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Research Article

Asymmetrically coordinated main group atomic In-S1N3 interface sites for promoting electrochemical CO2 reduction

Yan Gao1( ), Jinlong Ge1, Jingqiao Zhang2,3, Ting Cao2,3, Zhiyi Sun5, Wensheng Yan6, Yu Wang7, Jie Lin4( ), Wenxing Chen5, Zheng Liu2,3( )
Anhui Provincial Engineering Laboratory of Silicon-based Materials, Bengbu University, Bengbu 233030, China
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
SEPA Key Laboratory of Eco-Industry, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo 315201, China
Energy & Catalysis Center, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China
Shanghai Synchrotron Radiation Facilities, Shanghai Institute of Applied Physics, Chinese Academy of Science, Shanghai 201204, China
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Graphical Abstract

Outstandingly, the engineered In-S1N3 demonstrated a maximum formate Faradaic efficiency (FEHCOO−) of 94.3% at −0.8 V vs. reversible hydrogen electrode (RHE), exceeding the In-S2N2 and In-N4 catalysts. Furthermore, at a potential of −1.10 V vs. RHE, In-S1N3 achieves an impressive FE of 93.7% in flow cell. In-situ X-ray absorption fine structure (XAFS) and density functional theory (DFT) reveal the boosted catalytic performance of In-S1N3 sites. The contributions of In-S1N3 interfaces are deeply analysed by DFT calculations.

Abstract

Designing catalysts with highly active, selectivity, and stability for electrocatalytic CO2 to formate is currently a severe challenge. Herein, we developed an electronic structure engineering on carbon nano frameworks embedded with nitrogen and sulfur asymmetrically dual-coordinated indium active sites toward the efficient electrocatalytic CO2 reduction reaction. As expected, atomically dispersed In-based catalysts with In-S1N3 atomic interface with asymmetrically coordinated exhibited high efficiency for CO2 reduction reaction (CO2RR) to formate. It achieved a maximum Faradaic efficiency (FE) of 94.3% towards formate generation at −0.8 V vs. reversible hydrogen electrode (RHE), outperforming that of catalysts with In-S2N2 and In-N4 atomic interface. And at a potential of −1.10 V vs. RHE, In-S1N3 achieves an impressive Faradaic efficiency of 93.7% in flow cell. The catalytic performance of In-S1N3 sites was confirmed to be enhanced through in-situ X-ray absorption near-edge structure (XANES) measurements under electrochemical conditions. Our discovery provides the guidance for performance regulation of main group metal catalysts toward CO2RR at atomic scale.

Keywords

indium single-site catalystmain group metalasymmetrical coordinationCO2 reduction reactionstructure–activity relationship

Electronic Supplementary Material

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References

[1]

Gao, D. F.; Arán-Ais, R. M.; Jeon, H. S.; Cuenya, B. R. Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products. Nat. Catal. 2019, 2, 198–210.
Crossref Google Scholar
[2]

Sun, Z. Y.; Hu, Y. N.; Zhou, D. N.; Sun, M. R.; Wang, S.; Chen, W. X. Factors influencing the performance of copper-bearing catalysts in the CO2 reduction system. ACS Energy Lett. 2021, 6, 3992–4022.
Crossref Google Scholar
[3]

Xie, Y.; Ou, P. F.; Wang, X.; Xu, Z. Y.; Li, Y. C.; Wang, Z. Y.; Huang, J. E.; Wicks, J.; McCallum, C.; Wang, N. et al. High carbon utilization in CO2 reduction to multi-carbon products in acidic media. Nat. Catal. 2022, 5, 564–570.
Crossref Google Scholar
[4]

Yang, X. F.; Wang, Q. R.; Chen, F. R.; Zang, H.; Liu, C. J.; Yu, N.; Geng, B. Y. In-situ electrochemical restructuring of Cu2BiS x solid solution into Bi/Cu x S y heterointerfaces enabling stabilization intermediates for high-performance CO2 electroreduction to formate. Nano Res. 2023, 16, 7974–7981
Crossref Google Scholar
[5]

Zhao, Z. B.; Zhang, J. G.; Lei, M.; Lum, Y. Reviewing the impact of halides on electrochemical CO2 reduction. Nano Res. Energy. 2023, 2, e9120044.
Crossref Google Scholar
[6]

