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Research Article

Hydroxylated metal–organic-layer nanocages anchoring single atomic cobalt sites for robust photocatalytic CO2 reduction

Weiyi Pan1,2, Zhihe Wei1,2, Yanhui Su1,2, Yuebin Lian3, Zhangyi Zheng1,2, Huihong Yuan1,2, Yongze Qin1,2, Xulan Xie1,2, Qianqian Bai1,2, Zhenyang Jiao1,2, Wei Hua1,2, Jinzhou Chen1,2, Wenjun Yang1,2, Zhao Deng1,2( ), Yang Peng1,2,4( )
Soochow Institute for Energy and Materials Innovations, College of Energy, Soochow University, Suzhou 215006, China
Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, China
School of Photoelectric Engineering, Changzhou institute of technology, Changzhou 213032, China
Jiangsu Key Laboratory for Advanced Negative Carbon Technologies, Soochow University, Suzhou 215123, China
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Graphical Abstract

A new type of metal–organic-layer nanocages loaded with atomic cobalt catalytic sites was reported for photocatalytic CO2 reduction. The unique nanocage morphology in conjunction with the hydroxyl functional groups effectively boosts the reaction kinetics.

Abstract

Assembly of two-dimensional (2D) metal–organic layers (MOLs) based on the hard and soft acid–base theorem represents an exquisite strategy for the construction of photocatalytic platforms in virtue of the highly exposed active sites, much improved mass transport, and greatly elevated stability. Herein, nanocages composed of MOLs are produced for the first time through a cosolvent approach utilizing zirconium-based UiO-66-(OH)2 as the structural precursor. To endow the catalytic activity for CO2 conversion, single atomic Co2+ sites are appended to the Zr-oxo nodes of the MOL cages, demonstrating a remarkable CO yield of 7.74 mmol·g−1·h−1 and operational stability of 97.1% product retention after five repeated cycles. Such an outstanding photocatalytic performance is mainly attributed to the unique nanocage morphology comprising enormous 2D nanosheets for augmented Co2+ exposure and the abundant surface hydroxyl groups for local CO2 enrichment. This work underlines the tailoring of both metal–organic framework (MOF) morphology and functionality to boost the turnover rate of photocatalytic CO2 reduction reaction (CO2RR).

Keywords

photocatalytic CO2 reductionmetal–organic layernanocagesingle-atom catalystco-catalyst

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Nano Research
Volume 17 Issue 4,
April 2024
Pages 2410-2419
DOI: 10.1007/s12274-023-6083-2
Cite this article:
Pan W, Wei Z, Su Y, et al. Hydroxylated metal–organic-layer nanocages anchoring single atomic cobalt sites for robust photocatalytic CO2 reduction. Nano Research, 2024, 17(4): 2410-2419. https://doi.org/10.1007/s12274-023-6083-2
Topics:
Photocatalysis

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Received: 15 June 2023
Revised: 02 August 2023
Accepted: 10 August 2023
Published: 14 September 2023
© Tsinghua University Press 2023
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