantum dots enhance the activity of Bi2O3 nanosheets for electrochemical reduction of CO2 in a wide negative potential region. Angew. Chem., Int. Ed. 2018, 57, 12790–12794.
Crossref Google Scholar
[38]

Lee, C. W.; Hong, J. S.; Yang, K. D.; Jin, K.; Lee, J. H.; Ahn, H. Y.; Seo, H.; Sung, N. E.; Nam, K. T. Selective electrochemical production of formate from carbon dioxide with bismuth-based catalysts in an aqueous electrolyte. ACS Catal. 2018, 8, 931–937.
Crossref Google Scholar
[39]

Ma, M.; Kim, S.; Chorkendorff, I.; Seger, B. Role of ion-selective membranes in the carbon balance for CO2 electroreduction via gas diffusion electrode reactor designs. Chem. Sci. 2020, 11, 8854–8861.
Crossref Google Scholar
Nano Research
Volume 16 Issue 8,
August 2023
Pages 10803-10809
DOI: 10.1007/s12274-023-5824-6
Cite this article:
Liu Y, Wu T, Cheng H, et al. Active plane modulation of Bi2O3 nanosheets via Zn substitution for efficient electrocatalytic CO2 reduction to formic acid. Nano Research, 2023, 16(8): 10803-10809. https://doi.org/10.1007/s12274-023-5824-6
Topics:
Selective catalytic reduction

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Received: 27 February 2023
Revised: 29 April 2023
Accepted: 09 May 2023
Published: 05 June 2023
© Tsinghua University Press 2023
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