Yang, X.; Li, Q. X.; Chi, S. Y.; Li, H. F.; Huang, Y. B.; Cao, R. Hydrophobic perfluoroalkane modified metal-organic frameworks for the enhanced electrocatalytic reduction of CO2. SmartMat 2022, 3, 163–172.
Crossref Google Scholar
[7]

Yang, P. P.; Gao, M. R. Enrichment of reactants and intermediates for electrocatalytic CO2 reduction. Chem. Soc. Rev. 2023, 52, 4343–4380.
Crossref Google Scholar
[8]
Duanmu, J. W.; Gao, M. R. Advances in bio-inspired electrocatalysts for clean energy future. Nano Res., in press, https://doi.org/10.1007/s12274-023-5977-3.
[9]

Deng, W. Y.; Zhang, P.; Seger, B.; Gong, J. L. Unraveling the rate-limiting step of two-electron transfer electrochemical reduction of carbon dioxide. Nat. Commun. 2022, 13, 803.
Crossref Google Scholar
[10]

Gu, Z. X.; Shen, H.; Chen, Z.; Yang, Y. Y.; Yang, C.; Ji, Y. L.; Wang, Y. H.; Zhu, C.; Liu, J. L.; Li, J. et al. Efficient electrocatalytic CO2 reduction to C2+ alcohols at defect-site-rich Cu surface. Joule 2021, 5, 429–440.
Crossref Google Scholar
[11]

Wang, M. L.; Yao, Y.; Tian, Y. H.; Yuan, Y. F.; Wang, L. G.; Yang, F. Y.; Ren, J. J.; Hu, X. R.; Wu, F.; Zhang, S. Q. et al. Atomically dispersed manganese on carbon substrate for aqueous and aprotic CO2 electrochemical reduction. Adv. Mater. 2023, 35, 2210658.
Crossref Google Scholar
[12]

Zhu, Y. T.; Cui, X. Y.; Liu, H. L.; Guo, Z. G.; Dang, Y. F.; Fan, Z. X.; Zhang, Z. C.; Hu, W. P. Tandem catalysis in electrochemical CO2 reduction reaction. Nano Res. 2021, 14, 4471–4486.
Crossref Google Scholar
[13]

Niu, Z. Z.; Chi, L. P.; Wu, Z. Z.; Yang, P. P.; Fan, M. H.; Gao, M. R. CO2-assisted formation of grain boundaries for efficient CO–CO coupling on a derived Cu catalyst. Natl. Sci. Rev. 2023, 2, 20220044.
Crossref Google Scholar
[14]

Lai, W. C.; Qiao, Y.; Wang, Y. N.; Huang, H. W. Stability issues in electrochemical CO2 reduction: Recent advances in fundamental understanding and design strategies. Adv. Mater. 2023, 35, 2306288.
Crossref Google Scholar
[15]

Huang, M.; Deng, B. W.; Zhao, X. L.; Zhang, Z. Y.; Li, F.; Li, K. L.; Cui, Z. H.; Kong, L. X.; Lu, J. M.; Dong, F. et al. Template-sacrificing synthesis of well-defined asymmetrically coordinated single-atom catalysts for highly efficient CO2 electrocatalytic reduction. ACS Nano 2022, 16, 2110–2119.
Crossref Google Scholar
[16]

Ge, H.; Kuwahara, Y.; Kusu, K.; Bian, Z.; Yamashita H. Ru/H x MoO3− y with plasmonic effect for boosting photothermal catalytic CO2 methanation. Appl. Catal. B: Environ. 2022, 317, 121734.
Crossref Google Scholar
[17]

He, J. L.; Jin, Z. H.; Gan, F. L.; Xie, L. L.; Guo, J. D.; Zhang, S. H.; Jia, C. Q.; Ma, D.; Dai, Z. D.; Jiang, X. Liquefiable biomass-derived porous carbons and their applications in CO2 capture and conversion. Green Chem. 2022, 24, 3376–3415.
Crossref Google Scholar
[18]

Zhang, W.; Jia, B. H.; Liu, X.; Ma, T. Y. Surface and interface chemistry in metal-free electrocatalysts for electrochemical CO2 reduction. SmartMat 2022, 3, 5–34.
Crossref Google Scholar
[19]

