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Review Article

Covalent triazine frameworks materials for photo- and electro-catalysis

Aoji Liang1,§, Wenbin Li1,§, Anbai Li1, Hui Peng1, Guofu Ma1( ), Lei Zhu2( ), Ziqiang Lei1, Yuxi Xu3( )
Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
School of Chemistry and Materials Science, Hubei Key Laboratory of Quality Control of Characteristic Fruits and Vegetables, Hubei Engineering University, Xiaogan 432000, China
School of Engineering, Westlake University, Hangzhou 310024, China

§ Aoji Liang and Wenbin Li contributed equally to this work.

Show Author Information

Graphical Abstract

Covalent triazine skeletons (CTFs) have attracted much attention as an attractive photocatalyst and electrocatalyst due to their unique structural features. The paper reviews the synthesis methods of CTFs and their applications in photo- and electro-catalysis, and also discusses the prospects and challenges of preparing highly crystalline CTFs and designing CTFs with excellent photo- and electro-catalytic properties.

Abstract

Covalent triazine frameworks (CTFs) are a class of unique two-dimensional nitrogen-rich triazine framework with adjustable chemical and electronic structures, rich porosity, good stability and excellent semiconductivity, which enable great various applications in efficient gas/molecular adsorption and separation, energy storage and conversion, especially photo- and electro-catalysis. Different synthesis strategies strongly affect the morphology of CTFs and play an important role in their structure and properties. In this concept, we provide a comprehensive and systematic review of the synthesis methods such as ionothermal synthesis, phosphorus pentoxide catalytic method, polycondensation and ultra-strong acid catalyzed method, and applications of CTFs in photo- and electro-catalysis. Finally we offer some insights into the future development progress of CTFs materials for catalytic applications.

Keywords

covalent triazine frameworkssynthetic strategyphotocatalysiselectrocatalysis

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Nano Research
Volume 17 Issue 9,
September 2024
Pages 7830-7839
DOI: 10.1007/s12274-024-6779-y
Cite this article:
Liang A, Li W, Li A, et al. Covalent triazine frameworks materials for photo- and electro-catalysis. Nano Research, 2024, 17(9): 7830-7839. https://doi.org/10.1007/s12274-024-6779-y
Topics:
Electrocatalysis Photocatalysis

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Received: 28 April 2024
Revised: 21 May 2024
Accepted: 22 May 2024
Published: 29 June 2024
© Tsinghua University Press 2024
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