Sun, M. Z.; Wong, H. H.; Wu, T.; Lu, Q. Y.; Lu, L.; Chan, C. H.; Chen, B. A.; Dougherty, A. W.; Huang, B. L. Double-dependence correlations in graphdiyne-supported atomic catalysts to promote CO2RR toward the Generation of C2 products. Adv. Energy Mater. 2023, 13, 2203858.
Crossref Google Scholar
[20]

Jin, S.; Hao, Z. M.; Zhang, K.; Yan, Z. H.; Chen, J. Advances and challenges for the electrochemical reduction of CO2 to CO: From fundamentals to industrialization. Angew. Chem., Int. Ed. 2021, 60, 20627–20648.
Crossref Google Scholar
[21]

Zhu, J. B.; Xiao, M. L.; Ren, D. Z.; Gao, R.; Liu, X. Z.; Zhang, Z.; Luo, D.; Xing, W.; Su, D.; Yu, A. et al. Quasi-covalently coupled Ni–Cu atomic pair for synergistic electroreduction of CO2. J. Am. Chem. Soc. 2022, 144, 9661–9671.
Crossref Google Scholar
[22]

Zhao, Q. L.; Wang, Y. A.; Li, M.; Zhu, S. Q.; Li, T. H.; Yang, J. X.; Lin, T.; Delmo, E. P.; Wang, Y. N.; Jang, J. et al. Organic frameworks confined Cu single atoms and nanoclusters for tandem electrocatalytic CO2 reduction to methane. SmartMat 2022, 3, 183–193.
Crossref Google Scholar
[23]

Li, Y. Z.; Chen, J. L.; Chen, S.; Liao, X. L.; Zhao, T. T.; Cheng, F. Y.; Wang, H. In situ confined growth of bismuth nanoribbons with active and robust edge sites for boosted CO2 electroreduction. ACS Energy Lett. 2022, 7, 1454–1461
Crossref Google Scholar
[24]

Wang, T.; Chen, J. D.; Ren, X. Y.; Zhang, J. C.; Ding, J.; Liu, Y. H.; Lim, K. H.; Wang, J. H.; Li, X. N.; Yang, H. et al. Halogen-incorporated Sn catalysts for selective electrochemical CO2 reduction to formate. Angew. Chem., Int. Ed. 2023, 62, e202211174.
Crossref Google Scholar
[25]

Xiao, T. S.; Tang, C.; Li, H. B.; Ye, T.; Ba, K.; Gong, P.; Sun, Z. Z. CO2 reduction with coin catalyst. Nano Res. 2022, 15, 3859–3865
Crossref Google Scholar
[26]

Dai, S.; Huang, T. H.; Liu, W. I.; Hsu, C. W.; Lee, S. W.; Chen, T. Y.; Wang, Y. C.; Wang, J. H.; Wang, K. W. Enhanced CO2 electrochemical reduction performance over Cu@AuCu catalysts at high noble metal utilization efficiency. Nano Lett. 2021, 21, 9293–9300.
Crossref Google Scholar
[27]

Li, Z.; Wu, R.; Zhao, L.; Li, P. B.; Wei, X. X.; Wang, J. J.; Chen, J. S.; Zhang, T. R. Metal-support interactions in designing noble metal-based catalysts for electrochemical CO2 reduction: Recent advances and future perspectives. Nano Res. 2021, 14, 3795–3809.
Crossref Google Scholar
[28]

Vijay, S.; Ju, W.; Brückner, S.; Tsang, S. C.; Strasser, P.; Chan, K. Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts. Nat. Catal. 2021, 4, 1024–1031.
Crossref Google Scholar
[29]

Guo, F. J.; Zhang, M. Y.; Yi, S. C.; Li, X. X.; Xin, R.; Yang, M.; Liu, B.; Chen, H. B.; Li, H. M.; Liu, Y. J. Metal-coordinated porous polydopamine nanospheres derived Fe3N-FeCo encapsulated N-doped carbon as a highly efficient electrocatalyst for oxygen reduction reaction. Nano Res. Energy. 2022, 1, 9120027.
Crossref Google Scholar
[30]

Wu, G.; Zheng, X. S.; Cui, P. X.; Jiang, H. Y.; Wang, X. Q.; Qu, Y. T.; Chen, W. X.; Lin, Y.; Li, H.; Han, X. et al. A general synthesis approach for amorphous noble metal nanosheets. Nat. Commun. 2019, 10, 4855.
Crossref Google Scholar
[31]

Cao, B.; Li, F. Z.; Gu, J. Designing Cu-based tandem catalysts for CO2 electroreduction based on mass transport of CO intermediate. ACS Catal. 2022, 12, 9735–9752.
Crossref Google Scholar
[32]

Chen, S. Y.; Li, X. Q.; Kao, C. W.; Luo, T.; Chen, K. J.; Fu, J. W.; Ma, C.; Li, H. M.; Li, M.; Chan, T. S. et al. Unveiling the proton-feeding effect in sulfur-doped Fe-N-C single-atom catalyst for enhanced CO2 electroreduction. Angew. Chem., Int. Ed. 2022, 61, e202206233.
Crossref Google Scholar
[33]

Guo, Y.; Wang, Y. C.; Shen, Y.; Cai, Z. Y.; Li, Z.; Liu, J.; Chen, J. W.; Xiao, C.; Liu, H. C.; Lin, W. B. et al. Tunable cobalt-polypyridyl catalysts supported on metal-organic layers for electrochemical CO2 reduction at low overpotentials. J. Am. Chem. Soc. 2020, 142, 21493–21501.
Crossref Google Scholar
[34]

Feng, J. Q.; Gao, H. S.; Zheng, L. R.; Chen, Z. P.; Zeng, S. J.; Jiang, C. Y.; Dong, H. F.; Liu, L. C.; Zhang, S. J.; Zhang, X. P. A Mn-N3 single-atom catalyst embedded in graphitic carbon nitride for efficient CO2 electroreduction. Nat. Commun. 2020, 11, 4341.
Crossref Google Scholar
[35]

Shang, H. S.; Wang, T.; Pei, J. J.; Jiang, Z. L.; Zhou, D. N.; Wang, Y.; Li, H. J.; Dong, J. C.; Zhuang, Z. B.; Chen, W. X. et al. Design of a single-atom Indium δ +-N4 interface for efficient electroreduction of CO2 to formate. Angew. Chem., Int. Ed. 2020, 59, 22465–22469.
Crossref Google Scholar
[36]

Jiang, Z. L.; Wang, T.; Pei, J. J.; Shang, H. S.; Zhou, D. N.; Li, H. C.; Dong, J.; Wang, Y.; Cao, R.; Zhuang, Z. B. et al. Discovery of main group single Sb-N4 active sites for CO2 electroreduction to formate with high efficiency. Energy Environ. Sci. 2020, 13, 2856–2863.
Crossref Google Scholar
[37]

Ren, B. H.; Wen, G. B.; Gao, R.; Luo, D.; Zhang, Z.; Qiu, W. B.; Ma, Q. Y.; Wang, X.; Cui, Y.; Ricardez-Sandoval, L. et al. Nano-crumples induced Sn–Bi bimetallic interface pattern with moderate electron bank for highly efficient CO2 electroreduction. Nat. Commun. 2022, 13, 2486.
Crossref Google Scholar
[38]

Zhang, J. W.; Zeng, G. M.; Chen, L. L.; Lai, W. C.; Yuan, Y. L.; Lu, Y. F.; Ma, C.; Zhang, W. H.; Huang, H. W. Tuning the reaction path of CO2 electroreduction reaction on indium single-atom catalyst: Insights into the active sites. Nano Res. 2022, 15, 4014–4022.
Crossref Google Scholar
[39]

Yuan, Y. L.; Wang, Q. Y.; Qiao, Y.; Chen, X. L.; Yang, Z. L.; Lai, W. C.; Chen, T. W.; Zhang, G. H.; Duan, H. G.; Liu, M. et al. In situ structural reconstruction to generate the active sites for CO2 electroreduction on Bismuth ultrathin nanosheets. Adv. Energy Mater. 2022, 12, 2200970
Crossref Google Scholar
[40]

Liu, J. Y.; Li, P. S.; Bi, J. H.; Wang, Y.; Zhu, Q. G.; Sun, X. F.; Zhang, J. L.; Liu, Z. M.; Han, B. X. Sm and S co-doping to construct homo-hetero Cu catalysts for synergistic enhancing CO2 electroreduction. Chin. J. Chem. 2023, 41, 1443–1449.
Crossref Google Scholar
[41]

Wei, Z. M.; Liu, Y. H.; Ding, J.; He, Q. Y.; Zhang, Q.; Zhai, Y. M. Promoting electrocatalytic CO2 reduction to CO via sulfur-doped Co-N-C single-atom catalyst†. Chin. J. Chem. 2023, 41, 3553–3559.
Crossref Google Scholar
[42]

Zhang, E. H.; Wang, T.; Yu, K.; Liu, J.; Chen, W. X.; Li, A.; Rong, H. P.; Lin, R.; Ji, S. F.; Zheng, X. S. et al. Bismuth single atoms resulting from transformation of metal-organic frameworks and their use as electrocatalysts for CO2 reduction. J. Am. Chem. Soc. 2019, 141, 16569–16573.
Crossref Google Scholar
[43]

Peng, H. J.; Tang, M. T.; Liu, X. Y.; Lamoureux, P. S.; Bajdich, M.; Abild-Pedersen, F. The role of atomic carbon in directing electrochemical CO2 reduction to multicarbon products. Energy Environ. Sci. 2021, 14, 473–482.
Crossref Google Scholar
[44]

Zhu, Y. Z.; Yang, X. X.; Peng, C.; Priest, C.; Mei, Y.; Wu, G. Carbon-supported single metal site catalysts for electrochemical CO2 reduction to CO and beyond. Small 2021, 17, 2005148.
Crossref Google Scholar
[45]

Zhang, W. J.; Jiang, M. H.; Yang, S. Y.; Hu, Y.; Mu, B.; Tie, Z.; Jin, Z. In-situ grown CuO x nanowire forest on copper foam: A 3D hierarchical and freestanding electrocatalyst with enhanced carbonaceous product selectivity in CO2 reduction. Nano Res. Energy 2022, 1, e9120033
Crossref Google Scholar
[46]

Boppella, R.; Austeria, P. M.; Kim, Y.; Kim, E.; Song, I.; Eom, Y.; Kumar, D. P.; Balamurugan, M.; Sim, E.; Kim, D. H. et al. Pyrrolic N-stabilized monovalent Ni single-atom electrocatalyst for efficient CO2 reduction: Identifying the role of pyrrolic-N and synergistic electrocatalysis. Adv. Funct. Mater. 2022, 32, 2202351.
Crossref Google Scholar
[47]

Tang, H.; Gu, H. F.; Li, Z. Y.; Chai, J.; Qin, F. J.; Lu, C. Q.; Yu, J. Y.; Zhai, H. Z.; Zhang, L.; Li, X. Y. et al. Engineering the coordination interface of isolated Co atomic sites anchored on N-doped carbon for effective hydrogen evolution reaction. ACS Appl. Mater. Interfaces 2022, 14, 46401–46409.
Crossref Google Scholar
[48]

Hu, Y. N.; Ying, D.; Sun, Z. Y.; Li, B.; Zhou, H. X.; Wang, S.; Hu, X. M.; He, K.; Qu, M.; Chen, W. X. et al. Rational design, application and dynamic evolution of Cu-N-C single-atom catalysts. J. Mater. Chem. A 2022, 10, 21769–21796.
Crossref Google Scholar
[49]

Su, X. Z.; Jiang, Z. L.; Zhou, J.; Liu, H. J.; Zhou, D. N.; Shang, H. S.; Ni, X. M.; Peng, Z.; Yang, F.; Chen, W. X. et al. Complementary operando spectroscopy identification of in-situ generated metastable charge-asymmetry Cu2-CuN3 clusters for CO2 reduction to ethanol. Nat. Commun. 2022, 13, 1322.
Crossref Google Scholar
[50]

Han, G. F.; Li, F.; Rykov, A. I.; Im, Y. K.; Yu, S. Y.; Jeon, J. P.; Kim, S. J.; Zhou, W.; Ge, R.; Ao, Z. et al. Abrading bulk metal into single atoms. Nat. Nanotechnol. 2022, 17, 403–407.
Crossref Google Scholar
[51]

Yang, T.; Mao, X. N.; Zhang, Y.; Wu, X. P.; Wang, L.; Chu, M. Y.; Pao, C. W.; Yang, S. Z.; Xu, Y.; Huang, X. Q. Coordination tailoring of Cu single sites on C3N4 realizes selective CO2 hydrogenation at low temperature. Nat. Commun. 2021, 12, 6022.
Crossref Google Scholar
[52]

Zhao, K.; Nie, X. W.; Wang, H. Z.; Chen, S.; Quan, X.; Yu, H. T.; Choi, W.; Zhang, G. H.; Kim, B.; Chen, J. G. Selective electroreduction of CO2 to acetone by single copper atoms anchored on N-doped porous carbon. Nat. Commun. 2020, 11, 2455.
Crossref Google Scholar
[53]

Zhang, S. L.; Sun, L.; Fan, Q. N.; Zhang, F. L.; Wang, Z. J.; Zou, J. S.; Zhao, S. Y.; Mao, J. F.; Guo, Z. P. Challenges and prospects of lithium-CO2 batteries. Nano Res. Energy 2022, 1, e9120001.
Crossref Google Scholar
[54]

Chen, P. Z.; Zhang, N.; Wang, S. B.; Zhou, T. P.; Tong, Y.; Ao, C. C.; Yan, W. S.; Zhang, L. D.; Chu, W. S.; Wu, C. Z. et al. Interfacial engineering of cobalt sulfide/graphene hybrids for highly efficient ammonia electrosynthesis. Proc. Natl. Acad. Sci. USA 2019, 116, 6635–6640.
Crossref Google Scholar
[55]

Tong, Y.; Chen, P. Z.; Zhou, T. P.; Xu, K.; Chu, W. S.; Wu, C.; Xie, Y. A bifunctional hybrid electrocatalyst for oxygen reduction and evolution: Cobalt oxide nanoparticles strongly coupled to B,N-decorated graphene. Angew. Chem., Int. Ed. 2017, 56, 7121–7125.
Crossref Google Scholar
[56]

Zhao, Y. S.; Yang, N. L.; Yao, H. Y.; Liu, D. B.; Song, L.; Zhu, J.; Li, S. Z.; Gu, L.; Lin, K. F.; Wang, D. Stereodefined codoping of sp-N and S atoms in few-layer graphdiyne for oxygen evolution reaction. J. Am. Chem. Soc. 2019, 141, 7240–7244.
Crossref Google Scholar
[57]

Shang, H. S.; Zhou, X. Y.; Dong, J. C.; Li, A.; Zhao, X.; Liu, Q. H.; Lin, Y.; Pei, J. J.; Li, Z.; Jiang, Z. L. et al. Engineering unsymmetrically coordinated Cu-S1N3 single atom sites with enhanced oxygen reduction activity. Nat. Commun. 2020, 11, 3049.
Crossref Google Scholar
[58]

Yang, H. H.; Chen, Y. Y.; Cui, X. J.; Wang, G. F.; Cen, Y. L.; Deng, T. S.; Yan, W. J.; Gao, J.; Zhu, S. H.; Olsbye, U. et al. A highly stable copper-based catalyst for clarifying the catalytic roles of Cu0 and Cu+ species in methanol dehydrogenation. Angew. Chem., Int. Ed. 2018, 57, 1836–1840.
Crossref Google Scholar
[59]

Lee, B. H.; Park, S.; Kim, M.; Sinha, A. K.; Lee, S. C.; Jung, E.; Chang, W. J.; Lee, K. S.; Kim, J. H.; Cho, S. P. et al. Reversible and cooperative photoactivation of single-atom Cu/TiO2 photocatalysts. Nat. Mater., 2019, 18, 620–626.
Crossref Google Scholar
[60]

Wu, Z. H.; Liu, Y. P.; Xing, X. Q.; Yao, L.; Chen, Z. J.; Mo, G.; Zheng, L. R.; Cai, Q.; Wang, H.; Zhong, J. J. et al. A novel SAXS/XRD/XAFS combined technique for in-situ time-resolved simultaneous measurements. Nano Res. 2023, 16, 1123–1131.
Crossref Google Scholar
Nano Research
Volume 17 Issue 6,
June 2024
Pages 5011-5021
DOI: 10.1007/s12274-024-6513-9
Cite this article:
Gao Y, Ge J, Zhang J, et al. Asymmetrically coordinated main group atomic In-S1N3 interface sites for promoting electrochemical CO2 reduction. Nano Research, 2024, 17(6): 5011-5021. https://doi.org/10.1007/s12274-024-6513-9
Topics:
Electrocatalysis

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Received: 29 November 2023
Revised: 20 January 2024
Accepted: 23 January 2024
Published: 07 March 2024
© Tsinghua University Press 2024
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